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Chemical disequilibrium has recently become a relevant topic in the study of the atmospheres of of transiting extrasolar planets, brown dwarfs, and directly imaged exoplanets. We present a new way of assessing whether or not a Jovian-like…

Earth and Planetary Astrophysics · Physics 2015-06-17 Michael R Line , Yuk Yung

Molecular species in planetary atmospheres provide key insights into their atmospheric processes and formation conditions. In recent years, high-resolution Doppler spectroscopy in the near-infrared has allowed detections of H$_2$O and CO in…

Earth and Planetary Astrophysics · Physics 2018-08-22 George A. Hawker , Nikku Madhusudhan , Samuel H. C. Cabot , Siddharth Gandhi

Characterizing the atmospheres of extrasolar planets is the new frontier in exoplanetary science. The last two decades of exoplanet discoveries have revealed that exoplanets are very common and extremely diverse in their orbital and bulk…

Earth and Planetary Astrophysics · Physics 2016-06-01 Nikku Madhusudhan , Marcelino Agúndez , Julianne I. Moses , Yongyun Hu

Three dimensional models that account for chemistry are useful tools to predict the chemical composition of (exo)planet and brown dwarf atmospheres and interpret observations of future telescopes. Recent Juno observations of the NH3…

Exoplanets that receive stellar irradiance of approximately Earth's or less have been discovered and many are suitable for spectral characterization. Here we focus on the temperate planets that have massive H2-dominated atmospheres, and…

Earth and Planetary Astrophysics · Physics 2021-11-03 Renyu Hu

Studying the atmospheres of exoplanets is one of the most promising ways to learn about distant worlds beyond our solar system. The composition of an exoplanet's atmosphere can provide critical insights into its geology and potential…

Earth and Planetary Astrophysics · Physics 2025-05-05 Surangkhana Rukdee

Context: The thermal and chemical structures of the upper atmospheres of planets crucially influence losses to space and must be understood to constrain the effects of losses on atmospheric evolution. Aims: We develop a 1D first-principles…

Earth and Planetary Astrophysics · Physics 2018-09-26 Colin P. Johnstone , Manuel Güdel , Helmut Lammer , Kristina G. Kislyakova

A detailed modeling of simultaneous UV-photochemical and thermochemical processes in exoplanet atmosphere-like conditions is essential for the analysis and interpretation of a vast amount of current and future spectral data from exoplanets.…

Earth and Planetary Astrophysics · Physics 2023-04-26 Jeehyun Yang , Murthy S. Gudipati , Bryana L Henderson , Benjamin Fleury

Chemical models are routinely used to predict the atmospheric composition of exoplanets and compare it with the composition retrieved from observations, but little is known about the reliability of the calculated composition. We carried out…

Earth and Planetary Astrophysics · Physics 2025-12-03 Marcelino Agundez

The Habitable Worlds Observatory (HWO) offers a unique opportunity to revolutionize our understanding of planetary formation and evolution. The goal of this Science Case Development Document (SCDD) is to investigate the physical and…

Very little experimental work has been done to explore the properties of photochemical hazes formed in atmospheres with very different compositions or temperatures than that of the outer solar system or of early Earth. With extrasolar…

Recent infrared spectroscopy of hot exoplanets is beginning to reveal their atmospheric composition. Deep with in the planetary atmosphere, the composition is controlled by thermochemical equilibrium. Photochemistry becomes important higher…

Earth and Planetary Astrophysics · Physics 2015-05-18 Michael R. Line , Mao-Chang Liang , Yuk L. Yung

Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called…

Earth and Planetary Astrophysics · Physics 2023-03-22 The JWST Transiting Exoplanet Community Early Release Science Team , Eva-Maria Ahrer , Lili Alderson , Natalie M. Batalha , Natasha E. Batalha , Jacob L. Bean , Thomas G. Beatty , Taylor J. Bell , Björn Benneke , Zachory K. Berta-Thompson , Aarynn L. Carter , Ian J. M. Crossfield , Néstor Espinoza , Adina D. Feinstein , Jonathan J. Fortney , Neale P. Gibson , Jayesh M. Goyal , Eliza M. -R. Kempton , James Kirk , Laura Kreidberg , Mercedes López-Morales , Michael R. Line , Joshua D. Lothringer , Sarah E. Moran , Sagnick Mukherjee , Kazumasa Ohno , Vivien Parmentier , Caroline Piaulet , Zafar Rustamkulov , Everett Schlawin , David K. Sing , Kevin B. Stevenson , Hannah R. Wakeford , Natalie H. Allen , Stephan M. Birkmann , Jonathan Brande , Nicolas Crouzet , Patricio E. Cubillos , Mario Damiano , Jean-Michel Désert , Peter Gao , Joseph Harrington , Renyu Hu , Sarah Kendrew , Heather A. Knutson , Pierre-Olivier Lagage , Jérémy Leconte , Monika Lendl , Ryan J. MacDonald , E. M. May , Yamila Miguel , Karan Molaverdikhani , Julianne I. Moses , Catriona Anne Murray , Molly Nehring , Nikolay K. Nikolov , D. J. M. Petit dit de la Roche , Michael Radica , Pierre-Alexis Roy , Keivan G. Stassun , Jake Taylor , William C. Waalkes , Patcharapol Wachiraphan , Luis Welbanks , Peter J. Wheatley , Keshav Aggarwal , Munazza K. Alam , Agnibha Banerjee , Joanna K. Barstow , Jasmina Blecic , S. L. Casewell , Quentin Changeat , K. L. Chubb , Knicole D. Colón , Louis-Philippe Coulombe , Tansu Daylan , Miguel de Val-Borro , Leen Decin , Leonardo A. Dos Santos , Laura Flagg , Kevin France , Guangwei Fu , A. García Muñoz , John E. Gizis , Ana Glidden , David Grant , Kevin Heng , Thomas Henning , Yu-Cian Hong , Julie Inglis , Nicolas Iro , Tiffany Kataria , Thaddeus D. Komacek , Jessica E. Krick , Elspeth K. H. Lee , Nikole K. Lewis , Jorge Lillo-Box , Jacob Lustig-Yaeger , Luigi Mancini , Avi M. Mandell , Megan Mansfield , Mark S. Marley , Thomas Mikal-Evans , Giuseppe Morello , Matthew C. Nixon , Kevin Ortiz Ceballos , Anjali A. A. Piette , Diana Powell , Benjamin V. Rackham , Lakeisha Ramos-Rosado , Emily Rauscher , Seth Redfield , Laura K. Rogers , Michael T. Roman , Gael M. Roudier , Nicholas Scarsdale , Evgenya L. Shkolnik , John Southworth , Jessica J. Spake , Maria E Steinrueck , Xianyu Tan , Johanna K. Teske , Pascal Tremblin , Shang-Min Tsai , Gregory S. Tucker , Jake D. Turner , Jeff A. Valenti , Olivia Venot , Ingo P. Waldmann , Nicole L. Wallack , Xi Zhang , Sebastian Zieba

We present novel, analytical, equilibrium-chemistry formulae for the abundances of molecules in hot exoplanetary atmospheres that include the carbon, oxygen and nitrogen networks. Our hydrogen-dominated solutions involve acetylene…

Earth and Planetary Astrophysics · Physics 2016-10-05 Kevin Heng , Shang-Min Tsai

Little is known about the interaction between atmospheres and crusts of exoplanets so far, but future space missions and ground-based instruments are expected to detect molecular features in the spectra of hot rocky exoplanets. We aim to…

Earth and Planetary Astrophysics · Physics 2020-04-22 Oliver Herbort , Peter Woitke , Christiane Helling , Aubrey Zerkle

The past twenty years have revealed the diversity of planets that exist in the Universe. It turned out that most of exoplanets are different from the planets of our Solar System and thus, everything about them needs to be explored. Thanks…

Earth and Planetary Astrophysics · Physics 2015-06-22 Olivia Venot , Marcelino Agúndez

It is important that we are able to accurately model the atmospheres of (exo)planets. This is because atmospheres play a central role in setting a planet's thermochemical environment at a given point in time, and also in regulating how it…

Instrumentation and Methods for Astrophysics · Physics 2025-06-03 Harrison Nicholls , Raymond Pierrehumbert , Tim Lichtenberg

We have developed a 1D planetary atmosphere model that solves in a self-consistent manner the evolution of temperature and disequilibrium chemistry in the vertical direction. Thermochemical kinetics is based on a reaction network built from…

Earth and Planetary Astrophysics · Physics 2025-06-16 Marcelino Agundez

The characterization of exoplanet atmospheres has proven to be successful using high-resolution spectroscopy. Phase curve observations of hot/ultra-hot Jupiters can reveal their compositions and thermal structures, thereby allowing the…

Earth and Planetary Astrophysics · Physics 2023-09-01 Swaetha Ramkumar , Neale P. Gibson , Stevanus K. Nugroho , Cathal Maguire , Mark Fortune

To date, the ability for observers to reveal the composition or thermal structure of an exoplanet's atmosphere has rested on two techniques: high-contrast direct imaging and time-series observations of transiting exoplanets. The former is…

Earth and Planetary Astrophysics · Physics 2020-07-30 Kevin B. Stevenson