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The thermodynamics and mechanics of the surface of a deformable body are studied here, following and refining the general approach of Gibbs. It is first shown that the 'local' thermodynamic variables of the state of the surface are only the…

Statistical Mechanics · Physics 2019-06-27 Juan Olives

The understanding of the spreading of liquids on solid surfaces is an important challenge for contemporary physics. Today, the motion of the contact line formed at the intersection of two immiscible fluids and a solid is still subject to…

Classical Physics · Physics 2009-11-13 Henri Gouin

The elastic deformation of a soft solid induced by capillary forces crucially relies on the excess stress inside the solid-liquid interface. While for a liquid-liquid interface this "surface stress" is strictly identical to the "surface…

Soft Condensed Matter · Physics 2015-06-17 Joost H. Weijs , Jacco H. Snoeijer , Bruno Andreotti

In the present work we investigate a new statistical ensemble, which seems logical to be entitled the open one, for the case of a one-component system of ordinary particles. Its peculiarity is in complementing the consideration of a system…

Statistical Mechanics · Physics 2009-12-13 V. M. Zaskulnikov

The wetting of solid surfaces by fluids is a problem of great practical importance that has been extensively studied over the years. Most often, the experimental work has involved measurements of the contact angle made by a liquid on the…

Statistical Mechanics · Physics 2007-05-23 S. Curtarolo , M. J. Bojan , G. Stan , M. W. Cole , W. A. Steele

We study a three-dimensional system of self-propelled Brownian particles interacting via the Lennard-Jones potential. Using Brownian Dynamics simulations in an elongated simulation box, we investigate the steady states of vapour-liquid…

Soft Condensed Matter · Physics 2017-08-29 Siddharth Paliwal , Vasileios Prymidis , Laura Filion , Marjolein Dijkstra

Even though the study of interfacial phenomena dates back to Laplace and was formalised by Gibbs, it appears that some concepts and relations among them are still causing some confusion and debates in the literature, particularly for…

Statistical Mechanics · Physics 2020-03-30 Nicodemo Di Pasquale , Ruslan L. Davidchack

With an aim to include the contribution of surface tension in the action of the boundary, we define the tangential pressure in terms of surface tension and Normal curvature in a more naturally geometric way. First, we show that the negative…

General Relativity and Quantum Cosmology · Physics 2013-01-21 Himanshu kumar , Sharf Alam , Suhail Ahmad

The surface free energy, or surface tension, of a liquid interface gives rise to a pressure jump when the interface is curved. Here we show that a similar capillary pressure arises at the interface of soft solids. We present experimental…

Fluid Dynamics · Physics 2015-06-03 Antonin Marchand , Siddhartha Das , Jacco H. Snoeijer , Bruno Andreotti

Conventionally, surface tension is expressed as a force per unit length or as an energy per unit area. In this paper, we propose a thought experiment that consists of replacing the surface tension with an equivalent force per unit area…

Fluid Dynamics · Physics 2025-12-01 Andre Schiltz

This paper concerns the dynamics of two layers of compressible, barotropic, viscous fluid lying atop one another. The lower fluid is bounded below by a rigid bottom, and the upper fluid is bounded above by a trivial fluid of constant…

Analysis of PDEs · Mathematics 2016-04-20 Juhi Jang , Ian Tice , Yanjin Wang

We develop a methodology for the calculation of surface free energies based on the probability distribution of a wandering interface. Using a simple extension of the NpT sampling, we allow the interface area to randomly probe the available…

Soft Condensed Matter · Physics 2009-11-13 Luis G. MacDowell , Pawel Bryk

Solid interfaces have intrinsic elasticity. However, in most experiments, this is obscured by bulk stresses. Through microscopic observations of the contact-line geometry of a partially wetting droplet on an anisotropically stretched…

Soft Condensed Matter · Physics 2017-11-29 Qin Xu , Robert W. Style , Eric R. Dufresne

We consider a coupled system of partial differential equations describing the interactions between a closed free interface and two viscous incompressible fluids. The fluids are assumed to satisfy the incompressible Navier-Stokes equations…

Optimization and Control · Mathematics 2023-08-01 Sebastien Court

This work focuses on the interfacial dynamics with interfacial mass flux in the presence of acceleration and surface tension. We employ the general matrix method to find the fundamental solutions for the linearized boundary value problem…

Fluid Dynamics · Physics 2021-07-07 D. V. Ilyin , S. I. Abarzhi

We discuss different definitions of pressure for a system of active spherical particles driven by a non-thermal coloured noise. We show that mechanical, kinetic and free-energy based approaches lead to the same result up to first order in…

Statistical Mechanics · Physics 2016-03-18 Umberto Marini Bettolo Marconi , Claudio Maggi , Simone Melchionna

Controlling interfaces of phase separating fluid mixtures is key to creating diverse functional soft materials. Traditionally, this is accomplished with surface-modifying chemical agents. Using experiment and theory, we study how mechanical…

Soft Condensed Matter · Physics 2022-08-15 Raymond Adkins , Itamar Kolvin , Zhihong You , Sven Witthaus , M. Cristina Marchetti , Zvonimir Dogic

Many textbooks dealing with surface tension favor the thermodynamic approach (minimization of some thermodynamic potential such as free energy) over the mechanical approach (balance of forces) to describe capillary phenomena, stating that…

Soft Condensed Matter · Physics 2021-03-17 Marc Durand

Particles bound to an interface interact because they deform its shape. The stresses that result are fully encoded in the geometry and described by a divergence-free surface stress tensor. This stress tensor can be used to express the force…

Soft Condensed Matter · Physics 2007-05-23 Martin Michael Mueller , Markus Deserno , Jemal Guven

We develop a theory of static friction by modeling the homogeneous surfaces of contact as being composed of a regular array of compressible elastic smooth microscopic inclines. Static friction is thought of as the resistance due to having…

Classical Physics · Physics 2014-07-14 Freeman Chee Siong Thun , Vee-Liem Saw , Kin Sung Chan