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Material science methods aim at developing efficient computational schemes for describing complex many-body effects and how they are revealed in experimentally measurable properties. Bethe-Salpeter equation in the self-consistent…

Strongly Correlated Electrons · Physics 2024-02-27 I. S. Tupitsyn , N. V. Prokof'ev

In this work we present a new procedure to compute optical spectra including excitonic effects and approximated quasiparticle corrections with reduced computational effort. The excitonic effects on optical spectra are included by solving…

Materials Science · Physics 2020-08-26 Filipe Matusalem , Marcelo Marques , Ivan Guilhon , Lara K. Teles

The Bethe-Salpeter equation (BSE) is currently the state of the art in the description of neutral electron excitations in both solids and large finite systems. It is capable of accurately treating charge-transfer excitations that present…

The Bethe-Salpeter equation (BSE) formalism is steadily asserting itself as a new efficient and accurate tool in the ensemble of computational methods available to chemists in order to predict optical excitations in molecular systems. In…

Chemical Physics · Physics 2020-08-26 Xavier Blase , Ivan Duchemin , Denis Jacquemin , Pierre-François Loos

We present a method to compute optical spectra and exciton binding energies of molecules and solids based on the solution of the Bethe-Salpeter equation (BSE) and the calculation of the screened Coulomb interaction in finite field. The…

Materials Science · Physics 2019-06-19 Ngoc Linh Nguyen , He Ma , Marco Govoni , Francois Gygi , Giulia Galli

We study the core hole-electron correlation in coherently coupled molecules by energy dispersive near edge X-ray absorption fine-structure spectroscopy. In a transient phase, which exists during the transition between two bulk arrangements,…

Materials Science · Physics 2013-12-03 M. Scholz , F. Holch , C. Sauer , M. Wiessner , A. Schöll , F. Reinert

The Bethe-Salpeter equation is a widely used approach to describe optical excitations in bulk semiconductors. It leads to spectra that are in very good agreement with experiment, but the price to pay for such accuracy is a very high…

The GW plus Bethe-Salpeter equation (GW-BSE) formalism is a well-established approach for calculating excitation energies and optical spectra of molecules, nanostructures, and crystalline materials. We implement GW-BSE in the CP2K code and…

Computational Physics · Physics 2026-05-29 Maximilian Graml , Jan Wilhelm

We present calculations of the absorption spectrum of semiconductors and insulators comparing various approaches: (i) the two-particle Bethe-Salpeter equation of Many-Body Perturbation Theory; (ii) time-dependent density-functional theory…

Other Condensed Matter · Physics 2009-11-13 Francesco Sottile , Marherita Marsili , Valerio Olevano , Lucia Reining

The electron-hole correlation length serves as an intrinsic length scale for analyzing excitonic interactions in semiconductor nanoparticles. In this work, the derivation of electron-hole correlation length using the two-particle reduced…

Atomic and Molecular Clusters · Physics 2014-06-03 Christopher J. Blanton , Arindam Chakraborty

Here we describe an efficient numerical implementation of the Bethe-Salpeter equation to obtain the excitonic spectrum of semiconductors. This is done on the electronic structure calculated either at the simplest tight-binding level or…

Theoretical spectroscopy, and more generally, electronic-structure theory, are powerful concepts for describing the complex many-body interactions in materials. They comprise a variety of methods that can capture all aspects, from…

We study the combined impact of random disorder and electron-electron, and electron-hole interactions on the absorption spectra of a three-dimensional Hubbard Hamiltonian. We determine the single-particle Green's function within the typical…

Strongly Correlated Electrons · Physics 2018-08-24 C. E. Ekuma

Absorption spectra, exciton energy levels and wave functions for solid Ne and Ar have been calculated from first principles using many-body techniques. Electronic band structures of Ne and Ar were calculated using the GW approximation.…

Other Condensed Matter · Physics 2009-11-10 S. Galamic-Mulaomerovic , C. H. Patterson

Absorption spectra of closed-shell Na_2, Na_3+, Na_4, Na_5+, Na_6, Na_7+, and Na_8 clusters are calculated using a recently implemented conserving linear response method. In the framework of a quasiparticle approach, we determine…

Materials Science · Physics 2015-05-14 George Pal , Georgios Lefkidis , Hans Christian Schneider , Wolfgang Huebner

Self-consistent Hartree-Fock approximation combined with solutions of the Bethe-Salpeter equation offers a powerful tool for studies of strong correlation effects arising in condensed matter models, nuclear physics, quantum field theories,…

Strongly Correlated Electrons · Physics 2024-02-06 I. S. Tupitsyn , N. V. Prokof'ev

An ab initio approach is presented for studying the collective excitations in excitonic insulators, charge/spin density waves and superconductors. We derive the Bethe-Salpeter-Equation for the particle-hole excitations in the quasiparticle…

Materials Science · Physics 2026-01-09 Fengyuan Xuan , Jiexi Song , Zhiyuan Sun

Given the growing significance of 2D materials in various optoelectronic applications, it is imperative to have simulation tools that can accurately and efficiently describe electron correlation effects in these systems. Here, we show that…

Strongly Correlated Electrons · Physics 2023-08-14 Oinam Romesh Meitei , Troy Van Voorhis

The emission from galactic black holes and Seyfert galaxies is generally understood in term of two-phase models (Haardt and Maraschi 1991, 1993). Such models postulate that a hot plasma coexists with relatively colder material in the inner…

Astrophysics · Physics 2009-11-10 Julien Malzac , Anne-Marie Dumont , Martine Mouchet

The Bethe-Salpeter formalism represents the most accurate method available nowadays for computing neutral excitation energies and optical spectra of crystalline systems from first principles. Bethe-Salpeter calculations yield very good…

Materials Science · Physics 2016-05-04 Yannick Gillet , Matteo Giantomassi , Xavier Gonze