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Perovskite solar cells (PSC) are shown to behave as coupled ionic-electronic conductors with strong evidence that the ionic environment moderates both the rate of electron-hole recombination and the band offsets in planar PSC. Numerous…

Materials Science · Physics 2017-04-05 Adam Pockett , Giles Eperon , Nobuya Sakai , Henry Snaith , Laurence M Peter , Petra J Cameron

A model is derived for the frequency- and time-domain opto-electronic response of perovskite solar cells (PSCs) that emphasizes the role of charge carrier exchange, .i.e. extraction and injection, from (to) the perovskite through the…

Materials Science · Physics 2023-11-10 Sandheep Ravishankar , Zhifa Liu , Yueming Wang , Thomas Kirchartz , Uwe Rau

Perovskite photovoltaic technologies are approaching commercial deployment, yet single junction and tandem architectures both still have significant room to improve power conversion efficiency and stability. The ability to perform rapid…

Ion migration in perovskite solar cells is usually analyzed and understood in terms of charge neutrality condition. However, several recent reports indicate possibility of ionic imbalance in the active layer due to external ion migration…

Materials Science · Physics 2023-01-27 Dhyana Sivadas , Abhimanyu Singareddy , Chittiboina vinod , Pradeep Nair

Lead-halide perovskites are semiconductor materials with attractive properties for photovoltaic and other optoelectronic applications. However, determining crucial electronic material parameters, such as charge-carrier mobility and…

Materials Science · Physics 2024-11-05 Ye Yuan , Genghua Yan , Samah Akel , Uwe Rau , Thomas Kirchartz

Metal halide perovskites exhibit coupled electronic and ionic properties that determine their photovoltaic performance and operational stability. Understanding and quantifying ionic transport are therefore essential for advancing perovskite…

Perovskite-based optoelectronic devices have shown great promise for solar conversion and other optoelectronic applications, but their long-term performance instability is regarded as a major obstacle to their widespread deployment.…

Control of materials through custom design of ionic distributions represents a powerful new approach to develop future technologies ranging from spintronic logic and memory devices to energy storage. Perovskites have shown particular…

Perovskite semiconductors have demonstrated outstanding external luminescence quantum yields, enabling high power conversion efficiencies (PCE). However, the precise conditions to advance to an efficiency regime above monocrystalline…

Billions of everyday objects could become part of the Internet of Things (IoT) by augmentation with low-cost, long-range, maintenance-free wireless sensors. Radio Frequency Identification (RFID) is a low-cost wireless technology that could…

Perovskite light-emitting field-effect transistors (PeLEFETs) provide a versatile device architecture to control transport and electroluminescence properties of hybrid perovskites, enabling injection of high charge carrier density and…

Applied Physics · Physics 2017-10-06 Francesco Maddalena , Xin Yu Chin , Daniele Cortecchia , Annalisa Bruno , Cesare Soci

Existing approaches for the field measurements of the frequency-dependent soil properties take a significant amount of time, making it difficult to obtain new experimental data and study the electrical soil properties further. However, a…

Geophysics · Physics 2022-02-07 Dmitry Kuklin

Fundamental working mechanisms of perovskite solar cells remain an elusive topic of research. Impedance Spectroscopy (IS) application to perovskite-based devices generates uncommon features and misleading outputs, mainly due to the lack of…

Applied Physics · Physics 2019-08-19 So-Min Yoo , Seog Joon Yoon , Juan A. Anta , Hyo Joong Lee , Pablo P. Boix , Iván Mora-Seró

The ideality factor determined by measuring the open circuit voltage (VOC) as function of light intensity is often used as a means to identify the dominant recombination mechanism in solar cells. However, applying this Suns-VOC technique to…

This paper presents a multiscale approach to evaluate perovskite solar cell performance which determines material properties at the atomistic scale with first-principles calculations, and applies them in macro-scale device models. This work…

In this perspective, we explore the insights into the device physics of perovskite solar cells gained from modeling and simulation of these devices. We discuss a range of factors that influence the modeling of perovskite solar cells,…

Applied Physics · Physics 2020-08-04 Nir Tessler , Yana Vaynzof

Optoelectronic devices operate under continuous thermal stress that may influence both long-term stability and optical properties of the active material. It is therefore useful to know the elastic properties of the active materials. In…

Recent developments in frequency metrology and optical clocks have been based on electronic transitions in atoms and singly charged ions as references. These systems have enabled relative frequency uncertainties at a level of a few parts in…

Atomic Physics · Physics 2018-12-06 M. G. Kozlov , M. S. Safronova , J. R. Crespo López-Urrutia , P. O. Schmidt

Two types of optically manipulated quantum electronic devices are considered: a quantum dot and a finite periodic molecular chain, with the period doubled under resonance optical excitation. The stability of the working regimes of the…

Quantum Physics · Physics 2007-05-23 I. Antoniou , B. Pavlov , A. Yafyasov

The frequency-dependent impedance is a fundamental property of electrical components. We show that it can be determined from the equilibrium dynamical fluctuations of the electrode charge in constant-potential molecular simulations,…

Chemical Physics · Physics 2023-03-15 Giovanni Pireddu , Benjamin Rotenberg