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Copper hydroxyhalide materials herbertsmithite ZnCu$_{3}$(OH)$_{6}$Cl$_{2}$ and Zn-barlowite ZnCu$_{3}$(OH)$_{6}$FrBr are thought to be the best realizations of the spin-$\frac{1}{2}$ Kagome quantum antiferromagnetic Heisenberg model and…

Strongly Correlated Electrons · Physics 2024-03-27 Jianhua Yang , Tao Li

The hexagonal swedenborgite, CaBaCo$_2$Fe$_2$O$_7$, is a chiral frustrated antiferromagnet, in which magnetic ions form alternating Kagome and triangular layers. We observe a long range $\sqrt{3} \times \sqrt{3}$ antiferromagnetic order…

Strongly Correlated Electrons · Physics 2018-04-11 Johannes D. Reim , Erik Rosén , Oksana Zaharko , Maxim Mostovoy , Julien Robert , Martin Valldor , Werner Schweika

We have successfully synthesized S = 1/2 kagome antiferromagnets MCu3(OH)6Cl2 (M = Ni and Co) by hydrothermal method with rotating pressure vessel. Structural characterization shows that both compounds have the similar crystal structure as…

Strongly Correlated Electrons · Physics 2012-12-10 Yue-sheng Li , Qing-ming Zhang

The emergent behavior of spin liquids that are born out of geometrical frustration makes them an intriguing state of matter. We show that in the quantum kagome antiferromagnet ZnCu$_3$(OH)$_6$SO$_4$ several different correlated, yet…

Strongly Correlated Electrons · Physics 2016-03-02 M. Gomilsek , M. Klanjsek , M. Pregelj , F. C. Coomer , H. Luetkens , O. Zaharko , T. Fennell , Y. Li , Q. M. Zhang , A. Zorko

We have studied the magnetic properties of clinoatacamite Cu$_2$Cl(OH)$_3$, the parent compound of the quantum spin liquid candidate herbertsmithite and a longstanding puzzle among frustrated quantum magnets. As we reveal using…

The spin-1/2 Cu2+ ions in beta-Cu3V2O8 occupy the sites of a Kagome-staircase lattice, an anisotropic variant of the Kagome net: buckled layers and imbedded plaquettes of three edge-shared CuO4 squares break the ideal Kagome symmetry.…

Condensed Matter · Physics 2012-08-16 N. Rogado , M. K. Haas , G. Lawes , D. A. Huse , A. P. Ramirez , R. J. Cava

Y3Cu9(OH)19Cl8 realizes an original anisotropic kagome model hosting a rich magnetic phase diagram [M. Hering et al, npj Computational Materials 8, 1 (2022)]. We present an improved synthesis of large phase-pure single crystals via an…

Geometrical frustration, quantum entanglement and disorder may prevent long-range order of localized spins with strong exchange interactions, resulting in a novel state of matter. $\kappa$-(BEDT-TTF)$_2$-Cu$_2$(CN)$_3$ is considered the…

We report the study of high quality samples of the frustrated S = 1/2 kagome antiferromagnet vesignieite, Cu3Ba(VO5H)2. Neutron powder diffraction measurements evidence the high quality of the kagome lattice and show no sign of a transition…

muSR experiments on the geometrically frustrated spinel oxide, Li2Mn2O4, show the development of spin correlations over a range of length scales with decreasing temperature. Increased relaxation below 150 K is consistent with the onset of…

Strongly Correlated Electrons · Physics 2009-11-11 C. R. Wiebe , P. L. Russo , A. T. Savici , Y. J. Uemura , G. J. MacDougall , G. M. Luke , S. Kuchta , J. E. Greedan

We report a detailed study of the magnetic properties, critical analysis of magnetization, and magnetocaloric effect of a spin-$2$ kagome lattice YCa$_3$(MnO)$_3$(BO$_3$)$_4$. The experiments are complemented by the density functional band…

Materials Science · Physics 2025-07-29 A. Choudhary , A. Magar , S. Ghosh , S. Kanungo , R. Nath

The antiferromagnetic - ferromagnetic phase transition in YBaCo2O5.50 and YBaCo2O5.44 cobaltites with different types of oxygen-ion ordering in the [YO0.5/0.44] layers has been studied by neutron powder diffraction. Using the magnetic…

Materials Science · Physics 2007-05-23 D. D. Khalyavin , D. N. Argyriou , U. Amann , A. A. Yaremchenko , V. V. Kharton

We report results of magnetic susceptibility and 51V- and 63,65Cu-NMR measurements on a high-quality powder sample of vesignieite BaCu3V2O8(OH)2, a candidate for the spin-1/2 kagome antiferromagnet. We observed a twostep magnetic…

Strongly Correlated Electrons · Physics 2017-12-01 Makoto Yoshida , Yoshihiko Okamoto , Masashi Takigawa , Zenji Hiroi

The crystal and magnetic structure of (La0.70Ca0.30)(CryMn1-y)O3 for y = 0.70, 0.50 and 0.15 has been investigated using neutron powder diffraction. The three samples crystallize in the Pnma space group at both 290 K and 5 K and exhibit…

Motivated by the recent synthesis of a number of Mott insulating square-kagome materials, we explore the rich phenomenology of frustrated magnetism induced by this lattice geometry, also referred to as the squagome or shuriken lattice. On…

Strongly Correlated Electrons · Physics 2023-12-11 Martin Gembé , Heinz-Jürgen Schmidt , Ciarán Hickey , Johannes Richter , Yasir Iqbal , Simon Trebst

The $4f$-electron system YbAl$_3$C$_3$ with a non-magnetic spin-dimer ground state has been studied by neutron diffraction in an applied magnetic field. A long-range magnetic order involving both ferromagnetic and antiferromagnetic…

Strongly Correlated Electrons · Physics 2015-06-15 D. D. Khalyavin , D. T. Adroja , P. Manuel , A. Daoud-Aladine , M. Kosaka , K. Kondo , K. A. McEwen , J. H. Pixley , Qimiao Si

We report muSR experiments on Mg{x}Cu{4-x}(OH)6Cl2 with x \sim 1, a new material isostructural to Herbertsmithite exhibiting regular kagome planes of spin 1/2 (Cu^{2+}), and therefore a candidate for a spin liquid ground state. We evidence…

Strongly Correlated Electrons · Physics 2014-10-06 E. Kermarrec , P. Mendels , F. Bert , R. H. Colman , A. S. Wills , P. Strobel , P. Bonville , A. Hillier , A. Amato

Using powder neutron diffraction we have discovered an unusual magnetic order-order transition in the Ising spin chain compound Ca3Co2O6. On lowering the temperature an antiferromagnetic phase with propagation vector k=(0.5,-0.5,1) emerges…

Strongly Correlated Electrons · Physics 2011-05-17 S. Agrestini , C. L. Fleck , L. C. Chapon , C. Mazzoli , A. Bombardi , M. R. Lees , O. A. Petrenko

The ground state of the solid solution of the two spin gap systems (CH3)2CHNH3CuCl3 and (CH3)2CHNH3CuBr3 has been investigated by 1H-NMR. The existence of a magnetic ordering in the sample with the Cl-content x=0.85 was clearly demonstrated…

Other Condensed Matter · Physics 2009-11-11 Keishi Kanada , Takehiro Saito , Akira Oosawa , Takayuki Goto , Takao Suzuki , Hirotaka Manaka

We report on the low-energy dynamics in the kagome antiferromagnet CaCu$_3$(OD)$_6$Cl$_2\cdot0.6$D$_2$O (Ca-kapellasite) as studied by use of $^2$D-NMR measurements. Previous $^{35}$Cl-NMR measurements revealed that the nuclear spin-lattice…