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The development of differentiable invariant descriptors for accurate representations of atomic environments plays a central role in the success of interatomic potentials for chemistry and materials science. We introduce a method to generate…

Materials Science · Physics 2023-04-26 Ngoc-Cuong Nguyen

The construction of density-functional approximations is explored by modeling the adiabatic connection em locally, using energy densities defined in terms of the electrostatic potential of the exchange-correlation hole. These local models…

Chemical Physics · Physics 2016-05-04 Stefan Vuckovic , Tom Irons , Andreas Savin , Andrew M. Teale , Paola Gori-Giorgi

The recent improvement in experimental capabilities for interrogating and controlling molecular systems with ultrafast coherent light sources calls for the development of theoretical approaches that can accurately and efficiently treat…

Chemical Physics · Physics 2024-08-20 Jonathan R. Mannouch , Aaron Kelly

The aim of this work is to introduce the main concepts of Fractional Calculus, followed by one of its application to classical electrodynamics, illustrating how non-locality can be interpreted naturally in a fractional scenario. In…

Numerical Analysis · Mathematics 2021-08-31 André Persechino

The study of electronic transitions within a molecule connected to the absorption or emission of light is a common task in the process of the design of new materials. The transitions are complex quantum mechanical processes and a detailed…

Human-Computer Interaction · Computer Science 2021-06-03 Talha Bin Masood , Signe Sidwall Thygesen , Mathieu Linares , Alexei I. Abrikosov , Vijay Natarajan , Ingrid Hotz

In this work we solve thermo-hydrodynamical equations considering a two dimensional electron system in the integer quantum Hall regime, to calculate the spatial distribution of the local electron temperature. We start from the…

Mesoscale and Nanoscale Physics · Physics 2012-03-14 N. Boz Yurdaşan , K. Akgüngör , A. Siddiki , İ. Sökmen

We consider a class of quantum lattice models in $1+1$ dimensions represented as local quantum circuits that enjoy a particular "dual-unitarity" property. In essence, this property ensures that both the evolution "in time" and that "in…

Statistical Mechanics · Physics 2019-11-26 Bruno Bertini , Pavel Kos , Tomaz Prosen

We obtain the conductance of a system of electrons connected to leads, within time-dependent density-functional theory, using a direct relation between the conductance and the density response function. Corrections to the non-interacting…

Materials Science · Physics 2007-10-04 P. Bokes , J. Jung , R. W. Godby

It is shown here that Kohn-Sham equations cannot be derived from Hohenberg-Kohn theory without an additional postulate. Assuming that a functional derivative with respect to total electron density exists leads in general to a theory…

Condensed Matter · Physics 2007-05-23 R. K. Nesbet

The main goal of the present paper is to convince that it is feasible to construct a `periodic orbit theory' of localization by extending the idea of classical action correlations. This possibility had been questioned by many researchers in…

chao-dyn · Physics 2009-10-28 Doron Cohen

The design of better exchange-correlation functionals for Density Functional Theory (DFT) is a central challenge of modern electronic structure theory. However, current developments are limited by the mathematical form of the functional,…

Chemical Physics · Physics 2024-08-19 Kyle Bystrom , Boris Kozinsky

In contemporary scientific research, understanding the distinction between correlation and causation is crucial. While correlation is a widely used analytical standard, it does not inherently imply causation. This paper addresses the…

Machine Learning · Computer Science 2023-12-27 Cao Zhihao , Qu Hongchun

There is a number of explicit kinetic energy density functionals for non-interacting electron systems that are obtained in terms of the electron density and its derivatives. These semilocal functionals have been widely used in the…

Other Condensed Matter · Physics 2011-12-22 David Garcia-Aldea , J. E. Alvarellos

Understanding electron correlation is crucial for developing new concepts in electronic structure theory, especially for strongly correlated electrons. We compare and apply two different approaches to quantify correlation contributions of…

Chemical Physics · Physics 2019-07-15 Christian Stemmle , Beate Paulus

We address the question of the degree of spatial non-locality of the self energy in the iron-based superconductors, a subject which is receiving considerable attention. Using LiFeAs as a prototypical example, we extract the self energy from…

Strongly Correlated Electrons · Physics 2021-04-07 Minjae Kim , Hu Miao , Sangkook Choi , Manuel Zingl , Antoine Georges , Gabriel Kotliar

Shannon entropies of one- and two-electron atomic structure factors in the position and momentum representations are used to examine the behavior of the off-diagonal elements of density matrices with respect to the uncertainty principle and…

Quantum Physics · Physics 2009-11-13 Robin P. Sagar , Nicolais L. Guevara

Understanding of bonding is key to modelling materials and predicting properties thereof. A widely adopted indicator of bonds and atomic shells is the electron localization function (ELF). The building blocks of the ELF are also used in the…

A geometric interpretation for quantum correlations and entanglement according to a particular framework of emergent quantum mechanics is developed. The mechanism described is based on two ingredients: 1. At an hypothetical sub-quantum…

Quantum Physics · Physics 2020-07-20 Ricardo Gallego Torromé

Using time-dependent current-density functional theory, we derive analytically the dynamical exchange-correlation correction to the DC conductance of nanoscale junctions. The correction pertains to the conductance calculated in the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Na Sai , Michael Zwolak , Giovanni Vignale , Massimiliano Di Ventra

According to Popescu's recent analysis [Phys. Rev. Lett. {\bf72}, 797 (1994)], {\it nonideal} measurements, rather than ideal ones, may be more sensitive to reveal nonlocal correlations between distant parts of composite quantum systems.…

Quantum Physics · Physics 2007-05-23 Lajos Diosi