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In this paper, we discuss extending the sub-system embedding sub-algebra coupled cluster (SESCC) formalism and the double unitary coupled cluster (DUCC) Ansatz to the time domain. An important part of the analysis is associated with proving…

Quantum Physics · Physics 2020-07-15 Karol Kowalski , Nicholas P. Bauman

In this paper we outline the extension of recently introduced the sub-system embedding sub-algebras coupled cluster (SES-CC) formalism to the unitary CC formalism. In analogy to the standard single-reference SES-CC formalism, its unitary CC…

The Green's function coupled cluster (GFCC) method is a powerful many-body tool for computing the electronic structure of molecular and periodic systems, especially when electrons of the system are strongly correlated. However, for the GFCC…

Computational Physics · Physics 2019-04-18 Bo Peng , Roel Van Beeumen , David B. Williams-Young , Karol Kowalski , Chao Yang

Downfolding coupled cluster (CC) techniques have recently been introduced into quantum chemistry as a tool for the dimensionality reduction of the many-body quantum problem. As opposed to earlier formulations in physics and chemistry based…

Quantum Physics · Physics 2022-03-23 Nicholas P. Bauman , Karol Kowalski

In this paper we discuss the utilization of Variational Quantum Solver (VQE) and recently introduced Generalized Unitary Coupled Cluster (GUCC) formalism for the diagonalization of downfolded/effective Hamiltonians in active spaces. In…

Quantum Physics · Physics 2020-11-05 Nicholas P. Bauman , Jaroslav Chládek , Libor Veis , Jiří Pittner , Karol Kowalski

In this manuscript, we provide an overview of the recent developments of the coupled cluster (CC) downfolding methods, where the ground-state problem of a quantum system is represented through effective/downfolded Hamiltonians defined using…

Quantum Physics · Physics 2023-03-02 Nicholas P. Bauman , Bo Peng , Karol Kowalski

Applications of quantum simulation algorithms to obtain electronic energies of molecules on noisy intermediate-scale quantum (NISQ) devices require careful consideration of resources describing the complex electron correlation effects. In…

Quantum Physics · Physics 2020-04-17 Mekena Metcalf , Nicholas P. Bauman , Karol Kowalski , Wibe A. de Jong

The recently introduced coupled cluster (CC) downfolding techniques for reducing the dimensionality of quantum many-body problems recast the CC formalism in the form of the renormalization procedure allowing, for the construction of…

Quantum Physics · Physics 2021-11-08 Nicholas P. Bauman , Karol Kowalski

In this work, we combine the recently developed double unitary coupled cluster (DUCC) theory with the adaptive, problem-tailored variational quantum eigensolver (ADAPT-VQE) to explore accuracy of unitary downfolded Hamiltonians for quantum…

Downfolding coupled cluster (CC) techniques are powerful tools for reducing the dimensionality of many-body quantum problems. This work investigates how ground-state downfolding formalisms can target excited states using non-Aufbau…

Chemical Physics · Physics 2023-10-24 Nicholas P. Bauman

In this paper, we evaluate the accuracy of the Hermitian form of the downfolding procedure utilizing the double unitary coupled cluster Ansatz (DUCC) on the H6 and H8 benchmark systems. The computational infrastructure employs the…

Quantum Physics · Physics 2023-05-18 Karol Kowalski , Bo Peng , Nicholas P. Bauman

We adapt the Coupled Cluster Method to solid state strongly correlated lattice Hamiltonians extending the Coupled Cluster linear response method to the calculation of electronic spectra and obtaining the space-time Fourier transforms of…

Strongly Correlated Electrons · Physics 2017-02-16 Alessandro Mirone

The practical application of quantum technologies to chemical problems faces significant challenges, particularly in the treatment of realistic basis sets and the accurate inclusion of electron correlation effects. A direct approach to…

Coupled cluster Green's function (GFCC) calculation has drawn much attention in the recent years for targeting the molecular and material electronic structure problems from a many body perspective in a systematically improvable way.…

Chemical Physics · Physics 2021-04-23 Bo Peng , Ajay Panyala , Karol Kowalski , Sriram Krishnamoorthy

We propose a scheme for the construction of one-particle Green's function (GF) of an interacting electronic system via statistical sampling on a quantum computer. Although the non-unitarity of creation and annihilation operators for the…

Quantum Physics · Physics 2020-02-19 Taichi Kosugi , Yu-ichiro Matsushita

We investigate the performance of Green's function coupled cluster singles and doubles (CCSD) method as a solver for Green's function embedding methods. To develop an efficient CC solver, we construct the one-particle Green's function from…

Strongly Correlated Electrons · Physics 2019-06-11 Avijit Shee , Dominika Zgid

We study the single-band Hubbard model under the action of an external magnetic field using the cumulant Green's functions method (CGFM). The starting point of the method is to diagonalize a cluster containing N correlated sites (seed) and…

Strongly Correlated Electrons · Physics 2023-04-12 Renan Lira , Peter Riseborough , Jereson Silva-Valencia , Marcos Figueira

We show that cluster algorithms for quantum models have a meaning independent of the basis chosen to construct them. Using this idea, we propose a new method for measuring with little effort a whole class of Green's functions, once a…

Statistical Mechanics · Physics 2015-06-25 R. Brower , S. Chandrasekharan , U. -J. Wiese

We formulate a general cluster Dual Fermion Approach to nonlocal correlations in crystals. The scheme allows the treatment of long-range correlations beyond cluster DMFT and nonlocal effects in realistic calculations of multiorbital…

Strongly Correlated Electrons · Physics 2015-05-13 H. Hafermann , S. Brener , A. N. Rubtsov , M. I. Katsnelson , A. I. Lichtenstein

In this paper we analyze new approximations of the Green's function coupled cluster (GFCC) method where locations of poles are improved by extending the excitation level of inner auxiliary operators. These new GFCC approximations can be…

Strongly Correlated Electrons · Physics 2018-12-07 Bo Peng , Karol Kowalski
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