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We study dynamics of nonclassical correlations by exactly solving a model consisting of two atomic qubits with spontaneous emission. We find that the nonclassical correlations defined by different measures give different qualitative…

Quantum Physics · Physics 2012-02-01 Ming-Liang Hu , Heng Fan

A method for increasing the accuracy of configuration interaction (CI) calculations of molecules and other electronic systems is proposed. The energy defect of a given calculation is associated with the electron pair origin of…

Chemical Physics · Physics 2025-11-18 Jerry L. Whitten

Due to efficient scaling with electron number N, density functional theory (DFT) is widely used for studies of large molecules and solids. Restriction of an exact mean-field theory to local potential functions has recently been questioned.…

Other Condensed Matter · Physics 2015-06-24 Robert K. Nesbet

We investigate the effects of inhomogeneities on spin entanglement in many-electron systems from an ab-initio approach. The key quantity in our approach is the local spin entanglement length, which is derived from the local concurrence of…

Quantum Physics · Physics 2015-03-27 S. Pittalis , F. Troiani , C. A. Rozzi , G. Vignale

We study non-linear adiabatic connection paths in density-functional theory using modified electron-electron interactions that perform a long-range/short-range separation of the Coulomb interaction. These adiabatic connections allows to…

Chemical Physics · Physics 2009-11-11 Julien Toulouse , Francois Colonna , Andreas Savin

The current work presents a natural orbital functional (NOF) for electronic systems with any spin value independent of the external potential being considered, that is, a global NOF (GNOF). It is based on a new two-index reconstruction of…

Chemical Physics · Physics 2021-12-07 Mario Piris

Two parts of an entangled quantum state can have a correlation in their joint behavior under measurements that is unexplainable by shared classical information. Such correlations are called non-local and have proven to be an interesting…

Quantum Physics · Physics 2009-03-25 Manuel Forster , Severin Winkler , Stefan Wolf

An approach to electron correlation effects in atoms that uses quantum trajectories is presented. A comparison with the exact quantum mechanical results for 1D Helium atom shows that the major features of the correlated ground state…

Atomic Physics · Physics 2025-02-07 Ivan P. Christov

By splitting the Coulomb interaction into long-range and short-range components, we decompose the energy of a quantum electronic system into long-range and short-range contributions. We show that the long-range part of the energy can be…

Chemical Physics · Physics 2009-11-10 Julien Toulouse , Francois Colonna , Andreas Savin

Quantitative simulation of electronic structure of solids requires treating local and non-local electron correlations on an equal footing. We present a new ab initio formulation of Green's function embedding which, unlike dynamical…

Materials Science · Physics 2024-10-01 Jiachen Li , Tianyu Zhu

Nonlocality is a defining feature of quantum mechanics and has long served as a key indicator of quantum resources since the formulation of Bell's inequalities. Identifying the contribution of nonlocality to extractable work remains a…

Quantum Physics · Physics 2025-12-17 B. Vigneshwar , R. Sankaranarayanan

The correlation part of the pair density is separated into two components, one of them being predominant at short electronic ranges and the other at long ranges. The analysis of the intracular part of these components permits to classify…

Chemical Physics · Physics 2019-07-10 Mireia Via-Nadal , Mauricio Rodríguez-Mayorga , Eloy Ramos-Cordoba , Eduard Matito

The ultimate goal of electronic structure calculations is to make the left and right hand sides of the titled ``equation'' as close as possible. This requires high-precision treatment of relativistic, correlation, and quantum…

Chemical Physics · Physics 2022-10-10 Wenjian Liu

Using an end-to-end differentiable implementation of the Kohn-Sham self-consistent field equations, we obtain an accurate neural network-based exchange and correlation (XC) functional of the electronic density. The functional is optimized…

Chemical Physics · Physics 2021-06-09 Sebastian Dick , Marivi Fernandez-Serra

A rich variety of non-equilibrium dynamical phenomena and processes unambiguously calls for the development of general numerical techniques to probe and estimate a complex interplay between spatial and temporal degrees of freedom in…

Quantum Physics · Physics 2025-08-26 E. A. Maletskii , I. A. Iakovlev , V. V. Mazurenko

We calculate the correlation energy of a two-dimensional homogeneous electron gas using several available approximations for the exchange-correlation kernel $f_{\rm xc}(q,\omega)$ entering the linear dielectric response of the system. As in…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 R. Asgari , M. Polini , B. Davoudi , M. P. Tosi

A novel approach to electronic correlations in magnetic crystals which takes into account a dynamical many-body effects is present. In order to to find a frequency dependence of the electron self energy, an effective quantum-impurity…

Strongly Correlated Electrons · Physics 2007-05-23 A. I. Lichtenstein , M. I. Katsnelson

Quantum nonlocality can be revealed "via local contextuality" in qudit-qudit entangled systems with $d > 2$, that is, through the violation of inequalities containing Alice-Bob correlations that admit a local description, and Alice-Alice…

Quantum Physics · Physics 2016-05-03 Debashis Saha , Adán Cabello , Sujit K. Choudhary , Marcin Pawłowski

Preparation, manipulation, and detection of strongly correlated states of quantum many body systems are among the most important goals and challenges of modern physics. Ultracold atoms offer an unprecedented playground for realization of…

Other Condensed Matter · Physics 2008-09-25 Kai Eckert , Oriol Romero-Isart , Mirta Rodriguez , Maciej Lewenstein , Eugene S. Polzik , Anna Sanpera

We review some recently published methods to represent atomic neighbourhood environments, and analyse their relative merits in terms of their faithfulness and suitability for fitting potential energy surfaces. The crucial properties that…

Computational Physics · Physics 2015-06-11 Albert P. Bartók , Risi Kondor , Gábor Csányi