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Geometric integrators of the Schr\"{o}dinger equation conserve exactly many invariants of the exact solution. Among these integrators, the split-operator algorithm is explicit and easy to implement, but, unfortunately, is restricted to…

Chemical Physics · Physics 2024-09-26 Seonghoon Choi , Jiří Vaníček

Ehrenfest dynamics is a useful approximation for ab initio mixed quantum-classical molecular dynamics that can treat electronically nonadiabatic effects. Although a severe approximation to the exact solution of the molecular time-dependent…

Chemical Physics · Physics 2021-09-24 Seonghoon Choi , Jiří Vaníček

Quantum computation is an attractive front for many problems that are intractable for computers today. One such problem is nonadiabatic quantum molecular dynamics, where quantized internal states coupling to parameterized modes result in a…

Quantum Physics · Physics 2026-04-22 Joshua Courtney

The explicit split-operator algorithm is often used for solving the linear and nonlinear time-dependent Schr\"{o}dinger equations. However, when applied to certain nonlinear time-dependent Schr\"{o}dinger equations, this algorithm loses…

Chemical Physics · Physics 2024-09-26 Julien Roulet , Jiří Vaníček

Diabatization of the molecular Hamiltonian is a standard approach to removing the singularities of nonadiabatic couplings at conical intersections of adiabatic potential energy surfaces. In general, it is impossible to eliminate the…

Chemical Physics · Physics 2021-03-26 Seonghoon Choi , Jiří Vaníček

Choosing an appropriate representation of the molecular Hamiltonian is one of the challenges faced by simulations of the nonadiabatic quantum dynamics around a conical intersection. The adiabatic, exact quasidiabatic, and strictly diabatic…

Chemical Physics · Physics 2024-09-26 Seonghoon Choi , Jiří Vaníček

The explicit split-operator algorithm has been extensively used for solving not only linear but also nonlinear time-dependent Schr\"{o}dinger equations. When applied to the nonlinear Gross-Pitaevskii equation, the method remains…

Chemical Physics · Physics 2024-09-26 Julien Roulet , Jiří Vaníček

Adiabatic limit is the presumption of the adiabatic geometric quantum computation and of the adiabatic quantum algorithm. But in reality, the variation speed of the Hamiltonian is finite. Here we develop a general formulation of adiabatic…

Quantum Physics · Physics 2009-11-10 Yu Shi , Yong-Shi Wu

In the circuit model of quantum computing, amplitude amplification techniques can be used to find solutions to NP-hard problems defined on $n$-bits in time $\text{poly}(n) 2^{n/2}$. In this work, we investigate whether such general…

We apply a flexible numerical integrator to the simulation of adiabatic quantum computation with nonlinear paths. We find that a nonlinear path may significantly improve the performance of adiabatic algorithms versus the conventional…

Quantum Physics · Physics 2014-03-20 Michael Hofmann , Gernot Schaller

Among variational quantum algorithms designed for NISQ devices, ADAPT-VQE stands out for its robustness against barren plateaus, particularly in estimating molecular ground states. On the other hand, counterdiabatic algorithms have shown…

Quantum Physics · Physics 2026-01-12 Diego Tancara , Herbert Díaz-Moraga , Dardo Goyeneche

Exploiting the similarity between adiabatic quantum algorithms and quantum phase transitions, we argue that second-order transitions -- typically associated with broken or restored symmetries -- should be advantageous in comparison to…

Quantum Physics · Physics 2010-01-07 Gernot Schaller , Ralf Schützhold

The adiabatic quantum algorithm has drawn intense interest as a potential approach to accelerating optimization tasks using quantum computation. The algorithm is most naturally realised in systems which support Hamiltonian evolution, rather…

Quantum Physics · Physics 2019-10-02 Liming Zhao , Carlos A. Perez-Delgado , Simon C. Benjamin , Joseph F. Fitzsimons

Hamiltonian systems of ordinary and partial differential equations are fundamental mathematical models spanning virtually all physical scales. A critical property for the robustness and stability of computational methods in such systems is…

Quantum Physics · Physics 2025-02-25 Hsuan-Cheng Wu , Xiantao Li

We develop and implement an exact conical intersection nonadiabatic wave packet dynamics method that combines the local diabatic representation, Strang splitting for the total molecular propagator, and discrete variable representation with…

Chemical Physics · Physics 2024-04-23 Bing Gu

Adiabatic quantum optimization is a procedure to solve a vast class of optimization problems by slowly changing the Hamiltonian of a quantum system. The evolution time necessary for the algorithm to be successful scales inversely with the…

Quantum Physics · Physics 2015-12-16 Salvatore Mandrà , Gian Giacomo Guerreschi , Alán Aspuru-Guzik

We propose a hybrid quantum-classical approximate optimization algorithm for photonic quantum computing, specifically tailored for addressing continuous-variable optimization problems. Inspired by counterdiabatic protocols, our algorithm…

Quantum Physics · Physics 2024-10-03 Pranav Chandarana , Koushik Paul , Mikel Garcia-de-Andoin , Yue Ban , Mikel Sanz , Xi Chen

Because of using geometric phases, nonadiabatic geometric gates have the robustness against control errors. On the other hand, decoherence still affects nonadiabatic geometric gates, which is a key factor in reducing their fidelities. In…

Quantum Physics · Physics 2022-05-06 Kangze Li , Guofu Xu , Dianmin Tong

We propose a non-adiabatic scheme for geometric quantum computation with trapped ions. By making use of the Aharonov-Anandan phase, the proposed scheme not only preserves the globally geometric nature in quantum computation, but also…

Quantum Physics · Physics 2009-11-07 Xin-Qi Li , Li-Xiang Cen , Guo-Xiang Huang , Lei Ma , YiJing Yan

Nonadiabatic geometric quantum computation in decoherence-free subspaces has received increasing attention due to the merits of its high-speed implementation and robustness against both control errors and decoherence. However, all the…

Quantum Physics · Physics 2017-01-04 P. Z. Zhao , G. F. Xu , D. M. Tong
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