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The density matrix renormalization group (DMRG) method generates the low-energy states of linear systems of $N$ sites with a few degrees of freedom at each site by starting with a small system and adding sites step by step while keeping…

Strongly Correlated Electrons · Physics 2016-10-05 Manoranjan Kumar , Dayasindhu Dey , Aslam Parvej , S. Ramasesha , Zoltán G. Soos

The Density Matrix Renormalization Group (DMRG) algorithm is a powerful tool for solving eigenvalue problems to model quantum systems. DMRG relies on tensor contractions and dense linear algebra to compute properties of condensed matter…

Distributed, Parallel, and Cluster Computing · Computer Science 2021-01-26 Ryan Levy , Edgar Solomonik , Bryan K. Clark

We propose a new numerical algorithm for computing the tensor rank decomposition or canonical polyadic decomposition of higher-order tensors subject to a rank and genericity constraint. Reformulating this computational problem as a system…

Numerical Analysis · Mathematics 2024-07-02 Simon Telen , Nick Vannieuwenhoven

We introduce the density matrix renormalization group (DMRG) method as an efficient computational tool for one-exciton approximations with off-diagonal disorder. This method allows us to reduce the computational effort by targetting only a…

Strongly Correlated Electrons · Physics 2007-05-23 M. A. Martin-Delgado , J. Rodriguez-Laguna , G. Sierra

We present the asymptotically fastest known algorithms for some basic problems on univariate polynomial matrices: rank, nullspace, determinant, generic inverse, reduced form. We show that they essentially can be reduced to two computer…

Symbolic Computation · Computer Science 2007-05-23 Claude-Pierre Jeannerod , Gilles Villard

We investigate the use of invariant polynomials in the construction of data-driven interatomic potentials for material systems. The "atomic body-ordered permutation-invariant polynomials" (aPIPs) comprise a systematic basis and are…

Computational Physics · Physics 2019-10-15 Cas van der Oord , Geneviève Dusson , Gabor Csanyi , Christoph Ortner

We develop an accelerated gradient descent algorithm on the Grassmann manifold to compute the subspace spanned by a number of leading eigenvectors of a symmetric positive semi-definite matrix. This has a constant cost per iteration and a…

Optimization and Control · Mathematics 2024-06-27 Foivos Alimisis , Simon Vary , Bart Vandereycken

The accurate but expensive product of geminals ansatz may be approximated by a geminal power, but this approach sacrifices size consistency. Here we show both analytically and numerically that a size consistent form very similar to the…

Strongly Correlated Electrons · Physics 2012-11-19 Eric Neuscamman

The density-matrix renormalization group (DMRG) method, which can deal with a large active space composed of tens of orbitals, is nowadays widely used as an efficient addition to traditional complete active space (CAS)-based approaches. In…

Strongly Correlated Electrons · Physics 2016-11-06 Yingjin Ma , Jing Wen , Haibo Ma

Algebraic Multigrid (AMG) methods are often robust and effective solvers for solving the large and sparse linear systems that arise from discretized PDEs and other problems, relying on heuristic graph algorithms to achieve their…

Numerical Analysis · Mathematics 2023-08-23 Tareq Zaman , Nicolas Nytko , Ali Taghibakhshi , Scott MacLachlan , Luke Olson , Matthew West

Single-reference methods such as Hartree-Fock-based coupled cluster theory are well known for their accuracy and efficiency for weakly correlated systems. For strongly correlated systems, more sophisticated methods are needed. Recent…

Strongly Correlated Electrons · Physics 2021-02-23 Armin Khamoshi , Guo P. Chen , Thomas M. Henderson , Gustavo E. Scuseria

We propose Matrix ALPS for recovering a sparse plus low-rank decomposition of a matrix given its corrupted and incomplete linear measurements. Our approach is a first-order projected gradient method over non-convex sets, and it exploits a…

Information Theory · Computer Science 2012-06-22 Anastasios Kyrillidis , Volkan Cevher

We first propose a concise singular value decomposition of dual matrices. Then, the randomized version of the decomposition is presented. It can significantly reduce the computational cost while maintaining the similar accuracy. We analyze…

Numerical Analysis · Mathematics 2024-07-25 Mengyu Wang , Jingchun Zhou , Hanyu Li

Herein, we report accurate atomization energy calculations for 55 molecules in the Gaussian-2 (G2) set using lattice regularized diffusion Monte Carlo (LRDMC). We compare the Jastrow-Slater determinant ansatz with a more flexible JsAGPs…

Chemical Physics · Physics 2023-04-19 Abhishek Raghav , Ryo Maezono , Kenta Hongo , Sandro Sorella , Kousuke Nakano

Given a random quantum state of multiple distinguishable or indistinguishable particles, we provide an effective method, rooted in symplectic geometry, to compute the joint probability distribution of the eigenvalues of its one-body reduced…

Quantum Physics · Physics 2014-10-21 Matthias Christandl , Brent Doran , Stavros Kousidis , Michael Walter

The presence of many degenerate $d/f$ orbitals makes polynuclear transition metal compounds such as iron-sulfur clusters in nitrogenase challenging for state-of-the-art quantum chemistry methods. To address this challenge, we present the…

Chemical Physics · Physics 2023-12-22 Chunyang Xiang , Weile Jia , Wei-Hai Fang , Zhendong Li

The Density Matrix Renormalization Group (DMRG) algorithm has been a rising star for the accurate ab initio exploration of Born-Oppenheimer potential energy surfaces in theoretical chemistry. However, owing to its iterative numerical…

Chemical Physics · Physics 2014-05-13 Sebastian F. Keller , Markus Reiher

The purpose of this paper is (i) to present a generic and fully functional implementation of the density-matrix renormalization group (DMRG) algorithm, and (ii) to describe how to write additional strongly-correlated electron models and…

Strongly Correlated Electrons · Physics 2015-05-13 G. Alvarez

The damped Gauss-Newton (dGN) algorithm for CANDECOMP/PARAFAC (CP) decomposition can handle the challenges of collinearity of factors and different magnitudes of factors; nevertheless, for factorization of an $N$-D tensor of size $I_1\times…

Numerical Analysis · Computer Science 2015-03-20 Anh Huy Phan , Petr Tichavský , Andrzej Cichocki

We give an efficient algorithm which can obtain a relative error approximation to the spectral norm of a matrix, combining the power iteration method with some techniques from matrix reconstruction which use random sampling.

Data Structures and Algorithms · Computer Science 2011-04-13 Malik Magdon-Ismail