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A new dual plasma coating process to produce platinum-free catalysts for the oxygen reduction reaction in a fuel cell is introduced. The catalysts thus produced were analysed with various methods. Electrochemical characterisation was…

The conversion of CO2 into high-value chemicals through a photoreduction reaction in water is a promising route to reduce the dependence on fossil fuels. Ag nanoparticles can drive this reaction via localized surface plasmon resonance, but…

The integration of the coupling effects of intrinsic wettability and surface charge in a nanochannel can cause non-intuitive behavior in the electrokinetic energy conversion processes. We demonstrate that in a nanofluidic device the energy…

Fluid Dynamics · Physics 2015-11-12 Chirodeep Bakli , Suman Chakraborty

Nitrate is an important pollutant in drinking water worldwide, and a number of methods exist for the removal of nitrate from water including ion exchange and reverse osmosis. However, these approaches suffer from a variety of disadvantages…

Chemical Physics · Physics 2017-06-20 James W. Palko , Diego I. Oyarzun , Byunghang Ha , Michael Stadermann , Juan G. Santiago

Efficient and selective CO2 electroreduction into value-added chemicals and fuels emerged as a significant approach for CO2 conversion, however, it relies on catalysts with controllable product selectivity and reaction paths. In this work,…

Mesoscale and Nanoscale Physics · Physics 2022-10-26 Wei Xun , Xiao Yang , Qing-Song Jiang , Ming-Jun Wang , Yin-Zhong Wu , Ping Li

Solid oxide fuel/electrolyzer cell (SOFC/SOEC) converts energy between chemical and electrical forms inversely. Yet electrolyte degradation takes place much more severe for SOEC than SOFC during long-term operations. By solving transport…

Materials Science · Physics 2018-10-23 Yanhao Dong , I-Wei Chen

Plasma electrolytic oxidation (PEO) processing of EV 31 magnesium alloy has been carried out in fluoride containing electrolyte under bipolar pulse current regime. Unusual PEO cathodic micro-discharges have been observed and investigated.…

Applied Physics · Physics 2019-02-27 A. Nominé , J. Martin , C. Noel , G. Henrion , T. Belmonte , I. Bardin , V. Kovalev , A. Rakoch

An extremely efficient ethanol fuel cell electrode is produced by combining the large surface area of vertically oriented and highly conductive few-layer graphene sheets with electrochemically deposited palladium nanoparticles. The…

Chemical Physics · Physics 2016-10-18 Michael Höltig , Charlotte Ruhmlieb , Tobias Kipp , Alf Mews

A novel Y-shaped membraneless flow-through electrolyzer is introduced to achieve a homogeneous electrochemical reaction across the entire electrode in a cost-efficient cell design with effective product separation. Numerical simulations of…

The photoconversion of CO$_2$ to hydrocarbons is a sustainable route to its transformation into value-added compounds and, thereby, crucial to mitigating the energy and climate crises. CuPt nanoparticles on TiO$_2$ surfaces have been…

Chemical looping methane partial oxidation provides an energy and cost effective route for methane utilization. However, there is considerable CO2 co-production in state-of-the-art chemical looping systems, rendering a decreased…

Chemical Physics · Physics 2020-01-08 Yan Liu , Lang Qin , Zhuo Cheng , Josh W. Goetze , Fanhe Kong , Jonathan A. Fan , Liang-shih Fan

Engineering systems modelling and analysis based on the bond graph approach has been applied to biomolecular systems. In this context, the notion of a Faraday-equivalent chemical potential is introduced which allows chemical potential to be…

Molecular Networks · Quantitative Biology 2017-06-07 Peter Gawthrop

Electrocatalytic CO2 reduction technology is key to mitigating greenhouse gas emissions and the energy crisis. However, controlling the selectivity of CO2RR products at low overpotential remains a challenge. In this paper, we predicted five…

Materials Science · Physics 2024-03-05 Ran Wang , Chaozheng He , Weixing Chen , Qingquan Kong , Thomas Frauenheimac

This paper details the development of an integrated AC electro-osmotic (ACEO) microfluidic pump for dilute electrolytes consisting of a long serpentine microchannel lined with three dimensional (3D) stepped electrode arrays. Using low AC…

Fluid Dynamics · Physics 2009-08-06 Chien-Chih Huang , Martin Z. Bazant , Todd Thorsen

We performed density-functional theory calculations using the generalized gradient approximation for the exhange-correlation functional to investigate the unusual catalytic behavior of Ru under elevated gas pressure conditions for the…

Materials Science · Physics 2008-02-03 C. Stampfl , M. Scheffler

Strong control over experimental conditions in microfluidic channels provides a unique opportunity to study and optimize membraneless microbial fuel cells (MFCs), particularly with respect to the role of flow. However, improved performance…

Li-CO$_2$ batteries are promising energy storage systems due to their high theoretical energy density and CO$_2$ fixation capability, relying on reversible Li$_2$CO$_3$/C formation during discharge/charge cycles. We present a multiscale…

Faradaic deionization (FDI) is a promising technology for energy-efficient water desalination using porous electrodes containing redox-active materials. Herein, we demonstrate for the first time the capability of a symmetric FDI flow cell…

Chemical Physics · Physics 2023-06-09 Vu Q. Do , Erik R. Reale , Irwin C. Loud , Paul G. Rozzi , Haosen Tan , David A. Willis , Kyle C. Smith

Based on the consideration of increasing the number of initial electrons and providing an appropriate distribution of electric field strength for discharge space, a method of adopting the wire-cylindrical type electrode structure with a…

Plasma Physics · Physics 2020-08-26 Shuai Zhao , Yong Hao , Tao Qiao , Weisheng Cui

The energy absorption on nanometer scale is vital for many bio and chemical systems. We report here that a two times amplification in absorption efficiency can be achieved by water molecules confined in carbon nanotubes with small radius,…

Mesoscale and Nanoscale Physics · Physics 2022-07-19 Rong-Yao Yang , Wei-Zhou Jiang , Pei-Ying Huo , Qi-Lin Zhang