Related papers: A chemical kinetics code for modelling exoplanetar…
Of the many recently discovered worlds orbiting distant stars, very little is yet known of their chemical composition. With the arrival of new transit spectroscopy and direct imaging facilities, the question of molecular detectability as a…
The search for potentially habitable exoplanets centers on detecting biosignature molecules in Earth-like atmospheres, which makes it essential to understand their detectability under biologically and geologically influenced conditions. In…
Due to strong irradiation, hot rocky exoplanets are able to sustain lava oceans. Direct interaction between these oceans and overlying atmospheres can provide insight into planetary interiors. In order to fully understand how the…
Determining the atmospheric structure and chemical composition of an exoplanet remains a formidable goal. Fortunately, advancements in the study of exoplanets and their atmospheres have come in the form of direct imaging - spatially…
The atmospheres of gaseous giant exoplanets orbiting close to their parent stars (hot Jupiters) have been probed for nearly two decades. They allow us to investigate the chemical and physical properties of planetary atmospheres under…
For solar-system objects, ultraviolet spectroscopy has been critical in identifying sources for stratospheric heating and measuring the abundances of a variety of hydrocarbon and sulfur-bearing species, produced via photochemical…
A primary goal of characterizing exoplanet atmospheres is to constrain planetary bulk properties, such as their metallicity, C/O ratio, and intrinsic heat. However, there are significant uncertainties in many aspects of atmospheric physics,…
The composition of a planet's atmosphere is determined by its formation, evolution, and present-day insolation. A planet's spectrum therefore may hold clues on its origins. We present a "chain" of models, linking the formation of a planet…
The atmospheric C/O ratio of exoplanets is widely used to constrain their formation. To guarantee that the C/O ratio provides robust information, we need to accurately quantify the amount of C and O in exoplanetary atmospheres. In the case…
Determining the habitability and interpreting atmospheric spectra of exoplanets requires understanding their atmospheric physics and chemistry. We use a 3-D Coupled Climate-Chemistry Model, the Met Office Unified Model with the UK Chemistry…
We are now on a clear trajectory for improvements in exoplanet observations that will revolutionize our ability to characterize their atmospheric structure, composition, and circulation, from gas giants to rocky planets. However, exoplanet…
Relating planet formation to atmospheric composition has been a long-standing goal of the planetary science community. So far, most modeling studies have focused on predicting the enrichment of heavy elements and the C/O ratio in giant…
Escaping exoplanet atmospheres have been observed as deep transit signatures in a few specific spectral lines. Detections have been made in the hydrogen Ly-$\alpha$ line, the metastable helium line at 10830 {\AA} and some UV lines of…
Using forward models for representative exoplanet atmospheres and a radiometric instrument model, we have generated synthetic observational data to explore how well the major C- and O-bearing chemical species (CO, CO2, CH4, and H2O),…
Atmospheric chemistry models have shown molecular oxygen can build up in CO2-dominated atmospheres on potentially habitable exoplanets without an input of life. Existing models typically assume a surface pressure of 1 bar. Here we present…
The past decade has seen significant progress on the direct detection and characterization of young, self-luminous giant planets at wide orbital separations from their host stars. Some of these planets show evidence for disequilibrium…
Over the last decade, exoplanetary transmission spectra have yielded an unprecedented understanding about the physical and chemical nature of planets outside our solar system. Physical and chemical knowledge is mainly extracted via fitting…
Exoplanet atmospheric retrieval is a computational technique widely used to infer properties of planetary atmospheres from remote spectroscopic observations. Retrieval codes typically employ Bayesian sampling algorithms or machine learning…
We present an open-source and validated chemical kinetics code for studying hot exoplanetary atmospheres, which we name VULCAN. It is constructed for gaseous chemistry from 500 to 2500 K using a reduced C-H-O chemical network with about 300…
A carbon-to-oxygen ratio (C/O) of around unity is believed to act as a natural separator of water- and methane-dominated spectra when characterizing exoplanet atmospheres. In this paper we quantify the C/O ratios at which this separation…