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We determine the frequency dependence of the four independent Cartesian tensor elements of the dielectric function for monoclinic symmetry Y$_2$SiO$_5$ using generalized spectroscopic ellipsometry from 40-1200 cm$^{-1}$. Three different…

Materials Science · Physics 2018-04-25 A. Mock , R Korlacki , S. Knight , M. Schubert

We derive a dielectric function tensor model approach to render the optical response of monoclinic and triclinic symmetry materials with multiple uncoupled infrared and farinfrared active modes. We apply our model approach to monoclinic…

We determine the frequency dependence of four independent CdWO$_4$ Cartesian dielectric function tensor elements by generalized spectroscopic ellipsometry within mid-infrared and far-infrared spectral regions. Single crystal surfaces cut…

Materials Science · Physics 2017-04-26 A. Mock , R. Korlacki , S. Knight , M. Schubert

The anisotropic complex dielectric response was accurately extracted from spectroscopic ellipsometry measurements at phonon frequencies for the three principal crystallographic directions of an orthorhombic (Pbnm) YTiO_3 single crystal. We…

Strongly Correlated Electrons · Physics 2009-11-13 N. N. Kovaleva , A. V. Boris , L. Capogna , J. L. Gavartin , P. Popovich , P. Yordanov , A. Maljuk , A. M. Stoneham , B. Keimer

A complete set of all optical phonon modes predicted by symmetry for bixbyite structure indium oxide is reported here from a combination of far-infrared and infrared spectroscopic ellipsometry, as well as first principle calculations.…

Using a combination of infrared ellipsometry, time-domain terahertz spectroscopy, and far-infrared reflectometry we have obtained the $ac$-plane complex dielectric function of monoclinic ($C2/c$) Ta$_2$NiSe$_5$ and orthorhombic ($Cmcm$)…

Strongly Correlated Electrons · Physics 2018-09-12 T. I. Larkin , R. D. Dawson , M. Höppner , T. Takayama , M. Isobe , Y. -L. Mathis , H. Takagi , B. Keimer , A. V. Boris

Reflection and transmission as a function of temperature (5--300 K) have been measured on single crystals of the multiferroic compound FeTe$_{2}$O$_{5}$Br utilizing light spanning the far infrared to the visible portions of the…

Strongly Correlated Electrons · Physics 2015-06-12 K. H. Miller , X. S. Xu , H. Berger , V. Craciun , X. Xi , C. Martin , G. L. Carr , D. B. Tanner

We present a broad band (THz to UV) ellipsometry study of the anisotropic dielectric response of the orthorhombic perovskite YAlO3. The ellipsometric measurements have been performed on YAlO3 crystals with three different surface cuts and…

Materials Science · Physics 2025-11-18 Laurent Bugnon , Christian Bernhard , Premysl Marsik

We use the density functional theory and lattice dynamics calculations to investigate the properties of potassium superoxide KO$_2$ in which spin, orbital, and lattice degrees of freedom are interrelated and determine the low-temperature…

We report on the structural and spectroscopic characterization of the multiferroic Fe$_2$Mo$_3$O$_8$. Synchrotron x-ray and neutron diffraction, as well as thermal expansion measurements reveal a lattice anomaly at $T_{\mathrm{N}}\simeq…

Strongly Correlated Electrons · Physics 2020-09-28 S. Reschke , A. A. Tsirlin , N. Khan , L. Prodan , V. Tsurkan , I. Kézsmárki , J. Deisenhofer

We have performed a first-principles study of the structural and vibrational properties of the three low-pressure (cubic, tetragonal, and especially monoclinic) phases of ZrO2, with special attention to the computation of the zone-center…

Materials Science · Physics 2009-11-07 Xinyuan Zhao , David Vanderbilt

Monoclinic $\beta$-Ga$_2$O$_3$ films grown on $c$-plane sapphire have been shown to exhibit six $(\bar{2}01)$-plane oriented domains, which are equally-spaced-by-rotation around the surface normal and equally-sized-by-volume that render the…

Optical properties of single-crystal monoclinic CuO in the range 70 - 6000 \cm were studied at temperatures from 7 to 300 K. Normal reflection spectra were obtained from the (001) and (010) crystal faces thus giving for the first time…

Strongly Correlated Electrons · Physics 2009-10-31 A. B. Kuz'menko , D. van der Marel , P. J. M. van Bentum , E. A. Tishchenko , C. Presura , A. A. Bush

The phonon dynamics of LiV2O5 single crystals is studied using infrared and Raman spectroscopy techniques. The infrared-active phonon frequencies and dielectric constants are obtained by oscillator fitting procedure of the reflectivity data…

Strongly Correlated Electrons · Physics 2009-10-31 Z. V. Popovic , R. Gajic , M. J. Konstantinovic , R. Provoost , V. V. Moshchalkov , A. N. Vasil'ev , M. Isobe , Y. Ueda

We use density functional theory to calculate the electronic band structures, cohesive energies, phonon dispersions, and optical absorption spectra of two-dimensional In$_2$X$_2$ crystals, where X is S, Se, or Te. We identify two…

Mesoscale and Nanoscale Physics · Physics 2014-09-19 V. Zolyomi , N. D. Drummond , V. I. Fal'ko

Ternary compounds of Transition Metal Dichalcogenides are emerging as an interesting class of crystals with tunable electronic properties, which make them attractive for nano-electronic and optoelectronic applications. Among them,…

Reflection and transmission as a function of temperature have been measured on a single crystal of the magnetoelectric ferrimagnetic compound Cu$_{2}$OSeO$_{3}$ utilizing light spanning the far infrared to the visible portions of the…

Materials Science · Physics 2015-05-19 K. H. Miller , X. S. Xu , H. Berger , E. S. Knowles , D. J. Arenas , M. W. Meisel , D. B. Tanner

Ilmenite-type crystals find a variety of technological applications due to their intriguing physical properties. We present the results of the lattice dynamics studies of honeycomb antiferromagnetic ilmenite CoTiO$_3$ single crystal by the…

Near normal incident far-infrared reflectivity spectra of [111] dysprosium titanate (Dy2Ti2O4) single crystal have been measured at different temperatures. Seven phonon modes (eight at low temperature) are identified at frequency below 1000…

Materials Science · Physics 2009-11-11 C. Z. Bi , J. Y. Ma , B. R. Zhao , Z. Tang , D. Yin , C. Z. Li , D. Z. Yao , J. Shi , X. G. Qiu

In this study, we present a comprehensive analysis of the Raman active phonon modes in orthorhombic LaInO$_3$ based on a combination of polarization-angle resolved Raman spectroscopy and density functional theory calculations. By using…

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