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Exciton-polaritons in semiconductors are quasi-particles which have recently shown the capability to undergo phase transition into a coherent hybrid state of light and matter. The observation of such quasi-particles in organic microcavities…

We present a microscopic semi-analytical theory for the description of organic molecules interacting strongly with a cavity mode. Exciton-vibration coupling within the molecule and exciton-cavity interaction are treated on an equal footing…

Mesoscale and Nanoscale Physics · Physics 2016-11-15 Ning Wu , Johannes Feist , Francisco J. Garcia-Vidal

Recent advancements on the fabrication of organic micro- and nanostructures have permitted the strong collective light-matter coupling regime to be reached with molecular materials. Pioneering works in this direction have shown the effects…

Strong light-matter coupling has shown great potential for modifying the electro-optical properties of semiconducting materials in recent years. In the strong coupling regime, excitons and cavity photons form new states named…

Applied Physics · Physics 2023-11-23 Yahui Tang , Alexandra Stuart , Timothy van der Laan , Girish Lakhwani

Polaritons - hybrid light-matter states formed from the strong coupling of a bright molecular transition with a confined photonic mode - may offer new opportunities for optical control of molecular behavior. Vibrational strong coupling…

Chemical Physics · Physics 2025-11-19 Liying Chen , Alexander M. McKillop , Ashley P. Fidler , Marissa L. Weichman

We present a detailed study of the electroluminescence of intersubband devices operating in the light-matter strong coupling regime. The devices have been characterized by performing angle resolved spectroscopy that shows two distinct light…

Mesoscale and Nanoscale Physics · Physics 2012-12-27 Pierre Jouy , Angela Vasanelli , Yanko Todorov , Luca Sapienza , Raffaele Colombelli , Ulf Gennser , Carlo Sirtori

Starting from a microscopic model, we investigate the optical spectra of molecules in strongly-coupled organic microcavities examining how they might self-consistently adapt their coupling to light. We consider both rotational and…

Mesoscale and Nanoscale Physics · Physics 2016-03-25 Justyna A. Cwik , Peter Kirton , Simone De Liberato , Jonathan Keeling

Strong light-matter coupling to form exciton- and vibropolaritons is increasingly touted as a powerful tool to alter the fundamental properties of organic materials. It is proposed that these states and their facile tunability can be used…

A theoretical variation between the two distinct light-matter coupling regimes, namely weak and strong coupling, becomes uniquely feasible in open optical Fabry-P\'erot microcavities with low mode volume, as discussed here. In combination…

Applied Physics · Physics 2019-12-02 Franziska Wall , Oliver Mey , Lorenz Maximilian Schneider , Arash Rahimi-Iman

Molecular polaritons arise when molecules interact so strongly with light that they become entangled with each other. This light-matter hybridization alters the chemical and physical properties of the molecular system and allows chemical…

Chemical Physics · Physics 2023-07-28 Tor S. Haugland , John P. Philbin , Tushar K. Ghosh , Ming Chen , Henrik Koch , Prineha Narang

Reversible exchange of photons between a material and an optical cavity can lead to the formation of hybrid light--matter states where material properties such as the work function\cite{Hutchison_AM2013a}, chemical…

Strong light-matter coupling is a quantum process in which light and matter are coupled together, generating hybridized states. This is similar to the notion of molecular hybridization, but one of the components is light. Here, we utilized…

Applied Physics · Physics 2024-02-20 Jhuma Dutta , Pooja Bhatt , Kuljeet Kaur , Daniel E. Gómez , Jino George

Recent experiments have demonstrated that molecular polaritons, hybrid states of light and matter formed by the strong coupling between molecular electronic or vibrational excitations and an optical cavity, can substantially modify the…

Chemical Physics · Physics 2021-07-08 Nguyen Thanh Phuc

The strong coupling between molecules and photonic modes in a Fabry-P\'{e}rot optical cavity, which forms hybrid light-matter states called polaritons, has been demonstrated as a promising route to control the rates of chemical reactions.…

Quantum Physics · Physics 2025-05-22 Kunyang Sun , Matthew Du , Joel Yuen-Zhou

Several years ago, it was shown that strong coupling between an electronic transition in organic molecules and a resonant photonic structure can modify the electronic landscape of the molecules and affect their chemical behavior. Since…

Recent experiments have shown contradictory effects of strong light-matter coupling on exciton-exciton annihilation (EEA) in organic molecular systems. In this work, we perform numerical simulations of polariton dynamics and reveal the role…

Chemical Physics · Physics 2026-05-20 I. Sokolovskii , B. S. Humphries , J. Blumberger , G. Groenhof

Engineering the properties of quantum materials via strong light-matter coupling is a compelling research direction with a multiplicity of modern applications. Those range from modifying charge transport in organic molecules, steering…

Exciton polaritons, arising from the interaction of electronic transitions with confined electromagnetic fields, have emerged as a powerful tool to manipulate the properties of organic materials. However, standard experimental and…

Cavity-mediated light-matter coupling can dramatically alter opto-electronic and physico-chemical properties of a molecule. Ab initio theoretical predictions of these systems need to combine non-perturbative, many-body electronic structure…

Quantum Physics · Physics 2024-06-19 Derek S. Wang , Tomáš Neuman , Johannes Flick , Prineha Narang

Strong light-matter interactions are gaining importance in controlling the photoswitching behavior of molecules exhibiting bistability. Here, we used the strategy of electronic strong coupling of both the E and Z-isomers of azopyrrole…