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The surface-enhanced Raman scattering (SERS) signal from an AgFON plasmonic substrate, recoated with benzenethiol, was observed to increase by about 100% upon heating for 3.5 min at 100C and 1.5 min at 125C. The signal intensity was found…

Chemical Physics · Physics 2013-04-02 Roshan L. Aggarwal , Lewis W. Farrar , Semion K. Saikin

This study examines the Raman scattering and charge transfer properties of molecules adsorbed on the surface of a tetrahedral Au$_{120}$ nanoparticle based on the time-dependent density functional tight-binding (TD-DFTB) method. We study…

Chemical Physics · Physics 2024-09-18 Sajal Kumar Giri , George C. Schatz

We present SERS-active metal holographic metasurfaces fabricated from metal periodical nanograting deposited on a dielectric substrate. The metasurface consists of a modulated dielectric, which is covered by a thin silver layer. The…

Surface-enhanced Raman spectroscopy (SERS) is enabled by local surface plasmon resonances (LSPRs) in metallic nanogaps. When SERS is excited by direct illumination of the nanogap, the background heating of lattice and electrons can prevent…

Mesoscale and Nanoscale Physics · Physics 2023-08-23 Shusen Liao , Yunxuan Zhu , Qian Ye , Stephen Sanders , Jiawei Yang , Alessandro Alabastri , Douglas Natelson

In Impulsive Stimulated Raman Scattering vibrational oscillations, coherently stimulated by a femtosecond Raman pulse, are real time monitored and read out as intensity modulations in the transmission of a temporally delayed probe pulse.…

Chemical Physics · Physics 2019-11-28 Giovanni Batignani , Carino Ferrante , Giuseppe Fumero , Tullio Scopigno

Surface-enhanced Raman spectroscopy (SERS) sensing of DNA sequences by plasmonic nanopores could pave a way to new generation single-molecule sequencing platforms. The SERS discrimination of single DNA bases depends critically on the time…

This article reviews the new developments in Tip-enhanced Raman scattering (TERS). The fundamental mechanisms underlying the Raman enhancement are discussed, including the role of the plasmonic character of the metallic tips, the nature of…

Chemical Physics · Physics 2008-04-01 Catalin C. Neacsu , Samuel Berweger , Markus B. Raschke

We present a graphene/Cu nanoparticle hybrids (G/CuNPs) system as a surface-enhanced Raman scattering (SERS) substrate for adenosine detection. The Cu nanoparticles wrapped around a monolayer graphene shell were directly synthesized on flat…

Biological Physics · Physics 2015-03-03 Shicai Xu , Baoyuan Man , Shouzhen Jiang , Jihua Wang , Jie Wei , Shida Xu , Hanping Liu

The ability to perform sensitive, real-time, in situ, multiplex chemical analysis is indispensable for diverse applications such as human health monitoring, food safety testing, forensic analysis, environmental sensing, and homeland…

Plasmonic materials have got wide attention as a potential candidate for light driven catalysis of chemical conversions by harnessing solar energy to reduce the environmental issues generated by fossil fuels-based bulk chemical industries.…

Optics · Physics 2024-08-27 Mahadi Hasan , Mahamadu Tiah Mahama

Surface-enhanced Raman spectroscopy (SERS) is a sensitive vibrational spectroscopy technique that can enable fast and non-destructive detection of trace molecules. SERS substrates are critical for the advancement of the SERS application. By…

Materials Science · Physics 2020-11-30 Samir Kumar , Takao Fukuoka , Kyoko Namura , Motofumi Suzuki

Nanofibers functionalized by metal nanostructures and particles are exploited as effective flexible substrates for SERS analysis. Their complex three-dimensional structure may provide Raman signals enhanced by orders of magnitude compared…

Materials Science · Physics 2016-03-16 A. Camposeo , D. Spadaro , D. Magrì , M. Moffa , P. G. Gucciardi , L. Persano , O. M. Maragò , D. Pisignano

Characterizing a monolayer of biological molecules has been a major challenge. We demonstrate nanophotonic wave-guide enhanced Raman spectroscopy (NWERS) of monolayers in the near-infrared region, enabling real-time measurements of the…

Femtosecond, broadband stimulated Raman spectroscopy is a popular approach to measuring molecular dynamics with excellent signal-to-noise and spectral resolution. We present a new method for broadband stimulated Raman spectroscopy that…

Optics · Physics 2025-08-19 Nathan G. Drouillard , TJ Hammond

A typical surface-enhanced Raman scattering (SERS) system relies on deeply subwavelength field localization in nanoscale plasmonic cavities to enhance both the excitation and emission of Raman-active molecules. Here, we demonstrate that a…

Quantum Physics · Physics 2025-05-27 Mikolaj K. Schmidt , Alexander A. High , Michael J. Steel

In this study, we present a highly sensitive Surface Plasmon Resonance (SPR)-based biosensor integrated with a circular-lattice Photonic Crystal Fiber (PCF) for early-stage cancer detection. The proposed sensor leverages the synergy between…

Fluorescence imaging and spectroscopy remain the most powerful tools for visualization with chemical and immunological specificity of labeled biomolecules, viruses, cellular organelles, and living cells in complex biological backgrounds.…

Pseudo-heterodyne scattering-type scanning near-field optical microscopy (sSNOM) is applied in the mid-infrared region to detect the chemical composition of biomolecules on the nanoscale. However, the application of sSNOM in molecular…

Instrumentation and Detectors · Physics 2025-08-06 Yusuke Sakiyama , Emanuel Pfitzner , Santiago H. Andany , Georg E. Fantner , Joachim Heberle

Surface-enhanced Raman spectroscopy is a powerful and versatile sensing method with a detection limit down to the single molecule level. In this article, we demonstrate how topology optimization (TopOpt) can be used for designing surface…

Mesoscale and Nanoscale Physics · Physics 2021-08-25 Ying Pan , Rasmus E. Christiansen , Jerome Michon , Juejun Hu , Steven G. Johnson

More than twenty years ago, scientists succeeded in pushing the limits of optical detection to single molecules using fluorescence. This breakthrough has revolutionized biophysical measurements, but restrictions in photophysics and labeling…

Biological Physics · Physics 2015-06-17 Marek Piliarik , Vahid Sandoghdar