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According to Thermodynamics, the efficiency of a heat engine is upper bounded by Carnot efficiency. For macroscopic systems, the Carnot efficiency is, however, achieved only for quasi static processes. And, considerable attention has been…

Statistical Mechanics · Physics 2023-05-03 Takaaki Monnai

At the dawn of thermodynamics, Carnot's constraint on efficiency of heat engines stimulated the formulation of one of the most universal physical principles, the second law of thermodynamics. In recent years, the field of heat engines…

Statistical Mechanics · Physics 2021-12-23 Viktor Holubec , Artem Ryabov

According to the laws of thermodynamics, no heat engine can beat the efficiency of a Carnot cycle. This efficiency traditionally comes with vanishing power output and practical designs, optimized for power, generally achieve far less.…

Statistical Mechanics · Physics 2018-09-26 Viktor Holubec , Artem Ryabov

The Carnot cycle imposes a fundamental upper limit to the efficiency of a macroscopic motor operating between two thermal baths. However, this bound needs to be reinterpreted at microscopic scales, where molecular bio-motors and some…

Statistical Mechanics · Physics 2016-02-03 Ignacio A. Martínez , Édgar Roldán , Luis Dinis , Dmitri Petrov , Juan M. R. Parrondo , Raúl A. Rica

For finite-time quantum Otto heat engine with working fluid consisting of either a (i) qubit or (ii) a harmonic oscillator, we show that the relative fluctuation of output work is always greater than the corresponding relative fluctuation…

Statistical Mechanics · Physics 2021-06-30 Sushant Saryal , Bijay Kumar Agarwalla

We investigate fluctuations of output work for a class of Stirling heat engines with working fluid composed of interacting units and compare these fluctuations to an average work output. In particular, we focus on engine performance close…

Statistical Mechanics · Physics 2017-09-08 Viktor Holubec , Artem Ryabov

We study the stochastic energetic exchanges in quantum heat engines. Due to microreversibility, these obey a fluctuation relation, called the heat engine fluctuation relation, which implies the Carnot bound: no machine can have an…

Quantum Physics · Physics 2015-03-24 Michele Campisi , Jukka Pekola , Rosario Fazio

A heat engine operating in the one-shot finite-size regime, where systems composed of a small number of quantum particles interact with hot and cold baths and are restricted to one-shot measurements, delivers fluctuating work. Further,…

Quantum Physics · Physics 2021-02-15 Mohit Lal Bera , Maciej Lewenstein , Manabendra Nath Bera

In the standard framework of thermodynamics the work produced or consumed in a process is a random variable whose average value is bounded by the change in the free energy of the system. This work is calculated without regard for the size…

Quantum Physics · Physics 2017-04-19 Jonathan G. Richens , Lluis Masanes

We study the maximum efficiency of a Carnot cycle heat engine based on a small system. It is revealed that due to the finiteness of the system, irreversibility may arise when the working substance contacts with a heat bath. As a result,…

Statistical Mechanics · Physics 2014-02-05 H. T. Quan

We introduce heat engines working in the nano-regime that allow to extract a finite amount of deterministic work. We show that the efficiency of these cycles is strictly smaller than Carnot's, and we associate this difference with a…

Quantum Physics · Physics 2024-06-11 Federico Cerisola , Facundo Sapienza , Augusto Roncaglia

We study bounds on ratios of fluctuations in steady-state time-reversal heat engines controlled by multi affinities. In the linear response regime, we prove that the relative fluctuations (precision) of the output current (power) is always…

Statistical Mechanics · Physics 2021-11-17 Sushant Saryal , Matthew Gerry , Ilia Khait , Dvira Segal , Bijay Kumar Agarwalla

The efficiency of an heat engine is traditionally defined as the ratio of its average output work over its average input heat. Its highest possible value was discovered by Carnot in 1824 and is a cornerstone concept in thermodynamics. It…

Statistical Mechanics · Physics 2015-06-19 Gatien Verley , Tim Willaert , Christian Van den Broeck , Massimiliano Esposito

The Carnot theorem, one expression of the second law of thermodynamics, places a fundamental upper bound on the efficiency of heat engines operating between two heat baths. The Carnot theorem can be stated in a more generalized form for…

Statistical Mechanics · Physics 2022-06-03 Yuki Izumida

Fluctuations of thermodynamic quantities become non-negligible and play an important role when the system size is small. We develop finite-time thermodynamics of fluctuations in microscopic heat engines whose environmental temperature and…

Statistical Mechanics · Physics 2022-02-16 Gentaro Watanabe , Yuki Minami

The thermodynamic properties of quantum heat engines are stochastic owing to the presence of thermal and quantum fluctuations. We here experimentally investigate the efficiency and nonequilibrium entropy production statistics of a spin-1/2…

Quantum Physics · Physics 2021-04-29 Tobias Denzler , Jonas F. G. Santos , Eric Lutz , Roberto Serra

A long standing open problem whether a heat engine with finite power achieves the Carnot efficiency is investigated. We rigorously prove a general trade-off inequality on thermodynamic efficiency and time interval of a cyclic process with…

Statistical Mechanics · Physics 2017-08-18 Naoto Shiraishi , Hiroyasu Tajima

We derive a bound on the efficiency of thermal engines that can be sharper than Carnot's limit. It is a function of statistical correlations between the engine internal state and Hamiltonian, can be saturated even in finite-time cycles, and…

Quantum Physics · Physics 2026-04-14 Anna Gabetti , Fabrizio Dolcini , Davide Girolami

The stochastic efficiency [G. Verley et al., Nat. Commun. 5, 4721 (2014)] was introduced to evaluate the performance of energy-conversion machines in micro-scale. However, such an efficiency generally diverges when no heat is absorbed while…

Statistical Mechanics · Physics 2022-03-02 Zhayu Fei , Jin-Fu Chen , Yu-Han Ma

Developments in the thermodynamics of small quantum systems envisage non-classical thermal machines. In this scenario, energy fluctuations play a relevant role in the description of irreversibility. We experimentally implement a quantum…

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