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Spontaneous vibrational Raman scattering is a ubiquitous form of light-matter interaction whose description necessitates quantization of the electromagnetic field. It is usually considered as an incoherent process because the scattered…

Quantum Physics · Physics 2023-07-18 Valeria Vento , Santiago Tarrago Velez , Anna Pogrebna , Christophe Galland

Water is an ubiquitous liquid that has several exotic and anomalous properties. Despite its apparent simple chemical formula, its capability of forming a dynamic network of hydrogen bonds leads to a rich variety of physics. Here we study…

Soft Condensed Matter · Physics 2023-08-15 R. Vuilleumier , A. P. Seitsonen

We use a method based on optical coherent transients to study the vibrational coherence lifetimes of atoms trapped in the potential wells of a near-resonant optical lattice in the oscillating regime. The dependence of the positions and…

Atomic Physics · Physics 2009-11-06 O. Morsch , P. H. Jones , D. R. Meacher

Due to their sub picosecond temporal resolution, coherent Raman spectroscopies have been proposed as a viable extension of Spontaneous Raman (SR) thermometry, to determine dynamics of mode specific vibrational energy content during out of…

Coherent Raman scattering provides highly sensitive vibrational analysis through nonlinear light-matter interactions. However, its application to metal interfaces has remained challenging because the intrinsically large non-resonant…

We have employed the method of spectral moments to study the density of vibrational states and the Raman coupling coefficient of large 2- and 3- dimensional percolators at threshold and at higher concentration. We first discuss the over-and…

Condensed Matter · Physics 2009-10-28 G. Viliani , R. Dell'Anna , O. Pilla , M. Montagna , G. Ruoco , G. Signorelli , V. Mazzacurati

We develop an ultrafast frequency-resolved Raman spectroscopy with entangled photons for polyatomic molecules in condensed phases, to probe the electronic and vibrational coherences. Using quantum correlation between the photons, the signal…

Quantum Physics · Physics 2021-06-23 Zhedong Zhang , Tao Peng , Xiaoyu Nie , Girish S. Agarwal , Marlan O. Scully

Based on the Bell theorem, it has been believed that a theoretical computation of the Bell correlation requires explicit use of an entangled state. Such a physical superposition of light waves occurs in the downconverter sources used in…

Quantum Physics · Physics 2021-01-14 Louis Sica

In the context of the quantum-mechanical description of single-molecule surface-enhanced Raman scattering, intensity-field correlation measurements of photons emitted from a plasmonic cavity are explored, theoretically, using the technique…

Quantum Physics · Physics 2019-07-10 Octavio de los Santos Sánchez

Time resolved measurements provide a new way to disentangle complex interactions in quantum materials due to their different timescales. We used pump-probe Raman scattering to investigate the apical oxygen vibration in…

Superconductivity · Physics 2021-12-07 N. Pellatz , S. Roy , J-W. Lee , J. L. Schad , H. Kandel , N. Arndt , C. B. Eom , A. F. Kemper , D. Reznik

Ultrafast lasers have become one of the most powerful tools in coherent nonlinear optical spectroscopy. Short pulses enable direct observation of fast molecular dynamics, whereas broad spectral bandwidth offers ways of controlling nonlinear…

Chemical Physics · Physics 2015-05-13 X. G. Xu , S. O. Konorov , J. W. Hepburn , V. Milner

We develop a Hamiltonian formalism to study energy and position/momentum correlations between a single Stokes photon and a single material excitation that are created as a pair in the spontaneous Raman scattering process. Our approach…

Quantum Physics · Physics 2020-01-16 Kai Shinbrough , Yanting Teng , Bin Fang , Virginia O. Lorenz , Offir Cohen

We combine the concept of Bell measurements, in which two systems are projected into a maximally entangled state, with the concept of continuous measurements, which concerns the evolution of a continuously monitored quantum system. For such…

Quantum Physics · Physics 2013-10-24 Sebastian G. Hofer , Denis V. Vasilyev , Markus Aspelmeyer , Klemens Hammerer

Understanding the interaction of charge carriers with lattice vibrations in the quasi-equilibrium regime is crucial for semiconductor functionality. However, the structural signatures of these interactions are often too subtle for…

Materials Science · Physics 2026-03-11 Guy Reuveni , Maya Levy Greenberg , Matan Menahem , Olle Hellman , Omer Yaffe

During the long course of evolution, nature has learnt how to exploit quantum effects. In fact, recent experiments reveal the existence of quantum processes whose coherence extends over unexpectedly long time and space ranges. In…

Quantum Physics · Physics 2015-07-14 G. L. Giorgi , M. Roncaglia , F. A. Raffa , M. Genovese

It is theoretically and experimentally shown that photons emitted by statistically independent incoherent classical light sources and measured in the far field in spatially separated modes may display spatial correlations akin to…

Vibrational Raman scattering -- a process where light exchanges energy with a molecular vibration through inelastic scattering -- is most fundamentally described in a quantum framework where both light and vibration are quantized. When the…

The motion of chemical bonds within molecules can be observed in real time, in the form of vibrational wavepackets prepared and interrogated through ultrafast nonlinear spectroscopy. Such nonlinear optical measurements are commonly…

Raman spectra obtained by the inelastic scattering of light by crystalline solids contain contributions from first-order vibrational processes (e.g. the emission or absorption of one phonon, a quantum of vibration) as well as higher-order…

Materials Science · Physics 2017-08-22 Yannick Gillet , Stefan Kontur , Matteo Giantomassi , Claudia Draxl , Xavier Gonze

State-of-the-art microscopes use intense lasers that can severely disturb biological processes, function and viability. This introduces hard limits on performance that only quantum photon correlations can overcome. Here we demonstrate this…

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