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With infrared and terahertz ellipsometry we investigated the anisotropy of the infrared active phonon modes in SrTiO3 (110) single crystals in the tetragonal state below the so-called antiferrodistortive transition at T* = 105 K. In…

Materials Science · Physics 2017-01-06 M. Yazdi-Rizi , P. Marsik , B. P. P. Mallett , C. Bernhard

We apply a generalized model for the determination and analysis of the dielectric function of optically anisotropic materials with colour dispersion to phonon modes and show that it can also be generalized to excitonic polarizabilities and…

We measured the Raman and the Infrared phonon spectrum of SmFeAsO polycrystalline samples. We also performed Density Functional Theory calculations within the pseudopotential approximation to obtain the structural and dynamical lattice…

We calculate the lattice dielectric function of strongly anharmonic rutile $\mathrm{TiO}_2$ from ab initio anharmonic lattice dynamics methods. Since an accurate calculation of the $\Gamma$ point phonons is essential for determining optical…

Materials Science · Physics 2023-03-24 Tomohito Amano , Tamio Yamazaki , Ryosuke Akashi , Terumasa Tadano , Shinji Tsuneyuki

The lattice dynamics of Ba$_2$CuGe$_2$O$_7$, a compound which develops Dzyaloshinsky-Moriya (DM) helical magnetism below $T_N$ = 3.2 K, has been studied by measuring the infrared reflectivity of a single crystal with the radiation polarized…

The phonon mode parameters and anisotropic mid-infrared dielectric function tensor components of high- Al-content Al$_x$Ga$_{1-x}$N alloys in dependence of the Al content $x$ are precisely determined from mid-infrared spectroscopic…

Structural and electronic properties of CaCu{3}Ti{4}O{12} have been calculated using density-functional theory within the local spin-density approximation. After an analysis of structural stability, zone-center optical phonon frequencies…

Materials Science · Physics 2009-11-07 Lixin He , J. B. Neaton , Morrel H. Cohen , David Vanderbilt , C. C. Homes

We report on polarized infrared reflectivity measurements of multiferroic, monoclinic MnWO4 between 10K and 295K. The full dielectric tensor and the frequency dependence of the orientation of the principal axes have been determined in the…

Strongly Correlated Electrons · Physics 2014-10-08 T. Möller , P. Becker , L. Bohaty , J. Hemberger , M. Grüninger

Micromechanically exfoliated mono- and multilayers of molybdenum disulfide (MoS2) are investigated by spectroscopic imaging ellipsometry. In combination with knife edge illumination, MoS2 flakes can be detected and classified on arbitrary…

Mesoscale and Nanoscale Physics · Physics 2016-11-17 S. Funke , B. Miller , E. Parzinger , P. Thiesen , A. W. Holleitner , U. Wurstbauer

We report the complex dielectric function along and perpendicular to the IrO2 planes in the layered perovskite Sr2IrO4 determined by spectroscopic ellipsometry in the spectral range from 12 meV to 6 eV. Thin high quality single crystals…

Strongly Correlated Electrons · Physics 2016-08-24 D. Pröpper , A. N. Yaresko , M. Höppner , Y. Matiks , Y. -L. Mathis , T. Takayama , A. Matsumoto , H. Takagi , B. Keimer , A. V. Boris

Anharmonic effects in an atomic monolayer thin crystal with honeycomb lattice structure are investigated by analytical and numerical lattice dynamical methods. Starting from a semi-empirical model for anharmonic couplings of third and…

Materials Science · Physics 2015-05-20 K. H. Michel , S. Costamagna , F. M. Peeters

Intrinsic electron- and hole-phonon interactions are investigated in monolayer transition metal dichalcogenides MX$_2$ (M=Mo,W; X=S,Se) based on a density functional theory formalism. Due to their structural similarities, all four materials…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 Zhenghe Jin , Xiaodong Li , Jeffrey Thomas Mullen , Ki Wook Kim

From an investigation of the optical conductivity of FeSi single crystals using FTIR spectroscopy in the frequency range from 30 to 20000 wavenumbers we conclude that the transverse effective charge of the Fe and Si ions is approximately…

Strongly Correlated Electrons · Physics 2009-10-28 A. Damascelli , K. Schulte , D. van der Marel , A. A. Menovsky

We have investigated crystal field and phonon dynamics of the multiferroic orthoferrite DyFeO$_3$ via polarized infrared spectroscopy. Reflectance of single crystals was measured in the far- to mid-infrared spectral range at range of…

Strongly Correlated Electrons · Physics 2013-02-14 A. D. LaForge , J. Whalen , T. Siegrist , A. P. Ramirez , Z. Schlesinger

We determine the anisotropic dielectric functions of rhombohedral $\alpha$-Ga$_2$O$_3$ by far-infrared and infrared generalized spectroscopic ellipsometry and derive all transverse optical and longitudinal optical phonon mode frequencies…

We present a study of the lattice dynamical properties of superconducting SrPt$_3$P ($T_c = 8.4$ K) via high-resolution inelastic x-ray scattering (IXS) and ab initio calculations. Density functional perturbation theory including spin-orbit…

Superconductivity · Physics 2016-01-20 D. A. Zocco , S. Krannich , R. Heid , K. -P. Bohnen , T. Wolf , T. Forrest , A. Bossak , F. Weber

The electron-phonon interaction and related transport properties are investigated in monolayer silicene and MoS2 by using a density functional theory calculation combined with a full-band Monte Carlo analysis. In the case of silicene, the…

Mesoscale and Nanoscale Physics · Physics 2015-06-12 Xiaodong Li , Jeffrey T. Mullen , Zhenghe Jin , Kostyantyn M. Borysenko , M. Buongiorno Nardelli , Ki Wook Kim

The anharmonic behavior of phonons and intrinsic thermal conductivity associated with the Umklapp scattering in monolayer MoS2 sheet are investigated via first-principles calculations within the framework of density functional perturbation…

Materials Science · Physics 2015-06-18 Yongqing Cai , Jinghua Lan , Gang Zhang , Yong-Wei Zhang

We have investigated the structural and dielectric properties of Sr$_{2}$TiO$_{4}$,the first member of the Sr$_{n+1}$Ti$_{n}$O$_{3n+1}$ Ruddlesden-Popper series, within density functional theory. Motivated by recent work in which thin films…

Materials Science · Physics 2009-11-10 Craig J. Fennie , Karin M. Rabe

We use a combined generalized spectroscopic ellipsometry and density functional theory approach to determine and analyze the anisotropic dielectric functions of an $\alpha$-Ga$_2$O$_3$ thin film. The sample is grown epitaxially by…