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This paper is devoted to a generalisation of the quantum adiabatic theorem to a nonlinear setting. We consider a Hamiltonian operator which depends on the time variable and on a finite number of parameters and acts on a separable Hilbert…

Mathematical Physics · Physics 2020-10-16 Clotilde Fermanian Kammerer , Alain Joye

We treat a quantum mechanical system with certain general properties which are expected to be common in macroscopic quantum systems. Starting from a PURE initial state (which may not describe an equilibrium) in which energy is mildly…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

We have studied dynamical responses and the Jarzynski equality (JE) of classical open systems described by the generalized Caldeira-Leggett model with the nonlocal system-bath coupling. In the derived non-Markovian Langevin equation, the…

Statistical Mechanics · Physics 2015-05-30 Hideo Hasegawa

The free-energy difference $\Delta F$ between two high-dimensional systems is notoriously difficult to compute, but very important for many applications, such as drug discovery. We demonstrate that an unconventional definition of work…

Soft Condensed Matter · Physics 2024-10-24 Adrianne Zhong , Benjamin Kuznets-Speck , Michael R. DeWeese

Work fluctuation and total entropy production play crucial roles in small thermodynamic systems subject to large thermal fluctuations. We investigate a trade-off relation between them in a nonequilibrium situation in which a system starts…

Statistical Mechanics · Physics 2016-12-15 Ken Funo , Tomohiro Shitara , Masahito Ueda

A main goal of single-molecule experiments is to evaluate equilibrium free energy differences by applying fluctuation relations to repeated work measurements along irreversible processes. We quantify the error that is made in a free energy…

Statistical Mechanics · Physics 2009-06-22 Alessandro Mossa , Sara de Lorenzo , Josep Maria Huguet , Felix Ritort

We suggest and discuss a simple model of an ideal gas under the piston to gain an insight into the workings of the Jarzynski identity connecting the average exponential of the work over the non-equilibrium trajectories with the equilibrium…

Statistical Mechanics · Physics 2007-05-23 R. C. Lua , A. Y. Grosberg

There is evidence that taking the time average of the work performed by a thermally isolated system effectively "transforms" the adiabatic process into an isothermal one. This approach allows inherent quantities of adiabatic processes to be…

Statistical Mechanics · Physics 2025-10-03 Pierre Nazé

Quantum work is usually determined from two projective measurements of the energy at the beginning and at the end of a thermodynamic process. However, this paradigm cannot be considered thermodynamically consistent as it does not account…

Quantum Physics · Physics 2016-07-13 Sebastian Deffner , Juan Pablo Paz , Wojciech H. Zurek

The relation between the work performed to a system and the change of its free energy during a certain process is important in nonequilibrium statistical mechanics. In particular, the work relation with measurement and feedback control has…

Statistical Mechanics · Physics 2018-11-26 Hideyuki Miyahara , Kazuyuki Aihara

Two identities in statistical mechanics involving entropy differences (or ratios of density of states) at constant energy are derived. The first provides a nontrivial extension of the Jarzynski equality to the microcanonical ensemble [C.…

Statistical Mechanics · Physics 2009-11-10 Artur B. Adib

We show how statistical thermodynamics can be formulated in situations in which thermodynamics applies, while equilibrium statistical mechanics does not. A typical case is, in the words of Landau and Lifshitz, that of partial (or…

Statistical Mechanics · Physics 2013-04-16 A. Carati , A. Maiocchi , L. Galgani

Free energy fixes the maximum work of a thermodynamic process once the state and Hamiltonian are specified. A work-extraction task asks a different question: how much average work can a single device realize across several preparations and…

Quantum Physics · Physics 2026-05-06 Sumit Rout , Aravinth Balaji Ravichandran , Paweł Horodecki , Anubhav Chaturvedi

We study thermodynamic operations which bring a nonequilibrium steady state (NESS) to another NESS in physical systems under nonequilibrium conditions. We model the system by a suitable Markov jump process, and treat thermodynamic…

Statistical Mechanics · Physics 2018-08-02 Teruhisa S. Komatsu , Naoko Nakagawa , Shin-ichi Sasa , Hal Tasaki

We discuss the stochastic thermodynamics of systems that are described by a time-dependent density field, for example simple liquids and colloidal suspensions. For a time-dependent change of external parameters, we show that the Jarzynski…

Statistical Mechanics · Physics 2014-03-18 T. Leonard , B. Lander , U. Seifert , T. Speck

Jarzynski's equality [1] allows us to investigate free energy landscapes (FELs) by constructing distributions of work performed on a system from an initial ensemble of states to final states. This work is experimentally measured by…

Biological Physics · Physics 2011-05-24 Van Ngo

This work focuses on the response to an external field of a Brownian particle submerged in an Ohmic quantum thermal bath. The field only affects the dynamics of the central particle without affecting the thermal reservoir. The thermodynamic…

Quantum Physics · Physics 2019-11-12 Pedro J. Colmenares

According to the Jarzynski theorem, equilibrium free energy differences can be calculated from the statistics of work carried out during non-equilibrium transformations. Although exact, this approach can be plagued by large statistical…

Statistical Mechanics · Physics 2007-05-23 Wolfgang Lechner , Christoph Dellago

We briefly introduce the quantum Jarzynski and Bochkov-Kuzovlev equalities in isolated quantum Hamiltonian systems, which includes the origin of the equalities, their derivations using a quantum Feynman-Kac formula, the quantum Crooks…

Statistical Mechanics · Physics 2015-06-19 Fei Liu , Zhong-can Ou-Yang

The second law of thermodynamics for adiabatic operations -- constraints on state transitions in closed systems under external control -- is one of the fundamental principles of thermodynamics. On the other hand, it is recently established…

Statistical Mechanics · Physics 2026-02-09 Yuuya Chiba , Yasushi Yoneta , Ryusuke Hamazaki , Akira Shimizu