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We study the breakup of $\text{H}_2^+$ exposed to super-intense, femtosecond laser pulses with frequencies greater than that corresponding to the ionization potential. By solving the time-dependent Schr\"odinger equation in an extensive…

Atomic Physics · Physics 2016-04-12 Lun Yue , Lars Bojer Madsen

The accurate description of iron oxides/water interfaces requires reliable force field parameters that can be developed through the comparison with sophisticated quantum mechanical calculations. Here a set of CLASS2 force field parameters…

Materials Science · Physics 2021-12-07 Paulo Siani , Enrico Bianchetti , Hongsheng Liu , Cristiana Di Valentin

Hyperpolarized water can be a valuable aid in protein NMR, leading to amide group 1H polarizations that are orders of magnitude larger than their thermal counterparts. Suitable procedures can exploit this to deliver 2D 1H-15N correlations…

Chemical Physics · Physics 2020-04-28 Or Szekely , Gregory Lars Olsen , Mihajlo Novakovic , Rina Rosenzweig , Lucio Frydman

This paper presents a comprehensive exposition of a spontaneous laser model for a resonant semi-classical system of radiation and ion cluster-solvated rotating water molecules, which have subtly variable moments of inertia. In this system,…

Quantum Physics · Physics 2021-01-28 Eiji Konishi

Molecular ions formed in cold hybrid ion-atom experiments may find interesting applications ranging from precision measurements to controlled chemical reactions. Here, we investigate electronic structure of the Sr$_2^+$ molecular ion, which…

Atomic Physics · Physics 2020-06-17 Michał Śmiałkowski , Tatiana Korona , Michał Tomza

High-resolution spectroscopy allows one to probe weak interactions and to detect subtle phenomena. While such measurements are routinely performed on atoms and molecules in the gas phase, spectroscopy of adsorbed species on surfaces is…

We comment some recent unexpected experimental results on proton/deuteron deep inelastic scattering off water molecules in H2O-D2O mixtures (C.A. Chatzidimitrou-Dreismann et al. Phys. Rev. Lett. 79, 2839 (1997)) where a strong dependence of…

Statistical Mechanics · Physics 2007-05-23 Matteo Buzzacchi , Emilio Del Giudice , Giuliano Preparata

Molecular-scale dynamics in sub- to super-critical water is studied with inelastic X-ray scattering and molecular dynamics simulations. The obtained longitudinal current correlation spectra can be decomposed into two main components: a…

Soft Condensed Matter · Physics 2020-12-15 Peihao Sun , J. B. Hastings , Daisuke Ishikawa , Alfred Q. R. Baron , Giulio Monaco

Analysis of SFG vibrational spectra of OH stretching bands in four experimental configurations shows that orientational motion of water molecule at air/water interface is libratory within a limited angular range. This picture is…

Other Condensed Matter · Physics 2007-06-11 Wei Gan , Dan Wu , Zhen Zhang , Hong-fei Wang

Aqueous radiation chemistry emerges through ultrafast proton transfer and ion-radical formation with unexplored energy-redistribution dynamics steering the subsequent reactions. We performed time-resolved disruptive probing on pure water…

We observe energy-dependent angle-resolved diffraction patterns in protons from strong-field dissociation of the molecular hydrogen ion H$_2^+$. The interference is a characteristic of dissociation around a laser-induced conical…

Atomic and Molecular Clusters · Physics 2016-04-11 Adi Natan , Matthew R Ware , Vaibhav S. Prabhudesai , Uri Lev , Barry D. Bruner , Oded Heber , Philip H Bucksbaum

The toolbox for imaging molecules is well-equipped today. Some techniques visualize the geometrical structure, others the electron density or electron orbitals. Molecules are many-body systems for which the correlation between the…

We show that the momentum flexibility of inelastic x-ray scattering may be exploited to invert its loss function, alowing real time imaging of density disturbances in a medium. We show the disturbance arising from a point source in liquid…

Condensed Matter · Physics 2009-11-10 P. Abbamonte , K. D. Finkelstein , M. D. Collins , S. M. Gruner

Water is essential for almost every aspect of life on our planet and, unsurprisingly, its properties have been studied in great detail. However, disproportionately little remains known about the electrical properties of interfacial and…

We report the detection of the H_2O molecule in absorption at a redshift z = 0.68466 in front of the gravitationally lensed quasar B0218+357. We detect the fundamental transition of ortho-water at 556.93 GHz (redshifted to 330.59 GHz). The…

Astrophysics · Physics 2016-08-30 F. Combes , T. Wiklind

The most common species in liquid water, next to neutral H$_2$O molecules, are the H$_3$O$^+$ and OH$^-$ ions. In a dynamic picture, their exact concentrations depend on the time scale at which these are probed. Here, using a…

Materials Science · Physics 2026-03-26 V. G. Artemov , E. Uykur , S. Roh , A. V. Pronin , H. Ouerdane , M. Dressel

Here, by making use of medium and high resolution autocorrected off-axis electron holography, we directly probe the electrostatic potential as well as in-plane and out-of-plane charge delocalization at edges and steps in multilayer…

Using the frequency-domain theory, the high-order above threshold ionization (HATI) of a molecule is treated as a two-step transition: an above threshold ionization (ATI) followed by a laser-assisted collision (LAC). It is found that the…

Atomic Physics · Physics 2009-05-28 Bingbing Wang , Yingchun Guo , Zong-Chao Yan , Panming Fu

We present a consistent analysis of linear spectroscopy for arrays of nearest neighbor dipole-coupled two-level molecules that reveals distinct signatures of weak and strong coupling regimes separated for infinite size arrays by a quantum…

Quantum Physics · Physics 2015-06-16 A. A. Kocherzhenko , J. Dawlaty , B. P. Abolins , F. Herrera , D. B. Abraham , K. B. Whaley

The alignment dependence of the ionization behavior of H$_2$ exposed to intense ultrashort laser pulses is investigated on the basis of solutions of the full time-dependent Schr\"odinger equation within the fixed-nuclei and dipole…

Quantum Physics · Physics 2013-05-29 Yulian V. Vanne , Alejandro Saenz