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Stimulated Raman Spectroscopy with Tunable Visible Broadband Probe Pulse Generated by Kerr-Instability Amplification

Optics 2025-08-19 v5 Applied Physics Chemical Physics

Abstract

Femtosecond, broadband stimulated Raman spectroscopy is a popular approach to measuring molecular dynamics with excellent signal-to-noise and spectral resolution. We present a new method for broadband stimulated Raman spectroscopy that employs Kerr-instability amplification to amplify the supercontinuum spectrum from sapphire and create a highly tunable Raman probe spectrum spanning from 530 to 1000 nm (-6000 to 2800 cm^(-1)). Our method, called Kerr-instability amplification for broadband stimulated Raman spectroscopy (KAB-SRS) provides an alternative to optical parametric amplifiers by producing a broader and more tunable spectrum at a significantly reduced cost to OPA implementations. We demonstrate the effectiveness of KAB-SRS by measuring the stimulated Raman loss spectrum of 1-decanol.

Keywords

Cite

@article{arxiv.2409.19080,
  title  = {Stimulated Raman Spectroscopy with Tunable Visible Broadband Probe Pulse Generated by Kerr-Instability Amplification},
  author = {Nathan G. Drouillard and TJ Hammond},
  journal= {arXiv preprint arXiv:2409.19080},
  year   = {2025}
}