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Thermal quenching (TQ) generally occurs in phosphors and is ascribed to the activation of non-radiative transitions at elevated temperatures. This effect limits the use of most phosphors in high-power/high-temperature applications, such as…

Materials Science · Physics 2026-02-27 Baowei Zhang , Liberato Manna

Understanding the physical mechanisms behind thermal effects in phosphors is crucial for white light-emitting diodes (WLEDs) applications, as thermal quenching of their photoluminescence might render them useless. The two chemically close…

Materials Science · Physics 2015-08-26 Samuel Ponce , Yongchao Jia , Matteo Giantomassi , Masayoshi Mikami , Xavier Gonze

In this manuscript we present a computational study on the photoluminescence properties of several heteroleptic [Ru(H)(CO)(N^N)(tpp)2]+ complexes (tpp = triphenylphosphine). A special focus is set on disentangling the temperature-dependent…

Chemical Physics · Physics 2019-01-07 Denis Jacquemin , Daniel Escudero

The luminescence of fifteen representative Eu$^{2+}$-doped phosphors used for white-LED and scintillation applications is studied through a Constrained Density Functional Theory. Transition energies and Stokes shift are deduced from…

Materials Science · Physics 2017-09-20 Yongchao Jia , Anna Miglio , Samuel Poncé , Masayoshi Mikami , Xavier Gonze

Currently,lanthanide ions doped luminescence materials applying as optical thermometers have arose much concern. Basing on the different responses of two emissions to temperature, the fluorescence intensity ratio (FIR) technique can be…

Materials Science · Physics 2023-02-22 Yude Niu , Yuzhen Wang , Kaiming Zhu , Wanggui Ye , Zhe Feng , Hui Liu , Xin Yi , Yihuan Wang , Xuanyi Yuan

There has been a stringent demand for blue (~450-470 nm) absorbing and red (~611 nm) emitting material system in phosphor converted white light emitting diodes (WLEDs) available in the market. Conventionally used red-emitting…

The temperature dependence of the complex optical properties of the layered phosphide material EuCd$_2$P$_2$ have been measured over a wide frequency range above and below $T_{\rm N} \simeq 11.5$ K for light polarized in the $a-b$ planes.…

Strongly Correlated Electrons · Physics 2023-03-23 C. C. Homes , Z. -C. Wang , K. Fruhling , F. Tafti

The synthesis, structural, and luminescence properties have been carried out for Cr3+-activated Al2(WO4)3 (AWO) and Sc2(WO4)3 (SWO) phosphors for application in pc-NIR LED. Upon blue excitation, these compounds are capable of exhibiting…

We develop Dy$^{3+}$-doped yttrium complexes for use as two-color thermometry (TCT) phosphor molecular crystals in heterogeneous materials. These complexes include: Dy:Y(acac)$_3$(phen), Dy:Y(hfa)$_3$(DPEPO), Dy:Y(4-BBA)$_3$(TPPO),…

Chemical Physics · Physics 2017-06-09 Benjamin R. Anderson , Ray Gunawidjaja , Hergen Eilers

Phosphorus-doped diamond is relevant for applications in sensing, optoelectronics and quantum photonics, since the unique optical properties of color centers in diamond can be combined with the n-type conductivity attained by the inclusion…

White light-emitting diodes are gaining popularity and are set to become the most common light source in the U.S. by 2025. However, their performance is still limited by the lack of an efficient red-emitting component with a narrow band…

Materials Science · Physics 2023-07-10 Julien Bouquiaux , Samuel Poncé , Yongchao Jia , Anna Miglio , Masayoshi Mikami , Xavier Gonze

White light tunable phosphors are obtained from a sol-gel derived siliceous network to which oxyethylene units are covalently grafted by means of urea or urethane cross-linkages. The bright photoluminescence is ascribed to an unusual…

Materials Science · Physics 2007-05-23 L. D. Carlos , R. A. Sa Ferreira , V. De Zea Bermudez , Sidney J. L. Ribeiro

An experimental observation on irreversible thermal quenching and antiquenching behavior is reported for photoluminescence (PL) of ZnS/CdS:Mn/ZnS quantum well quantum dots (QWQDs) prepared with a reverse micelle method. The dual-color…

Materials Science · Physics 2013-09-20 X. Ding , R. C. Dai , Z. Zhao , Z. P. Wang , Z. Q. Sun , Z. M. Zhang , Z. J. Ding

To explain the effect of electron density saturation at high phosphorus concentrations the model of negatively charged phosphorus clusters was compared with the experimental data. A number of negatively charged clusters incorporating a…

Materials Science · Physics 2011-09-20 O. I. Velichko , N. A. Sobolevskaya

We report operating temperatures and heating coefficients measured in a multi-layer black phosphorus device as a function of injected electrical power. By combining micro-Raman spectroscopy and electrical transport measurements, we have…

Materials Science · Physics 2015-12-15 Michael Engel , Mathias Steiner , Shu-Jen Han , Phaedon Avouris

Currently available temperature measurements or imaging at nano-micro scale are limited to fluorescent molecules and luminescent nanocrystals, whose spectral properties respond to temperature variation. The principle of operation of these…

To date, the intrinsic thermal conductivity tensor of bulk black phosphorus (BP), an important 2D material, is still unknown, since recent studies focus on BP flakes not on bulk BP. Here we report the anisotropic thermal conductivity tensor…

Materials Science · Physics 2016-11-22 Bo Sun , Xiaokun Gu , Qingsheng Zeng , Xi Huang , Yuexiang Yan , Zheng Liu , Ronggui Yang , Yee Kan Koh

This study investigates the temperature-dependent quasi-static magnetoelectric (ME) response of electrically poled lead-free Na$_{0.4}$K$_{0.1}$Bi$_{0.5}$TiO$_3$-NiFe$_2$O$_4$ (NKBT-NFO) laminated composites. The aim is to understand the…

Developing phosphors with narrow photoluminescence emission peaks and high chromatic stability holds significant importance in light-emitting diode (LED) display technologies, where a wide color gamut is essential to achieve the Rec. 2020…

Materials Science · Physics 2025-03-04 Nakyung Lee , Justyna Zeler , Małgorzata Sójka , Eugeniusz Zych , Jakoah Brgoch

In the current work, a novel class of (Ca0.9Si0.1)Al2O6:Eu2+,Nd3+ long persistent phosphor was synthesized using high-temperature (1000-1500oC) solid-state reaction method. Further, the phosphor material was formulated into a phosphorescent…

Applied Physics · Physics 2020-02-20 Vishnu V. Jaiswal , D. Haranath
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