Related papers: New study of the line profiles of sodium perturbed…
Ultracool stellar atmospheres show absorption by alkali resonance lines severely broadened by collisions with neutral perturbers. In the coolest and densest atmospheres, such as those of T dwarfs, Na I and K I broadened by molecular…
Collision broadening by molecular hydrogen of sodium and potassium is one of the major broadening mechanisms in the atmospheres of brown dwarf stars and exoplanets at an effective temperature of about 1000K. The accurate computation of line…
At the low temperatures achieved in cool brown dwarf and hot giant planet atmospheres, the less refractory neutral alkali metals assume an uncharacteristically prominent role in spectrum formation. In particular, the wings of the Na-D (5890…
Transit spectroscopy of terrestrial planets around nearby M dwarfs is a primary goal of space missions in coming decades. 3-D climate modeling has shown that slow-synchronous rotating terrestrial planets may develop thick clouds at the…
Ultracool stellar atmospheres show absorption by alkali resonance lines severely broadened by collisions with neutral perturbers. In the coolest and densest atmospheres, such as those of T dwarfs, Na I and K I broadened by molecular…
We develop a new 1D photochemical kinetics code to address stratospheric chemistry and stratospheric heating in hot Jupiters. Here we address optically active S-containing species and CO2 at 1200 < T < 2000 K. HS (mercapto) and S2 are…
We present and validate a new network of atmospheric thermo-chemical and photo-chemical sulfur reactions. We use a 1-D chemical kinetics model to investigate these reactions as part of a broader HCNO chemical network in a series of hot and…
The atmospheric pressure-temperature profiles for transiting giant planets cross a range of chemical transitions. Here we show that the particular shape of these irradiated profiles for warm giant planets below 1300 K lead to striking…
We report on our new calculations of unified line profiles of K perturbed by He using ab initio potential data for the conditions prevailing in cool substellar brown dwarfs and hot dense planetary atmospheres with temperatures from…
Ultra-hot Jupiters (UHJs) have recently been the focus of several atmospheric studies due to their extreme properties. While molecular hydrogen (H$_2$) plays a key role in UHJ atmospheres, it has not been directly detected on an exoplanet.…
Studies of the atmospheres of hot Jupiters reveal a diversity of atmospheric composition and haze properties. Similar studies on individual smaller, temperate planets are rare due to the inherent difficulty of the observations and also to…
The high cosmic abundance and the intermediate volatility and chemical properties of sulfur allow the use of sulfur-bearing species as a tracer of the chemical processes in the atmospheres of hot Jupiter exoplanets. Nevertheless, despite…
Interior models of gas giants in the Solar System traditionally assume a fully convective molecular hydrogen envelope. However, recent observations from the Juno mission suggest a possible depletion of alkali metals in Jupiter's molecular…
We use a 1D thermochemical and photochemical kinetics model to predict the disequilibrium stratospheric chemistries of warm and hot Jupiters (800 < T < 1200 K). Thermal chemistry and vertical mixing are generally more important than…
Brown dwarfs are essential targets for understanding planetary and sub-stellar atmospheres across a wide range of thermal and chemical conditions. As surveys continue to probe ever deeper, and as observing capabilities continue to improve,…
The coldest Y spectral type brown dwarfs are similar in mass and temperature to cool and warm ($\sim$200 -- 400 K) giant exoplanets. We can therefore use their atmospheres as proxies for planetary atmospheres, testing our understanding of…
As brown dwarfs cool, a variety of species condense in their atmospheres, forming clouds. Iron and silicate clouds shape the emergent spectra of L dwarfs, but these clouds dissipate at the L/T transition. A variety of other condensates are…
The formation of clouds affects brown dwarf and planetary atmospheres of nearly all effective temperatures. Iron and silicate condense in L dwarf atmospheres and dissipate at the L/T transition. Minor species such as sulfides and salts…
K2-18b, a sub-Neptune orbiting in the habitable zone of an M dwarf, has attracted significant interest following observations with the Hubble Space Telescope (HST) and, more recently, with the James Webb Space Telescope (JWST) that reveal…
Most of the molecules detected thus far in exoplanet atmospheres, such as water and CO, are present for a large range of pressures and temperatures. In contrast, metal hydrides exist in much more specific regimes of parameter space, and so…