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Related papers: Reproducibility in $G_0W_0$ Calculations for Solid…

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The many-body $GW$ formalism, for the calculation of ionization potentials or electronic affinities, relies on the frequency-dependent dielectric function built from the electronic degrees of freedom. Considering the case of water as a…

Materials Science · Physics 2024-09-04 Ivan Duchemin , David Amblard , Xavier Blase

We present algorithmic and implementation details for the fully self-consistent finite-temperature $GW$ method in Gaussian Bloch orbitals for solids. Our implementation is based on the finite-temperature Green's function formalism in which…

Materials Science · Physics 2022-12-14 Chia-Nan Yeh , Sergei Iskakov , Dominika Zgid , Emanuel Gull

We solve the Dyson equation for atoms and diatomic molecules within the GW approximation, in order to elucidate the effects of self-consistency on the total energies and ionization potentials. We find GW to produce accurate energy…

Materials Science · Physics 2015-03-30 Adrian Stan , Nils Erik Dahlen , Robert van Leeuwen

We analyze a data set comprising 370 GW band structures composed of 61716 quasiparticle (QP) energies of two-dimensional (2D) materials spanning 14 crystal structures and 52 elements. The data results from PAW plane wave based one-shot…

Materials Science · Physics 2021-01-05 Asbjørn Rasmussen , Thorsten Deilmann , Kristian S. Thygesen

We present a diagrammatic approach to construct self-energy approximations within many-body perturbation theory with positive spectral properties. The method cures the problem of negative spectral functions which arises from a…

Other Condensed Matter · Physics 2015-06-22 G. Stefanucci , Y. Pavlyukh , A. -M. Uimonen , R. van Leeuwen

Common G$_0$W$_0$ implementations rely on numerical or analytical frequency integration to determine the G$_0$W$_0$ self-energy, which results in a variety of practical complications. Recently, we demonstrated an exact connection between…

Chemical Physics · Physics 2023-12-01 Johannes Tölle , Garnet Kin-Lic Chan

We combine the renormalized singles (RS) Green's function with the T-Matrix approximation for the single-particle Green's function to compute quasiparticle energies for valence and core states of molecular systems. The $G_{\text{RS}}T_0$…

Chemical Physics · Physics 2021-08-05 Jiachen Li , Zehua Chen , Weitao Yang

We present an {\it ab initio} many-body GW calculation of the self-energy, the quasiparticle band plot and the spectral functions in free-standing undoped graphene. With respect to other approaches, we numerically take into account the full…

Materials Science · Physics 2008-12-02 P. E. Trevisanutto , C. Giorgetti , L. Reining , M. Ladisa , V. Olevano

We apply a recently developed quasiparticle self-consistent $GW$ method (QSGW) to Gd, Er, EuN, GdN, ErAs, YbN and GdAs. We show that QSGW combines advantages separately found in conventional $GW$ and LDA+$U$ theory, in a simple and fully…

Materials Science · Physics 2007-11-10 Athanasios N. Chantis , Mark van Schilfgaarde , Takao Kotani

We present the formalism and implementation of quasi-particle self-consistent GW (qsGW) and eigenvalue only quasi-particle self-consistent GW (evGW) adapted to standard quantum chemistry packages. Our implementation is benchmarked against…

Chemical Physics · Physics 2024-04-10 F. Kaplan , M. E. Harding , C. Seiler , F. Weigend , F. Evers , M. J. van Setten

A GW approximation (GWA) method named U+GWA is proposed, where we can start GWA with more localized wave functions obtained by the local spin-density approximation (LSDA)+U method. Then GWA and U+GWA are applied to MnO, NiO, and V$_2$O$_3$…

Strongly Correlated Electrons · Physics 2008-10-18 S. Kobayashi , Y. Nohara , S. Yamamoto , T. Fujiwara

We consider a general class of approximations which guarantees the conservation of particle number in many-body perturbation theory. To do this we extend the concept of $\Phi$-derivability for the self-energy $\Sigma$ to a larger class of…

Strongly Correlated Electrons · Physics 2016-09-15 Daniel Karlsson , Robert van Leeuwen

In this chapter, we provide a review of ground-state Kohn-Sham density-functional theory of electronic systems and some of its extensions, we present exact expressions and constraints for the exchange and correlation density functionals,…

Chemical Physics · Physics 2022-09-12 Julien Toulouse

We present a comprehensive quantum many body theory for kq deformed particles, offering a novel framework that relates particle statistics directly to effective interaction strength. Deformed by the parameters k and q, these particles…

Statistical Mechanics · Physics 2024-12-10 Habib Esmaili , Hosein Mohammadzadeh , Mehdi Biderang , Morteza NattaghNajafi

Accurate and efficient predictions of the quasiparticle properties of complex materials remain a major challenge due to the convergence issue and the unfavorable scaling of the computational cost with respect to the system size.…

Materials Science · Physics 2020-07-14 Weiyi Xia , Weiwei Gao , Gabriel Lopez-Candales , Yabei Wu , Wei Ren , Wenqing Zhang , Peihong Zhang

The theory of Self-Consistent Green's Function (SCGF) is reformulated in an explicit Nambu-covariant fashion for applications to many-body systems at non-zero temperature in symmetry-broken phases. This is achieved by extending the…

Nuclear Theory · Physics 2025-07-09 M. Drissi , A. Rios , C. Barbieri

We present two new developments for computing excited state energies within the $GW$ approximation. First, calculations of the Green's function and the screened Coulomb interaction are decomposed into two parts: one is deterministic while…

Computational Physics · Physics 2020-10-28 Mariya Romanova , Vojtěch Vlček

The quantum dynamics of correlated fermionic or bosonic many-body systems following external excitation can be successfully studied using nonequilibrium Green functions (NEGF) or reduced density matrix methods. Approximations are introduced…

Strongly Correlated Electrons · Physics 2023-12-27 Erik Schroedter , Björn Jakob Wurst , Jan-Philip Joost , Michael Bonitz

We obtain the quasiparticle band structure of ABA and ABC-stacked graphene trilayers through ab initio density functional theory (DFT) and many-body quasiparticle calculations within the GW approximation. To interpret our results, we fit…

Mesoscale and Nanoscale Physics · Physics 2014-02-10 Marcos G. Menezes , Rodrigo B. Capaz , Steven G. Louie

We report quasiparticle-energy calculations of the electronic bandstructure as measured by valence-band photoemission for selected II-VI compounds and group-III-nitrides. By applying GW as perturbation to the ground state of the fictitious,…

Materials Science · Physics 2009-11-11 Patrick Rinke , Abdallah Qteish , Joerg Neugebauer , Christoph Freysoldt , Matthias Scheffler
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