Related papers: Solving the non-relativistic electronic Schrodinge…
The non-relativistic electronic Hamiltonian, Hkin + Hne + aHee, is linear in coupling strength parameter (a), but its eigenvalues (electronic energies) have only quasi-linear dependence on it. Detailed analysis is given on the participation…
Many equations have been introduced and derived by the author indicated in the title in relation to multi-electron densities between the Hohenberg-Kohn theorems and variational principle, conversion of the non-relativistic electronic…
The nonrelativistic Hamiltonians of scalar, spinor and vector particles in the electromagnetic field are studied by applying the Douglas-Kroll-Hess approach. Their relativistic Hamiltonians are expanded on the potential, and the…
The Brillouin theorem has been generalized for the extended non-relativistic electronic Hamiltonian (Hkin+ Hne+ aHee) in relation to coupling strength parameter (a), as well as for the configuration interactions (CI) formalism in this…
The congruent transformation of the electronic Hamiltonian is developed to address the electron correlation problem in many-electron systems. The central strategy presented in this method is to perform transformation on the electronic…
We substantiate the need for account of the proper electromagnetic field of the electron in the canonical problem of hydrogen in relativistic quantum mechanics. From mathematical viewpoint, the goal is equivalent to determination of the…
We present a new computational method for the determination of energy levels in four-particle systems like H$_2$, HD, and HeH$^+$ using explicitly correlated exponential basis functions and analytic integration formulas. In solving the…
The simplest, algebraic quantum-electrodynamical corrections, due to the double-negative energy subspace and instantaneous interactions, are computed to the no-pair energy of two-spin-1/2-fermion systems. Numerical results are reported for…
We present the effective Hamiltonian for an electron-nucleus interaction in non-relativistic limit up to the second order in the inverse nucleon mass. This Hamiltonian takes into account the distortion of electron waves and allows to…
The concept of energy-dependent forces in quantum mechanics is re-analysed. We suggest a simplification of their study via the representation of each self-adjoint and energy-dependent Hamiltonian H=H(E) with real spectrum by an auxiliary…
The relativistic Hartree-Fock and electron correlation methods without the negative-energy orbital problem are examined on the basis of the quantum electrodynamics (QED) Hamiltonian. First, several QED Hamiltonians previously proposed are…
We derive the effective Hamiltonian of the Nonrelativistic Quantum Electrodynamic up to $m\alpha^8$ by using scattering matching approach. At $m\alpha^6$ order, these results are coincide with Pachucki's, which is obtained by applying…
The effects on the non-relativistic dynamics of a system compound by two electrons interacting by a Coulomb potential and with an external harmonic oscillator potential, confined to move in a two dimensional Euclidean space, are…
The ordinary Schrodinger equation with minimal coupling for a nonrelativistic electron interacting with a single-mode photon field is not satisfied by the nonrelativistic limit of the exact solutions to the corresponding Dirac equation. A…
We investigate the ground state energy of an electron coupled to a photon field. First, we regard the self-energy of a free electron, which we describe by the Pauli-Fierz Hamiltonian. We show that, in the case of small values of the…
We present a numerical tool for solving the non-relativistic Kohn-Sham problem for spherically-symmetric atoms. It treats the Schr\"{o}dinger equation as an integral equation relying heavily on convolutions. The solver supports different…
We study the valence electron of an alkaline atom or a general charged particle with arbitrary spin and with magnetic moment moving in a rotating magnetic field. By using a time-dependent unitary transformation, the Schr\"odinger equation…
We present a direct ab initio solution of the Schrodinger equation for neutral helium and helium-like atoms that reproduces the energy of the singlet S state 1S0. By redefining the two-electron wavefunction with tools from complex analysis…
We present a nonrelativistic wave equation for the electron in (3+1)-dimensions which includes negative-energy eigenstates. We solve this equation for three well-known instances, reobtaining the corresponding Pauli equation (but including…
Electron-electron correlation forms the basis of difficulties encountered in many-body physics. Accurate treatment of the correlation problem is likely to unravel some nice physical properties of matter embedded in the correlation. In an…