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Many atomic descriptors are currently limited by their unfavourable scaling with the number of chemical elements $S$ e.g. the length of body-ordered descriptors, such as the Smooth Overlap of Atomic Positions (SOAP) power spectrum (3-body)…

Materials Science · Physics 2022-12-07 James P. Darby , James R. Kermode , Gábor Csányi

Developing data-driven machine-learning interatomic potentials for materials containing many elements becomes increasingly challenging due to the vast configuration space that must be sampled by the training data. We study the learning…

Materials Science · Physics 2022-08-16 Jesper Byggmästar , Kai Nordlund , Flyura Djurabekova

Predicting bioactivity and physical properties of molecules is a longstanding challenge in drug design. Most approaches use molecular descriptors based on a 2D representation of molecules as a graph of atoms and bonds, abstracting away the…

Quantitative Methods · Quantitative Biology 2020-10-27 William McCorkindale , Carl Poelking , Alpha A. Lee

We review some recently published methods to represent atomic neighbourhood environments, and analyse their relative merits in terms of their faithfulness and suitability for fitting potential energy surfaces. The crucial properties that…

Computational Physics · Physics 2015-06-11 Albert P. Bartók , Risi Kondor , Gábor Csányi

We introduce machine-learned potentials for Ag-Pd to describe the energy of alloy configurations over a wide range of compositions. We compare two different approaches. Moment tensor potentials (MTP) are polynomial-like functions of…

The development of differentiable invariant descriptors for accurate representations of atomic environments plays a central role in the success of interatomic potentials for chemistry and materials science. We introduce a method to generate…

Materials Science · Physics 2023-04-26 Ngoc-Cuong Nguyen

We briefly summarize the kernel regression approach, as used recently in materials modelling, to fitting functions, particularly potential energy surfaces, and highlight how the linear algebra framework can be used to both predict and train…

Computational Physics · Physics 2019-02-05 Michele Ceriotti , Michael J. Willatt , Gábor Csányi

Machine-learning of atomic-scale properties amounts to extracting correlations between structure, composition and the quantity that one wants to predict. Representing the input structure in a way that best reflects such correlations makes…

Chemical Physics · Physics 2021-02-02 Michael J. Willatt , Félix Musil , Michele Ceriotti

Evaluating the (dis)similarity of crystalline, disordered and molecular compounds is a critical step in the development of algorithms to navigate automatically the configuration space of complex materials. For instance, a structural…

Materials Science · Physics 2020-02-06 Sandip De , Albert P. Bartók , Gábor Csányi , Michele Ceriotti

In this work, we explore the quantum chemical foundations of descriptors for molecular similarity. Such descriptors are key for traversing chemical compound space with machine learning. Our focus is on the Coulomb matrix and on the smooth…

Chemical Physics · Physics 2022-10-10 Stefan Gugler , Markus Reiher

We introduce a Gaussian approximation potential (GAP) for atomistic simulations of liquid and amorphous elemental carbon. Based on a machine-learning representation of the density-functional theory (DFT) potential-energy surface, such…

Materials Science · Physics 2017-03-08 Volker L. Deringer , Gábor Csányi

Physics-based, atom-centered machine learning (ML) representations have been instrumental to the effective integration of ML within the atomistic simulation community. Many of these representations build off the idea of atoms as having…

Computational Physics · Physics 2024-03-29 Arthur Y. Lin , Kevin K. Huguenin-Dumittan , Yong-Cheol Cho , Jigyasa Nigam , Rose K. Cersonsky

We present an accurate machine learning (ML) model for atomistic simulations of carbon, constructed using the Gaussian approximation potential (GAP) methodology. The potential, named GAP-20, describes the properties of the bulk crystalline…

Computational Physics · Physics 2020-08-26 Patrick Rowe , Volker L Deringer , Piero Gasparotto , Gábor Csányi , Angelos Michaelides

Physically-motivated and mathematically robust atom-centred representations of molecular structures are key to the success of modern atomistic machine learning (ML) methods. They lie at the foundation of a wide range of methods to predict…

The applications of machine learning techniques to chemistry and materials science become more numerous by the day. The main challenge is to devise representations of atomic systems that are at the same time complete and concise, so as to…

Chemical Physics · Physics 2025-10-06 Michael J. Willatt , Felix Musil , Michele Ceriotti

The formulation of descriptors of the local chemical environment, enabling the construction of machine-learning models, is usually obtained by studying the properties of the expansion coefficients of a neighborhood density. In this work, we…

Chemical Physics · Physics 2025-08-07 Michelangelo Domina , Stefano Sanvito

Machine learning of the quantitative relationship between local environment descriptors and the potential energy surface of a system of atoms has emerged as a new frontier in the development of interatomic potentials (IAPs). Here, we…

A natural extension of the descriptors used in the Spectral Neighbor Analysis Potential (SNAP) method is derived to treat atomic interactions in chemically complex systems. Atomic environment descriptors within SNAP are obtained from a…

Chemical Physics · Physics 2020-09-09 Mary Alice Cusentino , Mitchell A. Wood , Aidan P. Thompson

We introduce the proper orthogonal descriptors for efficient and accurate interatomic potentials of multi-element chemical systems. The potential energy surface of a multi-element system is represented as a many-body expansion of…

Chemical Physics · Physics 2024-05-01 Ngoc-Cuong Nguyen

We have analysed structural motifs in the Deem database of hypothetical zeolites, to investigate whether the structural diversity found in this database can be well-represented by classical descriptors such as distances, angles, and ring…

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