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From a simplified version of the mathematical structure of the strong coupling limit of the exact exchange-correlation functional, we construct an approximation for the electronic repulsion energy at physical coupling strength, which is…

Chemical Physics · Physics 2017-05-11 Stefan Vuckovic , Paola Gori-Giorgi

The properties of excitons, or correlated electron-hole pairs, are of paramount importance to optoelectronic applications of materials. A central component of exciton physics is the electron-hole interaction, which is commonly treated as…

In order to realize the significant potential of optical materials such as metal halides, computational techniques which give accurate optical properties are needed, which can work hand-in-hand with experiments to generate high efficiency…

Materials Science · Physics 2021-03-04 Jamie M. Booth , Mike V. Klymenko , Jared H. Cole , Salvy P. Russo

A complete knowledge of its excitation spectrum could greatly benefit efforts to understand the unusual form of superconductivity occurring in the lightly hole-doped copper-oxides. Here we use tunnelling spectroscopy to measure the T\to 0…

The problem of calculating of the mass spectrum of the two-body Bethe-Salpeter equation is studied with no reduction to the three-dimensional ("quasipotential") equation. The method to find the ground state and excited states for a channel…

High Energy Physics - Phenomenology · Physics 2015-06-25 A. Yu. Umnikov , F. C. Khanna

The nonequilibrium total dielectric function lends itself to a simple and general method for calculating the inelastic collision term in the electron Boltzmann equation for scattering from a coupled mode system. Useful applications include…

Condensed Matter · Physics 2007-05-23 B. A. Sanborn

The electronic excitation of a conjugated molecule-insulator interface, as exemplified by the adsorption of benzoic acid and its phenolic derivative on NaCl(001) surface, is addressed by many-body Green's function methods. By solving the…

Mesoscale and Nanoscale Physics · Physics 2011-03-23 Wei Chen , Christoph Tegenkamp , Herbert Pfnür

The Bethe-Salpeter equation (BSE) combined with the Green's function GW method has successfully transformed into a robust computational tool to describe light-matter interactions and excitation spectra for molecules, solids, and materials…

Chemical Physics · Physics 2025-04-18 Christof Holzer , Yannick J. Franzke

In density functional theory the exchange-correlation (XC) energy functional can be defined exactly through the coupling-constant ($\lambda$) averaged XC hole $\bar{n}_\text{xc}(\mathbf{r},\mathbf{r}')$, representing the probability…

Chemical Physics · Physics 2023-03-31 Lin Hou , Tom J. P. Irons , Yanyong Wang , James W. Furness , Andrew M. Teale , Jianwei Sun

$\alpha$-Li$_x$V$_2$O$_5$ is obtained by intercalating Li between the layers of V$_2$O$_5$. The partial filling of the split-off conduction band by electron donation from Li leads to significant changes in optical properties. Here we study…

Materials Science · Physics 2025-07-16 Claudio Garcia , Walter R. L. Lambrecht

A systematic method of calculating the dynamical conductivity tensor in a general multiband electronic model with strong boson-mediated electron-electron interactions is described. The theory is based on the exact semiclassical expression…

Strongly Correlated Electrons · Physics 2013-03-13 I. Kupcic , Z. Rukelj , S. Barisic

We discuss a variety of many-body approaches, within effective-mass and $\mathbf{k}\cdot\mathbf{p}$ envelope-function formalisms, for calculating correlated single excitons in semiconductor nanocrystals (NCs) to all orders in the…

Mesoscale and Nanoscale Physics · Physics 2022-04-28 S. A. Blundell , C. Guet

We study the optical absorption spectra of small Ag_n (n=2,4,6,8) clusters using the Bethe-Salpeter equation (BSE) formalism with a Hamiltonian built from GW quasiparticle energies. Calculations are based on an effective core potential…

Materials Science · Physics 2026-01-16 Xavier Blase , Ivan Duchemin

We show that electron-hole correlation can be used to tune interband and intraband optical transition rates in semiconductor nanostructures with at least one weakly confined direction. The valence-to-conduction band transition rate can be…

Mesoscale and Nanoscale Physics · Physics 2018-08-24 Josep Planelles , Alexander W. Achtstein , Riccardo Scott , Nina Owschimikow , Juan I. Climente

Absorption of electromagnetic energy by a dissipative material is one of the most fundamental electromagnetic processes that underlies a plethora of applied problems, including sensing and molecular detection, radar detection, wireless…

Optics · Physics 2020-03-31 Alexey Proskurin , Andrey Bogdanov , Denis G. Baranov

We review the Bethe-Salpeter equation (BSE) approach to the calculation of electronic excitation energies of molecular systems. We recall the general Green's function many-theory formalism and give the working equations of the BSE approach…

Chemical Physics · Physics 2013-04-05 Elisa Rebolini , Julien Toulouse , Andreas Savin

We study within the many-body Green's function GW and Bethe-Salpeter approaches the neutral singlet excitations of the zinctetraphenylporphyrin and C70 fullerene donor-acceptor complex. The lowest transition is a charge-transfer excitation…

Materials Science · Physics 2015-06-12 Ivan Duchemin , Xavier Blase

An ab initio approach to the calculation of excitonic effects in the optical absorption spectra of semiconductors and insulators is formulated. It starts from a quasiparticle bandstructure calculation and is based on the relevant…

Condensed Matter · Physics 2016-08-31 Stefan Albrecht , Lucia Reining , Rodolfo Del Sole , Giovanni Onida

We apply quantum continuum mechanics to the calculation of the excitation spectrum of a coupled electron-hole bilayer. The theory expresses excitation energies in terms of ground-state intra- and inter-layer pair correlation functions,…

Strongly Correlated Electrons · Physics 2021-10-04 S. De Palo , P. E. Trevisanutto , G. Senatore , G. Vignale

Excitons in the weakly interacting regime can be well-described by many-body perturbation theories such as the Bethe-Salpeter equation formalism. However, for materials such as transition metal dichalcogenides moir\'e heterostructures under…

Materials Science · Physics 2026-03-16 Fangzhou Zhao , Carlos Mejuto-Zaera , Angel Rubio , Vojtěch Vlček