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We propose enhancing trajectory optimization methods through the incorporation of two key ideas: variable-grasp pose sampling and trajectory commitment. Our iterative approach samples multiple grasp poses, increasing the likelihood of…

Robotics · Computer Science 2023-05-23 Jiahe Pan , Kerry He , Jia Ming Ong , Akansel Cosgun

Several approximations are tested by calculating the ground-state energy and the energy of the first excited $0^{+}$ state using an exactly solvable model with two symmetric levels interacting via a pairing force. They are the BCS…

Nuclear Theory · Physics 2009-09-29 Nguyen Dinh Dang

To understand the dynamics of quantum many-body systems, it is essential to study excited eigenstates. While tensor network states have become a standard tool for computing ground states in computational many-body physics, obtaining…

Chemical Physics · Physics 2025-10-24 Madhumita Rano , Henrik R. Larsson

There is longstanding fundamental interest in 6-fold coordinated $d^6$ ($t_{2g}^6$) transition metal complexes such as [Ru(bpy)$_3$]$^{2+}$ and Ir(ppy)$_3$, particularly their phosphorescence. This interest has increased with the growing…

Chemical Physics · Physics 2016-06-16 B. J. Powell

This work presents a computationally lightweight motion planner for over-actuated platforms. For this purpose, a general state-space model for mobile platforms with several kinematic chains is defined, which considers non-linearities and…

Robotics · Computer Science 2023-04-26 G. J. Paz-Delgado , C. J. Pérez-del-Pulgar , M. Azkarate , F. Kirchner , A. García-Cerezo

Density functional theory can be extended to excited states by means of a unified variational approach for passive state ensembles. This extension overcomes the restriction of the typical density functional approach to ground states, and…

Chemical Physics · Physics 2019-07-10 Tim Gould , Stefano Pittalis

We introduce an approach to improve single-reference coupled cluster theory in settings where the Aufbau determinant is absent from or plays only a small role in the true wave function. Using a de-excitation operator that can be efficiently…

Chemical Physics · Physics 2024-07-03 Harrison Tuckman , Eric Neuscamman

We propose a new block localized excitation (BLE) method to directly construct diabatic excited states without the need to first compute the adiabatic states. The new method is capable to keep any electrons, spins, and excitations localized…

Chemical Physics · Physics 2020-01-22 Peng Bao , Qiang Shi , Jiali Gao

In equilibrium, the collective behaviour of particles interacting via steep, short-ranged potentials is well captured by the virial expansion of the free energy at low density. Here, we extend this approach beyond equilibrium to the case of…

Soft Condensed Matter · Physics 2023-06-21 Yuting Irene Li , Rosalba Garcia-Millan , Michael E. Cates , Étienne Fodor

We reexamine $\Delta$CCSD, a state-specific coupled-cluster (CC) with single and double excitations (CCSD) approach that targets excited states through the utilization of non-Aufbau determinants. This methodology is particularly efficient…

Chemical Physics · Physics 2024-06-13 Yann Damour , Anthony Scemama , Denis Jacquemin , Fábris Kossoski , Pierre-François Loos

We present a novel numerical approach to track the response of a quantum system to an external perturbation that is progressively switched-on. The method is applied, within the framework of the density matrix renormalization group…

Strongly Correlated Electrons · Physics 2013-09-27 M. Moliner , P. Schmitteckert

Motivated by the recent experiments that reported signatures of many-body localization of ultracold atoms in optical lattices [M. Schreiber {\it et al.}, Science {\bf 349}, 842 (2015)], we study dynamics of highly excited states in the…

Strongly Correlated Electrons · Physics 2019-03-13 Ivan Protopopov , Dmitry Abanin

We present an efficient particle-particle random phase approximation (ppRPA) approach that predicts accurate excitation energies of point defects, including the nitrogen-vacancy (NV$^-$) and the silicon-vacancy (SiV$^0$) centers in diamond…

Chemical Physics · Physics 2024-03-13 Jiachen Li , Yu Jin , Jincheng Yu , Weitao Yang , Tianyu Zhu

We present a dynamical simulation scheme to model the highly correlated excited state dynamics of linear polyenes. We apply it to investigate the internal conversion processes of carotenoids following their photoexcitation. We use the…

Chemical Physics · Physics 2023-07-19 Dilhan Manawadu , Darren J. Valentine , William Barford

Artificial neural networks have been recently introduced as a general ansatz to compactly represent many- body wave functions. In conjunction with Variational Monte Carlo, this ansatz has been applied to find Hamil- tonian ground states and…

Strongly Correlated Electrons · Physics 2018-10-24 Kenny Choo , Giuseppe Carleo , Nicolas Regnault , Titus Neupert

In this letter, we report on the time- and space-resolved measurement of subradiant excited state population in an ultra-cold atomic cloud of 174Yb atoms. We use a depletion imaging technique that exploits the V-type internal energy…

Recent years have seen an explosion of interest in organic radicals due to their promise for highly efficient organic light-emitting diodes (OLEDs) and molecular qubits. However, accurately and inexpensively computing their electronic…

Chemical Physics · Physics 2024-05-17 James D. Green , Timothy J. H. Hele

We show that the numerical results contained in a recent paper are affected by a non optimal implementation of the methods which have been used to obtain these results. A careful analysis done using the Rayleigh-Ritz method provides a…

Materials Science · Physics 2011-04-05 Paolo Amore

Neural network quantum states are a promising tool to analyze complex quantum systems given their representative power. It can however be difficult to optimize efficiently and effectively the parameters of this type of ansatz. Here we…

Quantum Physics · Physics 2023-05-10 Wenxuan Zhang , Xiansong Xu , Zheyu Wu , Vinitha Balachandran , Dario Poletti

Multi-task learning has gained popularity due to the advantages it provides with respect to resource usage and performance. Nonetheless, the joint optimization of parameters with respect to multiple tasks remains an active research topic.…

Computer Vision and Pattern Recognition · Computer Science 2021-06-01 Lucas Pascal , Pietro Michiardi , Xavier Bost , Benoit Huet , Maria A. Zuluaga