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The build up of polyelectrolyte multilayers (PEMs) was observed by a silicon-on-insulator (SOI) based thin film resistor. Differently charged polyelectrolytes adsorbing to the sensor surface result in defined potential shifts, which…

Soft Condensed Matter · Physics 2007-05-23 Petra A. Neff , Ali Naji , Christof Ecker , Bert Nickel , Regine von Klitzing , Andreas R. Bausch

Density functional theory (DFT) and many body perturbation theory at the G$_0$W$_0$ level are employed to study the electronic properties of polythiophene (PT) adsorbed on graphene surface. Analysis of charge density difference shows the…

Mesoscale and Nanoscale Physics · Physics 2017-09-07 F. Marsusi , I. A. Fedorov , S. Gerivani

Passivating lithium ion battery electrode surfaces to prevent electrolyte decomposition is critical for battery operations. Recent work on conformal atomic layer deposition (ALD) coating of anodes and cathodes has shown significant…

We report a detailed comparison on the role of a self-assembled monolayer (SAM) of dipolar molecules on the threshold voltage and charge carrier mobility of organic field-effect transistor (OFET) made of both amorphous and polycrystalline…

Materials Science · Physics 2014-02-05 C. Celle , C. Suspene , M. Ternisien , S. Lenfant , D. Guerin , K. Smaali , K. Lmimouni , J. P. Simonato , D. Vuillaume

Recent surveys have shown that the number of nanoparticle-based formulations actually used at the clinical level is significantly lower than expected a decade ago. One reason for this is that the nanoparticle physicochemical properties fall…

Using {\em ab initio} density functional theory calculations, we characterize changes in the electronic structure of MoS$_{2}$ monolayers introduced by missing or additional adsorbed sulfur atoms. We furthermore identify the chemical and…

Chemical Physics · Physics 2017-10-10 Anja Förster , Sibylle Gemming , Gotthard Seifert , David Tománek

We investigate the surface electronic structure and thermodynamic stability of the SrTiO3 (111) slabs using density functional theory. We observe that, for Ti-terminated slabs it is indeed possible to create a two-dimensional electron gas…

Materials Science · Physics 2015-06-16 N. Sivadas , H. Dixit , Valentino R. Cooper , Di Xiao

The interplay of electron-electron interaction and confining potential can lead to the reconstruction of fractional quantum Hall edges. We have performed exact diagonalization studies on microscopic models of fractional quantum Hall…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Xin Wan , E. H. Rezayi , Kun Yang

Pd(111) has recently been shown to exhibit a propensity to form a sub-nanometer thin surface oxide film already well before a full monolayer coverage of adsorbed O atoms is reached on the surface. Aiming at an atomic-scale understanding of…

Materials Science · Physics 2009-11-11 Mira Todorova , Karsten Reuter , Matthias Scheffler

We report how the electron transport through a solid-state metal/Gly-Gly-His tripeptide (GGH) monolayer/metal junction and the metal/GGH work function are modified by the GGH complexation with Cu2+ ions. Conducting AFM is used to measure…

We investigate the atomic and electronic structure of a single layer of pentacene on the Au(111) surface using density functional theory. To find the candidate structures we strain match the pentacene crystal geometry with the Au(111)…

Materials Science · Physics 2013-08-06 Kurt Stokbro , Søren Smidstrup

We investigate the work function (WF) variation of different Au crystallographic surface orientations with carbon atom adsorption. Ab-initio calculations within density-functional theory are performed on carbon deposited (100), (110), and…

Chemical Physics · Physics 2019-04-18 H. Z. Jooya , X. Fan , K. S. McKay , D. P. Pappas , D. A. Hite , H. R. Sadeghpour

Using density-functional theory with the local-density approximation and the generalized gradient approximation we compute the energy barriers for surface diffusion for Ag on Pt(111), Ag on one monolayer of Ag on Pt(111), and Ag on Ag(111).…

Materials Science · Physics 2009-10-30 C. Ratsch , A. P. Seitsonen , M. Scheffler

Here we a present a density functional theory study of pentacene ultra-thin films on flat [(111)] and vicinal [(455)] Au surfaces. We have performed crystal and electronic structure calculations by using PBE and optB86b-vdW functionals and…

Materials Science · Physics 2020-05-20 Ersen Mete , Mehmet Fatih Danisman

Polymer-based nanocomposite dielectrics are expected to become essential in future generations of high voltage electrical insulation. However, the physics behind their performance is not yet understood. Here we investigate electronic…

Materials Science · Physics 2016-07-29 Elena Kubyshkina , Mikael Unge , B. L. G. Jonsson

The energetics and structures of physisorbed and chemisorbed alkanethiols on Au(111) have been systematically investigated up to 10 carbon atoms using van der Waals (vdW) corrected density functional theory (DFT) calculations. The role of…

Chemical Physics · Physics 2018-03-07 Ersen Mete , Merve Yortanlı , Mehmet Fatih Danışman

We investigate the impact of the substrate on the structural properties and the morphology of alkanethiol self-assembled monolayers (SAMs) on gold, using first principles calculations and atomistic molecular dynamics simulations. We…

Materials Science · Physics 2021-02-02 Dimitrios Stefanakis , Vagelis Harmandaris , Georgios Kopidakis , Ioannis Remediakis

The atomic structures of clean and hydrogen-adsorbed Pd(001) are investigated by low energy electron diffraction (LEED) I/V analysis. Clean Pd(001) shows little surface relaxation in sharp contrast to previous reports. Adsorbing 1 monolayer…

Other Condensed Matter · Physics 2007-05-23 S. H. Kim , J. Barthel , H. L. Meyerheim , J. Kirschner , Jikeun Seo , J. -S. Kim

Using in situ low-energy electron microscopy and density functional theory, we studied the growth structure and work function of bilayer graphene on Pd(111). Low-energy electron diffraction analysis established that the two graphene layers…

Materials Science · Physics 2013-03-29 Y. Murata , S. Nie , A. Ebnonnasir , E. Starodub , B. B. Kappes , K. F. McCarty , C. V. Ciobanu , S. Kodambaka

We report on electronic transport calculations for self-assembled mono-layers (SAM) of 1,4-phenylene diisocyanide on Au(111) contacts. Experimentally one observes more structure (i.e peaks) within the measured conductance curve for this…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Robert Dahlke , Ulrich Schollwoeck