English

Coupled cluster downfolding techniques: a review of existing applications in classical and quantum computing for chemical systems

Quantum Physics 2023-03-02 v1

Abstract

In this manuscript, we provide an overview of the recent developments of the coupled cluster (CC) downfolding methods, where the ground-state problem of a quantum system is represented through effective/downfolded Hamiltonians defined using active spaces. All CC downfolding techniques discussed here are derived from a single-reference exponential ansatz for the ground-state problem. We discuss several extensions of the non-Hermitian and Hermitian downfolding approaches to the time domain and the so-called quantum flows. We emphasize the important role of downfolding formalisms in transitioning chemical applications from noisy quantum devices to scalable and error-corrected quantum computers.

Keywords

Cite

@article{arxiv.2303.00087,
  title  = {Coupled cluster downfolding techniques: a review of existing applications in classical and quantum computing for chemical systems},
  author = {Nicholas P. Bauman and Bo Peng and Karol Kowalski},
  journal= {arXiv preprint arXiv:2303.00087},
  year   = {2023}
}