English
Related papers

Related papers: Molecular polaritons for controlling chemistry wit…

200 papers

The coupling of internal electronic excitations to vibrational modes of the external motion of ultracold atoms in an optical lattice is studied here in using a perturbation expansion in small atomic displacements. In the Mott insulator case…

Quantum Gases · Physics 2011-06-08 Hashem Zoubi , Helmut Ritsch

We employ the exact factorization of a multi-component wavefunction to analyze the dynamics of interacting photons, electrons and nuclei. We consider physical situations emerging in the regime of strong coupling between light excitations…

Chemical Physics · Physics 2026-04-24 Claudia Magi , Peter Schuerger , David Lauvergnat , Federica Agostini

Quantum light-matter systems at strong coupling are notoriously challenging to analyze due to the need to include states with many excitations in every coupled mode. We propose a nonperturbative approach to analyze light-matter correlations…

Mesoscale and Nanoscale Physics · Physics 2021-04-15 Yuto Ashida , Atac Imamoglu , Eugene Demler

We revisited the intersubband polaritonics - the branch of mesoscopic physics having a huge potential for optoelectronic applications in the infrared and terahertz domains - and found that, contrary to the general opinion, the Coulomb…

Materials Science · Physics 2013-03-05 Oleksandr Kyriienko , Ivan A. Shelykh

The field of vibrational polariton chemistry was firmly established in 2016 when a chemical reaction rate at room temperature was modified within a resonantly tuned infrared cavity without externally driving the system. Despite intense…

Chemical Physics · Physics 2021-07-20 Derek S Wang , Susanne F Yelin

Dipolaritons are quasiparticles that arise in coupled quantum wells embedded in a microcavity, they are a superposition of a photon, a direct exciton and an indirect exciton. We propose the existence of dipolaritons in a system of two…

Mesoscale and Nanoscale Physics · Physics 2016-11-23 J. S. Rojas-Arias , B. A. Rodríguez , H. Vinck-Posada

Dipole-coupled subwavelength quantum emitter arrays respond cooperatively to external light fields as they may host collective delocalized excitations (a form of excitons) with super- or subradiant character. Deeply subwavelength…

Quantum Physics · Physics 2022-08-18 Raphael Holzinger , Sue Ann Oh , Michael Reitz , Helmut Ritsch , Claudiu Genes

Nonperturbative coupling of light with condensed matter in an optical cavity is expected to reveal a host of coherent many-body phenomena and states. In addition, strong coherent light-matter interaction in a solid-state environment is of…

Rayleigh scattering is usually considered to be the elastic scattering of photons from sub-wavelength physical objects, such as small particles or molecules. Here, we present the spectroscopic study of the scattering properties of molecules…

Quantum Physics · Physics 2020-04-28 Adina Golombek , Mukundakumar Balasubrahmaniyam , Maria Kaeek , Keren Hadar , Tal Schwartz

Light-matter interactions are known to lead to the formation of polariton states through what is called strong coupling, leading to the formation of two hybrid states usually tagged as Upper and Lower Polaritons. Here, we consider a similar…

An ideal and reversible transfer technique for the quantum state between light and metastable collective states of matter is presented and analyzed in detail. The method is based on the control of photon propagation in coherently driven…

Quantum Physics · Physics 2009-11-07 M. Fleischhauer , M. D. Lukin

This chapter reviews the fundamental optical properties and applications of pho-tonic molecules (PMs) - photonic structures formed by electromagnetic coupling of two or more optical microcavities (photonic atoms). Controllable interaction…

Optics · Physics 2015-03-13 Svetlana V. Boriskina

Organic microcavities can be engineered to reach exotic quantum regimes of strong and ultrastrong light-matter coupling. However, the microscopic interpretation of their spectroscopic signals can be challenging due to the competition…

Quantum Physics · Physics 2017-06-07 Felipe Herrera , Frank C. Spano

Intermolecular interactions are pivotal for aggregation, solvation, and crystallization. We demonstrate that the collective strong coupling of several molecules to a single optical mode results in notable changes in the molecular…

Quantum Physics · Physics 2024-02-19 Matteo Castagnola , Tor S. Haugland , Enrico Ronca , Henrik Koch , Christian Schäfer

Molecular complexes are held together via a variety of bonds, but they all share the common feature that their individual entities are in contact. In this work, we introduce and demonstrate the concept of a \textit{molecular optical bond},…

Mesoscale and Nanoscale Physics · Physics 2025-01-03 Jahangir Nobakht , André Pscherer , Jan Renger , Stephan Götzinger , Vahid Sandoghdar

The first exact quantum simulation of a real molecular system (HD$^+$) under strong ro-vibrational coupling to a quantized optical cavity mode in thermal equilibrium is presented. Theoretical challenges in describing strongly coupled…

Quantum Physics · Physics 2022-08-03 Dominik Sidler , Michael Ruggenthaler , Angel Rubio

Recent experiments have observed that the chemical and photophysical properties of molecules can be modified inside an optical Fabry-Perot microcavity under collective vibrational strong coupling (VSC) conditions, and such modification is…

Mesoscale and Nanoscale Physics · Physics 2021-03-09 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

Polaritonic chemistry investigates the possible modification of chemical and photochemical reactions by means of strong light-matter coupling in optical cavities, as demonstrated in numerous experiments over the last few years. These…

Quantum Physics · Physics 2025-07-30 Lucas Borges , Thomas Schnappinger , Markus Kowalewski

This thesis studies light-matter interactions in strong and weak coupling regimes. In the first part, we study the formation and propagation of exciton-polariton condensates in different microcavities in the strong coupling regime.…

Mesoscale and Nanoscale Physics · Physics 2024-01-19 Dogyun Ko

A quantum system composed of a molecule and an atomic ensemble, confined in a microscopic cavity, is investigated theoretically. The indirect coupling between atoms and the molecule, realized by their interaction with the cavity radiation…

Chemical Physics · Physics 2020-05-05 Tamás Szidarovszky , Gábor J. Halász , Ágnes Vibók