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Related papers: Negative thermal expansion in CdSe quasi-two-dimen…

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The phenomenon of negative thermal expansion (NTE) deals with the increase of the lattice parameters and the volume of the unit cell when the material is thermally cooled. The NTE is typically associated with thermal phonons and anomalous…

Strongly Correlated Electrons · Physics 2023-03-10 Wojciech Brzezicki , Filomena Forte , Canio Noce , Mario Cuoco , Andrzej M. Oleś

Recently, huge uniaxial negative thermal expansion (NTE) along a $c$-axis has been observed in transition-metal ($Tr$) zirconides $Tr$Zr$_{2}$ with a tetragonal CuAl$_{2}$-type structure. In a recent study on FeZr$_{2}$ [M. Xu et al., Nat.…

Critical thermoelectric parameters including Seebeck coefficient, electrical conductivity, thermal conductivity and figure of merit ZT of one-dimensional coaxial Bi2Te3/Sb2Te3 nanocomposite were modeled by following the single carrier…

Materials Science · Physics 2011-01-31 Qilin Gu

ZnSe nanowire heterostructures were grown by molecular beam epitaxy in the vapour-liquid-solid growth mode assisted by gold catalysts. Size, shape and crystal structure are found to strongly depend on the growth conditions. Both,…

We use a symmetry-motivated approach to analysing X-ray pair distribution functions to study the mechanism of negative thermal expansion in two ReO$_3$-like compounds; ScF$_3$ and CaZrF$_6$. Both average and local structure suggest that it…

Materials Science · Physics 2020-02-26 Tobias Bird , Jessica Woodland-Scott , Lei Hu , Michael Wharmby , Jun Chen , Andrew Goodwin , Mark Senn

Tailoring the thermal expansion of martensitic materials by crystallographic texture and anisotropic variation of lattice parameters is a promising route to a flexible design of thermally stable systems. NiTi alloys are prototype materials…

Unique zero thermal expansion (ZTE) materials are valuable for use in precision instruments, including electronics, aerospace parts, and engines. However, most ZTE materials have a temperature range less than 1000 K under which they do not…

Materials Science · Physics 2025-01-15 Chi-Hung Lee , Cheng-Yen Lin , Guan-Yu Chen

This study explores the relationship between phonon dynamics and negative thermal expansion (NTE) in Cu$_x$Ni$_{2-x}$(CN)$_4$. The partial replacement of nickel (II) by copper (II) in Ni(CN)$_2$ leads to a line phase, CuNi(CN)$_4$ (x = 1),…

Materials Science · Physics 2019-10-02 Stella d'Ambrumenil , Mohamed Zbiri , Ann Chippindale , Simon Hibble

We study the band-edge exciton fine structure and in particular its bright-dark splitting in colloidal semiconductor nanocrystals by four different optical methods based on fluorescence line narrowing and time-resolved measurements at…

We investigate detailed lattice dynamics of copper halides CuX (X=Cl, Br, I) using neutron inelastic scattering measurements and ab-initio calculations aimed at a comparative study of their thermal expansion behavior. We identify the low…

Materials Science · Physics 2017-06-07 Abhijith M. Gopakumar , M. K. Gupta , R. Mittal , S. Rols , S. L. Chaplot

Luminescent colloidal CdSe nanorings are a new type of semiconductor structure that have attracted interest due to the potential for unique physics arising from their non-trivial toroidal shape. However, the exciton properties and dynamics…

The role of the sublimation of the compound and of the evaporation of the constituents from the gold nanoparticle during the growth of semiconductor nanowires is exemplified with CdTe-ZnTe heterostructures. Operating close to the upper…

Semiconductor nanoplatelets possess exceptional optical properties that make them promising candidates for next-generation optoelectronic applications. However, unlike quantum dots where absorption spectroscopy alone can determine both size…

In this work, we show that the CuAl2-type superconductor CoZr2 and alloyed systems exhibit anomalous thermal expansion in a wide temperature range. We performed neutron powder diffraction and X-ray powder diffraction on CoZr2 and observed…

Materials Science · Physics 2022-09-23 Yoshikazu Mizuguchi , Md. Riad Kasem , Yoichi Ikeda

The structural dynamics of a 1D mixed-metal cyanide, Cu$_{1/3}$Ag$_{1/3}$Au$_{1/3}$CN, with intriguing thermal properties is explored. All the current known related compounds with straight-chain structures, such as CuCN, AgCN, AuCN and…

Thin films of CdTe were deposited on glass substrates by thermal evaporation. From the XRD measurements itis found that the films are of zinc-blende-type structure. Transmittance, absorption, extinction, and refractive coefficients are…

Materials Science · Physics 2009-11-11 S. Lalitha , S. Zh. Karazhanov , P. Ravindran , S. Senthilarasu , R. Sathyamoorthy , J. Janabergenov

Colloidal nanoplatelets - quasi-two-dimensional sheets of semiconductor exhibiting efficient, spectrally pure fluorescence - form when liquid-phase syntheses of spherical quantum dots are modified. Despite intense interest in their…

The thermal expansion coefficients of $\mathrm{Na}_{N}$ clusters with $8 \le N \le 40$ and $\mathrm{Al}_{7}$, $\mathrm{Al}_{13}^-$ and $\mathrm{Al}_{14}^-$ are obtained from {\it ab initio} Born-Oppenheimer LDA molecular dynamics. Thermal…

Atomic and Molecular Clusters · Physics 2009-11-06 S. Kümmel , J. Akola , M. Manninen

Previous experiments and numerical simulations have revealed that a limited number of two- and three-dimensional particle systems contract in volume upon heating isobarically. This anomalous phenomenon is known as negative thermal expansion…

Soft Condensed Matter · Physics 2025-07-21 Igor Travěnec , Ladislav Šamaj

A numerical study is performed to estimate thermal load on the nozzle base plate, which is in the upstream direction to the flow, from three hot plumes of pure (CO2), (H2O) and 50-50 (%) composition of (CO2) and (H2O) expanding through a…

Computational Physics · Physics 2023-01-13 Kamal Khemani , Pradeep Kumar , Ganesh Natarajan