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Simulations that couple different classical molecular models in an adaptive way by changing the number of degrees of freedom on the fly, are available within reasonably consistent theoretical frameworks. The same does not occur when it…

Soft Condensed Matter · Physics 2015-05-18 A. B. Poma , L. Delle Site

Instanton theory has arisen as a practical tool for calculating tunneling splittings in molecular systems. Unfortunately, the original formulation of instanton theory fundamentally breaks down when trying to calculate the level splitting in…

Chemical Physics · Physics 2025-10-31 Marit R. Fiechter , Gabriel Laude , Jeremy O. Richardson

A solution to the classical field equations in the massless (1+1)-dimensional O(3) sigma model is found, which describes a multi-particle instanton-like transition at high energy. In the limit of small number of initial particles, the…

High Energy Physics - Phenomenology · Physics 2007-05-23 V. A. Rubakov , D. T. Son , P. G. Tinyakov

The spin coherent state path integral describing the dynamics of a spin-1/2-system in a magnetic field of arbitrary time-dependence is considered. Defining the path integral as the limit of a Wiener regularized expression, the semiclassical…

Quantum Physics · Physics 2008-11-26 Adrian Alscher , Hermann Grabert

We derive a stochastic path integral representation of counting statistics in semi-classical systems. The formalism is introduced on the simple case of a single chaotic cavity with two quantum point contacts, and then further generalized to…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 S. Pilgram , A. N. Jordan , E. V. Sukhorukov , M. Buttiker

Essential properties of semiclassical approximation for quantum mechanics are viewed as axioms of an abstract semiclassical mechanics. Its symmetry properties are discussed. Semiclassical systems being invariant under Lie groups are…

Mathematical Physics · Physics 2009-11-07 Oleg Yu. Shvedov

The decay rate for a particle in a metastable cubic potential is investigated in the quantum regime by the Euclidean path integral method in semiclassical approximation. The imaginary time formalism allows one to monitor the system as a…

Statistical Mechanics · Physics 2008-04-22 Marco Zoli

Constructing an accurate approximation to nonadiabatic rate theory which is valid for arbitrary values of the electronic coupling has been a long-standing challenge in theoretical chemistry. Ring-polymer instanton theories offer a very…

Chemical Physics · Physics 2025-05-09 Rhiannon A. Zarotiadis , Joseph E. Lawrence , Jeremy O. Richardson

We present a general quantum instanton approach to calculating reaction rates for systems with two electronic states and arbitrary values of the electronic coupling. This new approach, which we call the non-adiabatic quantum instanton…

Chemical Physics · Physics 2020-05-29 Joseph E. Lawrence , David E. Manolopoulos

Semiclassical periodic orbit theory is used in many branches of physics. However, most applications of the theory have been to systems which involve only single particle dynamics. In this work, we develop a semiclassical formalism to…

Chaotic Dynamics · Physics 2009-10-31 Jamal Sakhr , Niall D. Whelan

We describe a quantum perturbative approach to evaluating the phase shift of an atom interferometer in a weakly anharmonic trap. This provides a simple way to evaluate quantum corrections to the standard semi-classical approximation. The…

Quantum Physics · Physics 2025-03-21 W. LaRow , M. Edwards , C. A. Sackett

We construct a field theory to describe energy averaged quantum statistical properties of systems which are chaotic in their classical limit. An expression for the generating function of general statistical correlators is presented in the…

Condensed Matter · Physics 2009-10-28 A. V. Andreev , B. D. Simons , O. Agam , B. L. Altshuler

We present a quantum averaging theory (QAT) for analytically modeling unitary gate dynamics in driven quantum systems beyond the rotating-wave approximation. QAT addresses the simultaneous presence of distinct timescales by generating a…

Quantum Physics · Physics 2026-01-05 Kristian D. Barajas , Wesley C. Campbell

Conventional scattering theory is incomplete in that it does not adequately describe the behaviour of the wave function at macroscopic distances from the scattering reaction volume. In scattering experiments particles are incident from…

Quantum Physics · Physics 2021-10-05 John S. Briggs , James M. Feagin

The momentum transfer between the normal components to an index direction in the collision of an atom with a periodic surface is investigated. For fast atoms with grazing angle of incidence there is an interval of azimuthal angles around…

Quantum Physics · Physics 2009-05-05 Antonia Ruiz , Jose P. Palao , Eric J. Heller

Thermal escape out of a metastable well is considered in the weak friction regime, where the bottleneck for decay is energy diffusion, and at lower temperatures, where quantum tunneling becomes relevant. Within a systematic semiclassical…

Statistical Mechanics · Physics 2015-05-13 Alvise Verso , Joachim Ankerhold

While there does not at this time exist a complete canonical theory of full 3+1 quantum gravity, there does appear to be a satisfactory canonical quantization of minisuperspace models. The method requires no `choice of time variable' and…

General Relativity and Quantum Cosmology · Physics 2011-09-09 Donald Marolf

The validity of the semiclassical approximation is investigated during the preheating phase in models of chaotic inflation using a modification of a criterion previously proposed for semiclassical gravity. If the modified criterion is…

General Relativity and Quantum Cosmology · Physics 2015-10-28 Paul R. Anderson , Carmen Molina-Paris , Dillon H. Sanders

Semiclassical methods provide important tools for approximating solutions in quantum mechanics. In several cases these methods are intriguingly exact rather than approximate, as has been shown by direct calculations on particular systems.…

Quantum Physics · Physics 2021-08-11 Asim Gangopadhyaya , Jonathan Bougie , Constantin Rasinariu

We study the decay of survival probability at quantum phase transitions (QPT). The semiclassical theory is found applicable in the vicinities of critical points with infinite degeneracy. The theory predicts a power law decay of the survival…

Quantum Physics · Physics 2015-05-13 Wen-ge Wang , Pinquan Qin , Lewei He , Ping Wang
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