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Related papers: Reproducibility in $G_0W_0$ Calculations for Solid…

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We present a method to calculate the electronic charge density of periodic solids in the GW approximation, using the space-time method. We investigate for the examples of silicon and germanium to what extent the GW approximation is…

Condensed Matter · Physics 2009-10-31 Martin M. Rieger , R. W. Godby

We describe an implementation of Hedin's GW approximation for molecules and clusters, the complexity of which scales as O(N^3) with the number of atoms. Our method is guided by two strategies: i) to respect the locality of the underlying…

Other Condensed Matter · Physics 2015-05-27 Dietrich Foerster , Peter Koval , Daniel Sánchez-Portal

The fully self-consistent GW approximation is an established method for electronic structure calculations. Its most serious deficiency is known to be an incorrect prediction of the dielectric response. In this work we examine the GW…

Strongly Correlated Electrons · Physics 2017-05-24 Kris Van Houcke , Igor S. Tupitsyn , Andrey S. Mishchenko , Nikolay V. Prokof'ev

In the standard framework of self-consistent many-body perturbation theory, the skeleton series for the self-energy is truncated at a finite order $\mathcal{N}$ and plugged into the Dyson equation, which is then solved for the propagator…

Strongly Correlated Electrons · Physics 2024-05-28 K. Van Houcke , E. Kozik , R. Rossi , Y. Deng , F. Werner

We introduce a systematic hierarchy of one-body Green's function methods derived from the $GW$ approximation, constructed by progressively reducing the dynamical content of the self-energy. Starting from the fully dynamical Dyson…

Chemical Physics · Physics 2026-04-10 Pierre-François Loos , Johannes Tölle

We have recently implemented a new version of the quasiparticle self-consistent GW (QSGW) method in the ecalj package released at http://github.com/tkotani/ecalj. Since the new version of the ecalj is numerically stable and accurate…

Materials Science · Physics 2016-04-20 Daiki Deguchi , Kazunori Sato , Hiori Kino , Takao Kotani

The SternheimerGW software uses time-dependent density-functional perturbation theory to evaluate GW quasiparticle band structures and spectral functions for solids. Both the Green's function G and the screened Coulomb interaction W are…

Materials Science · Physics 2018-12-11 Martin Schlipf , Henry Lambert , Nourdine Zibouche , Feliciano Giustino

Calculating the quasiparticle (QP) band structure of two-dimensional (2D) materials within the GW self-energy approximation has proven to be a rather demanding computational task. The main reason is the strong $\mathbf{q}$-dependence of the…

Materials Science · Physics 2016-10-12 Filip A. Rasmussen , Per S. Schmidt , Kirsten T. Winther , Kristian S. Thygesen

On the basis of first-principles GW calculations, we study the quasiparticle properties of the guanine, adenine, cytosine, thymine, and uracil DNA and RNA nucleobases. Beyond standard G0W0 calculations, starting from Kohn-Sham eigenstates…

Chemical Physics · Physics 2015-05-27 Carina Faber , Claudio Attaccalite , Valerio Olevano , Erich Runge , Xavier Blase

We explore the combination of the extended dynamical mean field theory (EDMFT) with the GW approximation (GWA); the former sums the local contributions to the self-energies to infinite order in closed form and the latter handles the…

Strongly Correlated Electrons · Physics 2009-11-10 Ping Sun , Gabriel Kotliar

We report on the importance of GW self-energy corrections for the electronic structure of light actinides in the weak-to-intermediate coupling regime. Our study is based on calculations of the band structure and total density of states of…

Strongly Correlated Electrons · Physics 2014-05-15 Towfiq Ahmed , R. C. Albers , A. V. Balatsky , C. Friedrich , Jian-Xin Zhu

In transition metal doped ZnO, the energy position of dopant 3$d$ states relative to host conduction and valence bands is crucial in determining the possibilty of long range ferromagnetism. Density functional theory based estimates of the…

Materials Science · Physics 2013-07-12 I. Abdolhosseini Sarsari , C. D. Pemmaraju , H. Salamati , S. Sanvito

We have investigated the group 14 nitrides (M$_3$N$_4$) in the spinel phase ($\gamma$-M$_3$N$_4$ with M= C, Si, Ge and Sn) and $\beta$ phase ($\beta$-M$_3$N$_4$ with M= Si, Ge and Sn) using density functional theory with the local density…

Materials Science · Physics 2014-08-01 Iek-Heng Chu , Anton Kozhenikov , Thomas C. Schulthess , Hai-Ping Cheng

This paper describes an all-electron implementation of the self-consistent GW (sc-GW) approach -- i.e. based on the solution of the Dyson equation -- in an all-electron numeric atom-centered orbital (NAO) basis set. We cast Hedin's…

Materials Science · Physics 2013-08-12 Fabio Caruso , Patrick Rinke , Xinguo Ren , Angel Rubio , Matthias Scheffler

Ab initio GW calculations are a standard method for computing the spectroscopic properties of many materials. The most computationally expensive part in conventional implementations of the method is the generation and summation over the…

Materials Science · Physics 2015-06-11 Jack Deslippe , Georgy Samsonidze , Manish Jain , Marvin L. Cohen , Steven G. Louie

We report a successful combination of magnetic force linear response theory with quasiparticle self-consistent GW method. The self-consistently determined wavefunctions and eigenvalues can just be used for the conventional magnetic force…

Materials Science · Physics 2019-09-04 Hongkee Yoon , Seung Woo Jang , Jae-Hoon Sim , Takao Kotani , Myung Joon Han

We introduce a method that allows for the calculation of quasi-particle spectra in the GW approximation, yet avoiding any explicit reference to empty one-electron states. This is achieved by expressing the irreducible polarizability…

Materials Science · Physics 2015-05-14 P. Umari , G. Stenuit , S. Baroni

The many-body problem can in general not be solved exactly, and one of the most prominent approximations is to build perturbation expansions. A huge variety of expansions is possible, which differ by the quantity to be expanded, the…

Chemical Physics · Physics 2020-06-24 Ayoub Aouina , Matteo Gatti , Lucia Reining

The GW approach produces highly accurate quasiparticle energies, but its application to large systems is computationally challenging, which can be largely attributed to the difficulty in computing the inverse dielectric matrix. To address…

Materials Science · Physics 2023-07-26 Mario G. Zauchner , Andrew Horsfield , Johannes Lischner

Atomic hydrogen provides a unique test case for computational electronic structure methods, since its electronic excitation energies are known analytically. With only one electron, hydrogen contains no electronic correlation and is…

Materials Science · Physics 2007-05-23 W. Nelson , P. Bokes , Patrick Rinke , R. W. Godby