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Neutron and x-ray diffraction techniques have been used to study the competing long and short-range polar order in the relaxor ferroelectric Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) under a [111] applied electric field. Despite reports of a…

Materials Science · Physics 2009-11-13 C. Stock , Guangyong Xu , P. M. Gehring , H. Luo , X. Zhao , H. Cao , J. F. Li , D. Viehland , G. Shirane

Single crystals of a ternary relaxor ferroelectric system, 0.29Pb(In1/2Nb1/2)O3-0.45Pb(Mg1/3Nb2/3)O3-0.26PbTiO3, have been studied using triple-axis based elastic and inelastic neutron scattering. Elastic diffuse scattering confirms the…

Materials Science · Physics 2022-08-10 Qian Li , Sergey Danilkin , Guochu Deng , Jian Wang , Zhengrong Li. Ray L. Withers , Zhuo Xu , Yun Liu

Neutron scattering measurements of the lowest-energy TO phonons in the relaxor Pb(Mg1/3Nb2/3)O3 (PMN) are reported for 10<=T<=750 K. The soft mode, which is overdamped by the polar nanoregions below the Burns temperature T_d = 620 K,…

Materials Science · Physics 2009-11-07 S. Wakimoto , C. Stock , R. J. Birgeneau , Z. -G. Ye , W. Chen , W. J. L. Buyers , P. M. Gehring , G. Shirane

High-pressure and variable temperature single crystal synchrotron X-ray measurements combined with first-principles based molecular dynamics simulations study diffuse scattering in the relaxor ferroelectric system PSN…

Materials Science · Physics 2015-05-13 P. Ganesh , E. Cockayne , M. Ahart , R. E. Cohen , B. Burton , R. J. Hemley , Yang Ren , Wenge Yang , Z-G Ye

Pb-based perovskites with multiple cations are fascinating materials showing various phenomena such as high piezoelectric, electromechanical, and relaxor properties. While chemical disordering accompanied by polar nanoregions and nanosized…

The microstructure and phase transition in relaxor ferroelectric Pb(Mg1/3Nb2/3)O3 (PMN) and its solid solution with PbTiO3 (PT), PMN-xPT, remain to be one of the most puzzling issues of solid state science. In the present work we have…

Materials Science · Physics 2009-11-07 Z. -G. Ye , Y. Bing , J. Gao , A. A. Bokov , P. Stephens , B. Noheda , G. Shirane

We report high $q$-resolution neutron scattering data on PMN-$x$PT single crystals with $x=20%$ and 27%. No rhombohedral distortion occurs in the 20PT sample for temperatures as low as 50 K. On the other hand, the 27PT sample transforms…

Materials Science · Physics 2007-05-23 Guangyong Xu , D. Viehland , J. F. Li , P. M. Gehring , G. Shirane

In ferroelectric materials, an electric field has been shown to change the phonon dispersion sufficiently to alter the lattice thermal conductivity, opening the possibility that a heat gradient could drive a polarization flux, and…

Materials Science · Physics 2025-01-08 Delaram Rashadfar , Brandi L. Wooten , Joseph P. Heremans

We propose a simple and solvable mean-field model of the scattering of transverse optic modes by Polarized Nano Regions (PNR) in the paraelectric phase of relaxor ferroelectrics. The PNR is assumed to be a ferroelectric sphere embedded in…

Materials Science · Physics 2010-07-22 E. Iolin , J. Toulouse

Ferroelectric soft mode in Pb(Mg1/3Nb2/3)O3 (PMN) has been clearly resolved by precision Raman scattering measurements for the first time. A polarization direction of the incident laser was chosen along [110] in cubic configuration in order…

Materials Science · Physics 2009-09-23 Hiroki Taniguchi , Masanori Oishi , Desheng Fu , Mitsuru Itoh

Recently, a new orthorhombic phase has been discovered in the ferroelectric system Pb(Zn1/3Nb2/3)O3-xPbTiO3 (PZN-xPT) for x= 9%, and for x= 8% after the application of an electric field. In the present work, synchrotron x-ray measurements…

Materials Science · Physics 2009-11-07 D. La-Orauttapong , B. Noheda , Z. -G. Ye , P. M. Gehring , J. Toulouse , D. E. Cox , G. Shirane

Relaxor ferroelectrics are applied in electronic devices such as actuators and sonars. Morphotrophic phase boundaries (MPBs) with monoclinic structures are known for their high piezoelectricity and electromechanical coupling factors in…

We review results obtained from recent neutron scattering studies of the lead-oxide class of perovskite relaxors PMN and PZN. A ferroelectric soft mode has been identified in PMN at 1100 K that becomes overdamped near 620 K. This is the…

Materials Science · Physics 2009-11-07 P. M. Gehring , S. Wakimoto , Z. -G. Ye , G. Shirane

Synchrotron x-ray scattering studies of anti-ferroelectric nanoregions (AFR) as fluctuations, which give rise to 1/2(hk0) superlattice reflections (alpha spots), were systematically performed in Pb(Mg1/3Nb2/3)O3 (PMN) ferroelectric relaxor.…

Materials Science · Physics 2007-05-23 A. Tkachuk , Haydn Chen

Raman scattering in relaxor ferroelectric PbMg1/3Ta2/3O3 (PMT) was investigated in the single crystalline form in the temperature range of 20 - 295 K. Anomalous temperature dependence of the integrated intensity and the Raman line contours…

Materials Science · Physics 2007-05-23 S. G. Lushnikov , S. N. Gvasaliya , R. S. Katiyar

We have performed polarized and unpolarized small angle neutron scattering experiments on single crystals of HoMnO3 and have found that an increase in magnetic scattering at low momentum transfers begins upon cooling through temperatures…

Strongly Correlated Electrons · Physics 2015-05-14 B. G. Ueland , J. W. Lynn , M. Laver , Y. J. Choi , S. W. Cheong

Diffuse scattering around the (110) reciprocal lattice point has been investigated by elastic neutron scattering in the paraelectric and the relaxor phases of the disordered complex perovskite crystal-Pb(Zn1/3Nb2/3)O3(PZN). The appearance…

Materials Science · Physics 2009-11-07 D. La-Orauttapong , J. Toulouse , J. L. Robertson , Z. -G. Ye

Dielectric, anelastic and ^139La NMR relaxation measurements have been made on the relaxor ferroelectric Pb(1-3x/2)La(x)Zr(0.2)Ti(0.8)O(3) (PLZT) with x = 0.22. The dielectric susceptibility exihibits the frequency dispersive maximum due to…

Materials Science · Physics 2010-07-23 F. Cordero , M. Corti , F. Craciun , C. Galassi , D. Piazza , F. Tabak

We report lattice dynamical measurements, made using neutron inelastic scattering methods, of the relaxor perovskite PbMg1/3Nb2/3O3 (PMN) at momentum transfers near the edge of the Brillouin zone. Unusual"columns" of phonon scattering that…

Materials Science · Physics 2015-05-13 I. P. Swainson , C. Stock , P. M. Gehring , Guangyong Xu , K. Hirota , Y. Qiu , H. Luo , X. Zhao , J. -F. Li , D. Viehland

Relaxor ferroelectrics are difficult to study and understand. The experiment shows that at low energy scattering there is an acoustic mode, an optic mode, dynamic quasi-elastic scattering and strictly elastic scattering as well as Bragg…

Materials Science · Physics 2008-08-29 R. A. Cowley , S. N. Gvasaliya , B. Roessli