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Related papers: Molecular polaritons for controlling chemistry wit…

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Polaritons are the collective excitations of many atoms dressed by resonant photons, which can be used to explain the slow light propagation with the mechanism of electromagnetically induced transparency. As quasi-particles, these…

Quantum Physics · Physics 2009-11-13 Lan Zhou , Jing Lu , D. L. Zhou , C. P. Sun

The insensitivity of photons towards external magnetic fields forms one of the hardest barriers against efficient magneto-optical control, aiming at modulating the polarization state of light. However, there is even scarcer evidence of…

Mesoscale and Nanoscale Physics · Physics 2024-08-02 Magdalena Furman , Rafał Mirek , Mateusz Król , Wojciech Pacuski , Helgi Sigurðsson , Jacek Szczytko , Barbara Piętka

Recent experiments in polariton chemistry have demonstrated that reaction rates can be modified by vibrational strong coupling to an optical cavity mode. Importantly, this modification only occurs when the frequency of the cavity mode is…

Chemical Physics · Physics 2023-05-15 Marit R. Fiechter , Johan E. Runeson , Joseph E. Lawrence , Jeremy O. Richardson

The concept of modifying molecular dynamics in strongly coupled exciton-polariton systems is an emerging topic in photonics due to its potential to produce customized chemical systems with tailored photophysical properties. However, before…

Materials Science · Physics 2020-10-09 Bin Liu , Vinod M. Menon , Matthew Y. Sfeir

We introduce a model description of a diatomic molecule in an optical cavity, with pump and fluorescent fields, and electron and nuclear motion are treated on equal footing and exactly. The model accounts for several optical response…

Quantum Physics · Physics 2024-05-30 Megha Gopalakrishna , Emil Viñas Boström , Claudio Verdozzi

Core-excitations on different atoms are highly localized and therefore decoupled. By placing molecules in an X-ray cavity the core-transitions become coupled via the exchange of cavity photons and form delocalized hybrid light-matter…

Quantum Physics · Physics 2021-02-08 Bing Gu , Artur Nenov , Francesco Segatta , Marco Garavelli , Shaul Mukamel

We introduce crystal polaritons, hybrid excitations formed when the collective excitations of a periodic quantum-emitter array strongly couple to the resonant Bloch modes of a metasurface. This realizes a cavity-QED platform in which…

We introduce a theoretical framework that allows for the systematic and efficient description of the ultrafast nonlinear response of molecular polaritons, i.e., hybrid light-matter states, in the collective regime of large numbers of…

Quantum Physics · Physics 2025-05-22 Michael Reitz , Arghadip Koner , Joel Yuen-Zhou

The polariton, a quasiparticle formed by strong coupling of a photon to a matter excitation, is a fundamental ingredient of emergent photonic quantum systems ranging from semiconductor nanophotonics to circuit quantum electrodynamics.…

Quantum Gases · Physics 2024-03-21 Joonhyuk Kwon , Youngshin Kim , Alfonso Lanuza , Dominik Schneble

Strong light-matter coupling to form exciton- and vibropolaritons is increasingly touted as a powerful tool to alter the fundamental properties of organic materials. It is proposed that these states and their facile tunability can be used…

Polaritons - hybrid light-matter states formed from the strong coupling of a bright molecular transition with a confined photonic mode - may offer new opportunities for optical control of molecular behavior. Vibrational strong coupling…

Chemical Physics · Physics 2025-11-19 Liying Chen , Alexander M. McKillop , Ashley P. Fidler , Marissa L. Weichman

Despite recent numerical evidence, one of the fundamental theoretical mysteries of polaritonic chemistry is how and if collective strong coupling can induce local changes of the electronic structure to modify chemical properties. Here we…

The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties such as lasing, room temperature polariton condensation, and the modification of excited electronic landscapes…

We study cavity optomechanics of a mixture of ultracold atoms with tunable nonlinear collisions. We show that atomic collisions provide linear couplings between fictitious condensate oscillators, leading to possibilities of achieving a…

Quantum Physics · Physics 2012-12-07 H. Jing , X. Zhao , L. F. Buchmann

Recent advancements on the fabrication of organic micro- and nanostructures have permitted the strong collective light-matter coupling regime to be reached with molecular materials. Pioneering works in this direction have shown the effects…

Polaritonic states arise when a bright optical transition of a molecular ensemble is resonantly matched to an optical cavity mode frequency. Here, we lay the groundwork to study the behavior of polaritons in clean, isolated systems by…

Chemical Physics · Physics 2023-10-20 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

Experiments show that light-matter strong coupling affects chemical properties, though the underlying mechanism remains unclear. We present an ab initio quantum electrodynamics coupled cluster method for the collective strong coupling…

Chemical Physics · Physics 2024-11-18 Matteo Castagnola , Marcus T. Lexander , Henrik Koch

Engineering strong interactions between optical photons is a great challenge for quantum science. Envisioned applications range from the realization of photonic gates for quantum information processing to synthesis of photonic quantum…

Mesoscale and Nanoscale Physics · Physics 2019-11-26 Patrick Knüppel , Sylvain Ravets , Martin Kroner , Stefan Fält , Werner Wegscheider , Atac Imamoglu

Organic polaritons resulting from the strong hybridisation between photons and matter excitations have arisen as a suitable platform to device light-matter technological interfaces at room temperature. Despite their inherent complexity,…

We investigate the interaction between light and molecular systems modeled as quantum emitters coupled to a multitude of vibrational modes via a Holstein-type interaction. We follow a quantum Langevin equations approach that allows for…

Quantum Physics · Physics 2020-04-27 Michael Reitz , Christian Sommer , Claudiu Genes