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Here we describe an optical method to determine the dynamics of optically excited carriers in nanostructured composite samples. By combining pump-probe time-resolved reflectivity with scattering measurements, we extract the characteristic…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 J. Barreto , T. Roger , A. Kaplan

Measurements of charge-carrier lifetime in many early-stage thin-film photovoltaic materials can be arduous due to the prevalence of defects and limited information about material properties. In this perspective, we give a brief overview of…

Materials Science · Physics 2018-05-16 Jeremy R. Poindexter , Edward S. Barnard , Rachel C. Kurchin , Tonio Buonassisi

Understanding carrier dynamics in photoexcited metal-halide perovskites is key for optoelectronic devices such as solar cells (low carrier densities) and lasers (high carrier densities). Trapping processes at low carrier densities and…

The understanding of the mixed ionic-electronic nature of charge transport in Metal Halide Perovskites (MHPs) and the role of morphological and interface defects is crucial for improving the performance of MHP based photovoltaic devices. We…

Applied Physics · Physics 2025-01-03 Mohd Warish , Gaurav Jamwal , Zara Aftab , Nidhi Bhatt , Asad Niazi

A modified detailed balance model is built to understand and quantify efficiency loss of perovskite solar cells. The modified model captures the light-absorption dependent short-circuit current, contact and transport-layer modified carrier…

We describe a theory on photo-thermoelectric properties of a semiconductor, which include photo-conductivity, photo-Seebeck coefficient, and photo-Hall effect. We demonstrate that these properties provide a powerful tool for the study of…

Materials Science · Physics 2019-11-01 Zhenyu Pan , Zheng Zhu , Jeffrey J. Urban , Fan Yang , Heng Wang

Investigation of the inherent field-driven charge transport behaviour of 3D lead halide perovskites has largely remained a challenging task, owing primarily to undesirable ionic migration effects near room temperature. In addition, the…

Semiconducting polycrystalline thin films are cheap to produce and can be deposited on flexible substrates, yet high-performance electronic devices usually utilize single-crystal semiconductors, owing to their superior electrical mobilities…

Halide perovskites have attracted increasing research attention regarding their outstanding optoelectronic applications. Owing to its low activation energy, ion migration is implicated in the long-term stability and many unusual transport…

Applied Physics · Physics 2020-12-02 Qiao Kong , Amael Obliger , Minliang Lai , Mengyu Gao , David T. Limmer , Peidong Yang

Defect tolerance is a critical enabling factor for efficient lead-halide perovskite materials, but the current understanding is primarily on band-edge (cold) carriers, with significant debate over whether hot carriers (HCs) can also exhibit…

The knowledge of the carrier dynamics in nanostructures is of fundamental importance for the development of (opto)electronic devices. This is true for semiconducting nanostructures as well as for plasmonic nanoparticles (NPs). Indeed,…

With rapidly growing photoconversion efficiencies, hybrid perovskite solar cells have emerged as promising contenders for next generation, low-cost photovoltaic technologies. Yet, the presence of nanoscale defect clusters, that form during…

The migration motion of defects in metal halide perovskites quantum dots (MHPQDs) results in charge-carrier trapping become more complicated. We study two-step trapping mediated by mobile defects between the ground state of MHPQDs and a…

Mesoscale and Nanoscale Physics · Physics 2023-04-12 Xiao-Yi Liu , Wei-Ping Li , Yu Cui , Shao-Juan Li , Ran-Bo Yang , Zhi-Qing Li , Zi-Wu Wang

Halide perovskite semiconductors are a promising material for high-efficiency solar cells. Their optical properties can vary within and between crystallographic grains. We present spatially-resolved cathodoluminescence (CL) spectroscopy at…

The capture of photoexcited deep-band hot carriers, excited by photons with energies far above the bandgap, is of significant importance for photovoltaic and photoelectronic applications since it is directly related to the quantum…

Materials Science · Physics 2021-03-18 Jin Zhang , Hao Hong , Jincan Zhang , Chunchun Wu , Hailin Peng , Kaihui Liu , Sheng Meng

Accurate determination of carrier transport properties in two-dimensional (2D) materials is critical for designing high-performance nano-electronic devices and quantum information platforms. While first-principles calculations effectively…

Mesoscale and Nanoscale Physics · Physics 2020-12-04 Sathwik Bharadwaj , Ashwin Ramasubramaniam , L. R. Ram-Mohan

The significant surge in energy use and escalating environmental concerns have sparked worldwide interest towards the study and implementation of solar cell technology. Perovskite solar cells (PSCs) have garnered remarkable attention as an…

Materials Science · Physics 2025-06-23 Md Yekra Rahman , Sharif Mohammad Mominuzzaman

The physical principles motivating the Z-scanning laser photoreflectance technique are discussed. The technique is shown to provide a powerful non-contact means to unambiguously characterize electronic transport properties in…

Mesoscale and Nanoscale Physics · Physics 2021-12-08 Will Chism

The dynamics of charge carriers in amorphous semiconductors fundamentally differ from those in crystalline semiconductors due to the lack of long-range order and the high defect density. Despite intensive technology-driven research…

Materials Science · Physics 2017-10-11 Bolin Liao , Ebrahim Najafi , Heng Li , Austin J. Minnich , Ahmed H. Zewail

Energy carrier evolution is crucial for material performance. Ultrafast microscopy has been widely applied to visualize the spatiotemporal evolution of energy carriers. However, direct imaging of small amounts of energy carriers on…

Optics · Physics 2022-05-26 Pin-Tian Lyu , Qing-Yue Li , Pei Wu , Chao Sun , Bin Kang , Hong-Yuan Chen , Jing-Juan Xu