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We investigated some variational methods to compute a wavefunction based on antisymmetric product of geminals (APG). The Waring decomposition on the APG wavefunction leads a finite sum of antisymmetrized geminal power (AGP) wavefunctions,…

Chemical Physics · Physics 2024-10-10 Airi Kawasaki , Naoki Nakatani

We show how to construct a linearly independent set of antisymmetrized geminal power (AGP) states, which allows us to rewrite our recently introduced geminal replacement models as linear combinations of non-orthogonal AGPs. This greatly…

Chemical Physics · Physics 2021-03-24 Rishab Dutta , Guo P. Chen , Thomas M. Henderson , Gustavo E. Scuseria

In our previous study, we proposed the low-rank antisymmetric product of geminals (APG) method, which reconstructs the wavefunction by extracting only the important eigenvalues from the APG wave function. However, its practical application…

Chemical Physics · Physics 2025-08-19 Airi Kawasaki , Rei Oshima , Naoki Nakatani , Hiromi Nakai

There has been recent interest in the deployment of ab initio density matrix renormalization group computations on high performance computing platforms. Here, we introduce a reformulation of the conventional distributed memory ab initio…

Chemical Physics · Physics 2021-06-24 Huanchen Zhai , Garnet Kin-Lic Chan

The antisymmetrized geminal power (AGP) wavefunction has a long history and is known by different names in various chemical and physical problems. There has been recent interest in using AGP as a starting point for strongly correlated…

Chemical Physics · Physics 2020-09-15 Rishab Dutta , Thomas M. Henderson , Gustavo E. Scuseria

Electronic structure methods typically benefit from symmetry breaking and restoration, specially in the strong correlation regime. The same goes for Ans\"atze on a quantum computer. We develop a unitary coupled cluster method on the…

Quantum Physics · Physics 2022-11-02 Armin Khamoshi , Guo P. Chen , Francesco A. Evangelista , Gustavo E. Scuseria

The antisymmetrized geminal power (AGP) wave function has a long history and considerable conceptual appeal, but in many situations its accuracy is wanting. Here, we consider a form of configuration interaction (CI) based upon the AGP wave…

Chemical Physics · Physics 2020-05-14 Thomas M. Henderson , Gustavo E. Scuseria

We present an efficient implementation of the Density Matrix Renormalization Group (DMRG) algorithm that includes an optimal ordering of the proton and neutron orbitals and an efficient expansion of the active space utilizing various…

Nuclear Theory · Physics 2015-11-18 Ö. Legeza , L. Veis , A. Poves , J. Dukelsky

We propose a new method for computing the eigenvalue decomposition of a dense real normal matrix $A$ through the decomposition of its skew-symmetric part. The method relies on algorithms that are known to be efficiently implemented, such as…

Numerical Analysis · Mathematics 2026-03-31 Simon Mataigne , Kyle A. Gallivan

The Density Matrix Renormalization Group (DMRG) has become a powerful numerical method that can be applied to low-dimensional strongly correlated fermionic and bosonic systems. It allows for a very precise calculation of static, dynamical…

Condensed Matter · Physics 2007-05-23 Karen Hallberg

We apply the density matrix renormalization group (DMRG) method to a non-equilibrium problem: the asymmetric exclusion process in one dimension. We study the stationary state of the process to calculate the particle density profile…

Statistical Mechanics · Physics 2009-10-30 Yasuhiro Hieida

The density-matrix renormalization group (DMRG) is a numerical algorithm for the efficient truncation of the Hilbert space of low-dimensional strongly correlated quantum systems based on a rather general decimation prescription. This…

Strongly Correlated Electrons · Physics 2009-11-10 Ulrich Schollwoeck

The Density Matrix Renormalization Group (DMRG) has become a powerful numerical method that can be applied to low-dimensional strongly correlated fermionic and bosonic systems. It allows for a very precise calculation of static, dynamic and…

Condensed Matter · Physics 2007-05-23 Karen Hallberg

In this paper we introduce the algorithm and the fixed point hardware to calculate the normalized singular value decomposition of a non-symmetric matrices using Givens fast (approximate) rotations. This algorithm only uses the basic…

Numerical Analysis · Computer Science 2017-07-18 Ehsan Rohani , Gwan Choi , Mi Lu

The generalized density matrix (GDM) method is used to calculate microscopically the parameters of the collective Hamiltonian. Higher order anharmonicities are obtained consistently with the lowest order results, the mean field…

Nuclear Theory · Physics 2011-09-23 L. Y. Jia

Positive semi-definite matrices commonly occur as normal matrices of least squares problems in statistics or as kernel matrices in machine learning and approximation theory. They are typically large and dense. Thus algorithms to solve…

Numerical Analysis · Mathematics 2020-12-01 Markus Hegland , Frank deHoog

In previous research, we tested the wave function format of a linear combination of several antisymmetrized geminal power states. A numerical problem in the geminal matrices was noted, which made the total energies of electronic systems…

Chemical Physics · Physics 2019-02-06 Wataru Uemura , Takahito Nakajima

We extend the active space decomposition method, recently developed by us, to more than two active sites using the density matrix renormalization group algorithm. The fragment wave functions are described by complete or restricted…

Chemical Physics · Physics 2014-12-09 Shane M. Parker , Toru Shiozaki

In this paper, we develop a polynomial time algorithm to compute a Dulmage-Mendelsohn-type decomposition of a matrix partitioned into submatrices of rank at most $1$.

Combinatorics · Mathematics 2018-02-20 Hiroshi Hirai

A biorthonormal-block density-matrix renormalization group algorithm is proposed to accurately compute properties of large-scale non-Hermitian many-body systems, in which a renormalized-space partition of the non-Hermitian reduced density…

Strongly Correlated Electrons · Physics 2025-07-08 Peigeng Zhong , Wei Pan , Haiqing Lin , Xiaoqun Wang , Shijie Hu
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