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We extend ground-state density-functional theory to excited states and provide the theoretical formulation for the widely used $\Delta SCF$ method for calculating excited-state energies and densities. As the electron density alone is…

Chemical Physics · Physics 2024-03-08 Weitao Yang , Paul W. Ayers

Accurate and efficient simulation of excited state properties is an important and much aspired cornerstone in the study of adsorbate dynamics on metal surfaces. To this end, the recently proposed linear expansion \Delta Self-Consistent…

Materials Science · Physics 2013-07-23 Reinhard J. Maurer , Karsten Reuter

In order to study the structure of excited states we perform a variational calculation after spin parity projection (VAP) within the framework of Antisymmetrized Molecular Dynamics (AMD). The framework is proven to be a new powerful…

Nuclear Theory · Physics 2009-11-07 Y. Kanada-En'yo

We describe a method to observe the dynamics of an excited-state transition in a room temperature atomic vapor using hyperfine quantum beats. Our experiment using cesium atoms consists of a pulsed excitation of the D2 transition, and…

We discuss the production of ultracold molecules in their electronic ground state by photoassociation employing electronically excited states with ion-pair character and strong spin-orbit interaction. A short photoassociation laser pulse…

Excited-state quantum phase transitions depend on and reveal the structure of the whole spectrum of many-body systems. While they are theoretically well understood, finding suitable signatures and detect them in actual experiments remains…

Quantum Gases · Physics 2022-01-19 Josep Cabedo , Alessio Celi

Calculations of the lowest valence {\pi}* as well as the 3s and higher energy 3p{\sigma} Rydberg excited states of the CO2 molecule are carried out using density functionals with variational optimization of the orbitals, an approach…

Chemical Physics · Physics 2026-04-08 Darío Barreiro-Lage , Gianluca Levi , Hannes Jonssón , Thanja Lamberts

The density of states of continuous models is known to span many orders of magnitudes at different energies due to the small volume of phase space near the ground state. Consequently, the traditional Wang-Landau sampling which uses the same…

Statistical Mechanics · Physics 2013-11-20 Yang Wei Koh , Hwee Kuan Lee , Yutaka Okabe

Based on a parametric point-wise decomposition, a kind of isospectral deformation, of the exact one-particle probability density of an externally confined, analytically solvable interacting two-particle model system we introduce the…

Quantum Physics · Physics 2014-06-12 C. L. Benavides-Riveros , I. Nagy

Based on the work of Gorling and that of Levy and Nagy, density-functional formalism for many Fermionic excited-states is explored through a careful and rigorous analysis of the excited-state density to external potential mapping. It is…

Materials Science · Physics 2009-11-11 Prasanjit Samal , Manoj K. Harbola

Recent developments in attosecond spectroscopy yield access to the correlated motion of electrons on their intrinsic time scales. Spin-flip dynamics is usually considered in the context of valence electronic states, where spin-orbit…

Atomic and Molecular Clusters · Physics 2017-08-02 H. Wang , S. I. Bokarev , S. G. Aziz , O. Kühn

Standard variational methods tend to obtain upper bounds on the ground state energy of quantum many-body systems. Here we study a complementary method that determines lower bounds on the ground state energy in a systematic fashion, scales…

Quantum Physics · Physics 2015-05-28 Tillmann Baumgratz , Martin B. Plenio

The motional electric field experienced by an H2+ ion moving in a magnetic field induces an electric dipole, so that one-photon dipole transitions between rovibrational states become allowed. Field induced spontaneous decay rates are…

Atomic Physics · Physics 2018-12-12 Jean-Philippe Karr

We examine some excited state energies in the non-unitary integrable quantum field theory obtained from the perturbation of the minimal conformal field theory model $M_{3,5}$ by its operator $\phi_{2,1}$. Using the correspondence of this…

High Energy Physics - Theory · Physics 2011-02-11 R. M. Ellem , V. V. Bazhanov

General positivity constraints linking various powers of observables in energy eigenstates can be used to sharply locate acceptable regions for the energy eigenvalues, provided that efficient recursive methods are available to calculate the…

High Energy Physics - Theory · Physics 2023-12-22 Zane Ozzello , Yannick Meurice

We study the trajectories of a single colloidal particle as it hops between two energy wells A and B, which are sculpted using adjacent optical traps by controlling their respective power levels and separation. Whereas the dynamical…

Data Analysis, Statistics and Probability · Physics 2008-03-05 David Wu , Kingshuk Ghosh , Mandar Inamdar , Heun Jin Lee , Scott Fraser , Ken Dill , Rob Phillips

In this paper we study the problem of designing periodic orbits for a special class of hybrid systems, namely mechanical systems with underactuated continuous dynamics and impulse events. We approach the problem by means of optimal control.…

Optimization and Control · Mathematics 2017-02-16 Sara Spedicato , Giuseppe Notarstefano

We exploit balancing the complex optical energy between scattering and guiding states at contrived exceptional points of degeneracy in order to form an active waveguide without utilizing an active medium. This study reports peculiar…

Optics · Physics 2020-01-03 Shahram Moradi

This paper presents a nonperturbative treatment of strong-coupling induced effects in atom-field systems which cannot be seen in traditional perturbative treatments invoking compromising assumptions such as the Born-Markov, rotating wave or…

Quantum Physics · Physics 2020-02-25 Jen-Tsung Hsiang , Bei-Lok Hu

A method is presented in which the ground-state subspace is projected out of a Hamiltonian representation. As a result of this projection, an effective Hamiltonian is constructed where its ground-state coincides with an excited-state of the…

Quantum Physics · Physics 2023-08-14 P. Jouzdani , S. Bringuier , M. Kostuk
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