Related papers: H$_2$ ortho-para spin conversion on inhomogeneous …
We have developed a model for molecular hydrogen formation under astrophysically relevant conditions. This model takes fully into account the presence of both physisorbed and chemisorbed sites on the surface, allows quantum mechanical…
A comprehensive phase diagram of lowest-energy structures and compositions of the rutile TiO_2(110) surface in equilibrium with a surrounding gas phase at finite temperatures and pressures has been determined using density functional theory…
The typical amount of molecular hydrogen (${\rm H_2}$) in interstellar ices is not known, but significant freeze-out of ${\rm H_2}$ on dust grains is not expected. However, chemical models ubiquitously predict large amounts of $\rm H_2$…
Emission from the pure rotational transitions of H$_2$ traces warm molecular gas, providing insight into its temperature distribution and local heating conditions. We have extended previous power-law H$_2$ temperature models to account for…
The mobility of atoms, molecules and radicals in icy grain mantles regulate ice restructuring, desorption, and chemistry in astrophysical environments. Interstellar ices are dominated by H2O, and diffusion on external and internal (pore)…
The H3+ ion plays a key role in the chemistry of dense interstellar gas clouds where stars and planets are forming. The low temperatures and high extinctions of such clouds make direct observations of H3+ impossible, but lead to large…
In molecular cloud cores, the cosmic ray (CR) induced sputtering via CR ion-icy grain collision is one of the desorption processes for ice molecules from mantles around dust grains. The efficiency of this process depends on the incident CR…
Diffusion of species in icy dust grain mantles is a fundamental process that shapes the chemistry of interstellar regions; yet measurements of diffusion in interstellar ice analogs are scarce. Here we present measurements of CO diffusion…
In this work, we present an off-lattice Monte Carlo model of accretion and migration of hydrogen atoms on a rough surface of carbon dust grain. The migration of physisorbed atoms by means of thermal diffusion and quantum tunnelling through…
We present LVG and non-local radiative transfer calculations involving the rotational and hyperfine structure of the spectrum of N$_2$H$^+$ with collisional rate coefficients recently derived by us. The goal of this study is to check the…
Rate coefficients for rotational transitions in H_2 induced by H_2 impact are presented. Extensive quantum mechanical coupled-channel calculations based on a recently published (H_2)_2 potential energy surface were performed. The potential…
Context: Despite the low elemental deuterium abundance in the Galaxy, enhanced molecular D/H ratios have been found in the environments of low-mass star-forming regions and, in particular, the Class 0 protostar IRAS 16293-2422. Aims: The…
The spin transition in LaCoO3 is investigated by temperature-dependent resonant soft X-ray emission spectroscopy near the Co 2p absorption edges. This element-specific technique is more bulk sensitive with respect to the temperature induced…
Interstellar dust grains exhibit complex dynamics which is essential for understanding many key interstellar processes that involve dust, including grain alignment, grain growth, grain shattering etc. Grain rotational and translational…
The chemistry of dense interstellar regions was analyzed using a time-dependent gas-grain astrochemical simulation and a new chemical network that incorporates deuterated chemistry taking into account nuclear spin-states for the hydrogen…
We study single crystals of Dy$_2$Ti$_2$O$_7$ and Ho$_2$Ti$_2$O$_7$ under magnetic field and stress applied along their [001] direction. We find that many of the features that the emergent gauge field of spin ice confers to the macroscopic…
Elastic and inelastic neutron scattering studies have been carried out on the pyrochlore magnet Ho2Ti2O7. Measurements in zero applied magnetic field show that the disordered spin ice ground state of Ho2Ti2O7 is characterized by a pattern…
We aim to constrain the kinetic temperature and H$_2$ volume density of massive star-forming clumps associated with HII regions using multiple para-H$_2$CO transitions. In addition, we investigate the interplay between ionized gas,…
The HRS is a complete volume-limited sample of nearby objects including Virgo cluster and isolated objects. Using a recent compilation of HI and CO data we study the effects of the cluster on the molecular gas content of spiral galaxies. We…
We mapped the kinetic temperature structure of the Orion molecular cloud 1 with para-H2CO(303-202, 322-221, and 321-220) using the APEX 12m telescope. This is compared with the temperatures derived from the ratio of the NH3(2,2)/(1,1)…