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Graphyne, a single atomic layer structure of the carbon six-member rings connected by one acetilenic linkage, is a promising anode of rechargeable batteries. In this paper, a first-principle study has been carried out on graphyne as a new…

Materials Science · Physics 2021-05-24 E. Shomali , I. Abdolhosseini Sarsari , F. Tabatabaei , MR. Mosaferi , N. Seriani

Traditional approaches to identify ion-transport pathways often presume equal probability of occupying all hopping sites and focus entirely on finding the lowest migration barrier channels between them. Although this strategy has been…

Materials Science · Physics 2023-01-27 Shashwat Anand , Tina Chen , Gerbrand Ceder

Rechargeable Zn batteries with aqueous electrolytes have been considered as promising alternative energy storage technology, with various advantages such as low cost, high volumetric capacity, environmentally friendly, and high safety.…

Materials Science · Physics 2021-08-31 Linming Zhou , Archie Mingze Yao , Yongjun Wu , Ziyi Hu , Yuhui Huang , Zijian Hong

Two-dimensional materials composed of transition metal carbides and nitrides (MXenes) are poised to revolutionize energy conversion and storage. In this work, we used density functional theory (DFT) to investigate adsorption of Mg and Na…

Materials Science · Physics 2021-12-01 G. Chaney , D. Çakır , F. M. Peeters , C. Ataca

Efficient energy storage systems are crucial to address the intermittency of renewable energy sources. As multivalent batteries, Zn-ion batteries (ZIBs), while inherently low voltage, offer a promising low cost alternative to Li-ion…

Materials Science · Physics 2025-04-17 Roberta Pascazio , Qian Chen , Haoming Howard Li , Aaron D. Kaplan , Kristin A. Persson

The ongoing search for high voltage positive electrode materials for Mg batteries has been primarily hampered by poor Mg mobility in bulk oxide frameworks. Motivated by the presence of Mo$_3$ clusters that can facilitate charge…

Materials Science · Physics 2016-10-20 Gopalakrishnan Sai Gautam , Xiaoqi Sun , Victor Duffort , Linda F. Nazar , Gerbrand Ceder

Stable and fast ionic conductors for magnesium cathode materials have the prospect of enabling high energy density batteries beyond current Lithium-ion technologies. So far, only a few candidate materials have been identified leading to…

Materials Science · Physics 2021-08-25 Felix T. Bölle , Arghya Bhowmik , Tejs Vegge , Juan Maria García Lastra , Ivano E. Castelli

Natural abundance of sodium and its similar behavior to lithium triggered recent extensive studies of cost-effective sodium-ion batteries (SIBs) for large-scale energy storage systems. A challenge is to develop electrode materials with a…

Materials Science · Physics 2017-09-19 Gum-Chol Ri , Song-Hyok Choe , Chol-Jun Yu

Using an ab initio evolutionary algorithm combined with first-principles calculations, two metastable NaMnO$_2$ polymorphs, $I4_1/amd$ and Cmcm, are identified as promising cathode materials for sodium-ion batteries. Both phases exhibit…

Materials Science · Physics 2025-06-24 Fukuan Wang , Chen Zhou , Busheng Wang , Yong Liu

Hybrid electrolyte materials comprising polymer-ionic salt matrixes embedded with garnet particles constitute a promising class of materials for the realization of all-solid-state batteries. In addition to providing solutions to the safety…

Applied Physics · Physics 2021-05-04 Juan C. Verduzco , John N. Vergados , Alejandro Strachan , Ernesto E. Marinero

Ionic conductors have great potential for interesting tunable physical properties via ionic liquid gating and novel energy storage applications such as all-solid-state lithium batteries. In particular, low migration barriers and high…

Materials Science · Physics 2024-12-12 Xin Chen , Xixiang Zhang , Jie-Xiang Yu , Jiadong Zang

This article reviews the development of cathode materials for secondary lithium ion batteries since its inception with the introduction of lithium cobalt oxide in early 1980s. The time has passed and numerous cathode materials are designed…

Materials Science · Physics 2021-09-07 Ambesh Dixit

Discovering new superionic materials is essential for advancing solid-state batteries, which offer improved energy density and safety compared to the traditional lithium-ion batteries with liquid electrolytes. Conventional computational…

Electrolyte gating is a powerful technique for accumulating large carrier densities in surface two-dimensional electron systems (2DES). Yet this approach suffers from significant sources of disorder: electrochemical reactions can damage or…

Ionic mobility determines the rate performance of several applications, such as batteries, fuel cells, and electrochemical sensors and is exponentially dependent on the migration barrier ($E_m$), a difficult to measure/calculate quantity.…

Materials Science · Physics 2026-02-16 Reshma Devi , Keith T. Butler , Gopalakrishnan Sai Gautam

It is of great importance to develop inorganic solid electrolytes with high ionic conductivity, thus enabling solid state Li-ion batteries to address the notorious safety issue about the current technology due to use of highly flammable…

Chemical Physics · Physics 2017-07-17 Zhuo Wang , Min Jie Xuan , Hong Jie Xu , Guosheng Shao

Identifying applicable anode materials is a significant task for Li- and Na-ion battery (LIB and NIB) technologies. We propose the GaN monolayer (2D GaN) can be a good anode candidate. The GaN monolayer manifests stable Li/Na adsorption and…

Materials Science · Physics 2018-12-31 Xiaoming Zhang , Lei Jin , Xuefang Dai , Guifeng Chen , Guodong Liu

Close-packed chalcogenide spinels, such as MgSc$_2$Se$_4$, MgIn$_2$S$_4$ and MgSc$_2$S$_4$, show potential as solid electrolytes in Mg batteries, but are affected by non-negligible electronic conductivity, which contributes to…

Na, K and Ca-ion battery electrode materials with appropriate electrochemical properties are desirable candidates for replacing lithium-ion batteries (LIBs) because of their natural richness and low cost. Recently, MoO2 has been reported as…

Computational Physics · Physics 2019-03-27 Yongchao Rao , Song Yu , Xiao Gu , Xiangmei Duan

There is a growing interest in the development of functional metal oxides with mixed ionic electronic conduction for their application in different strategic fields. In particular, ionic transport-related phenomena are of primary importance…

Materials Science · Physics 2018-12-03 Francesco Chiabrera , Inigo Garbayo , Albert Tarancon