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An implicit split-operator algorithm for the nonlinear time-dependent Schr\"{o}dinger equation

Chemical Physics 2024-09-26 v2 Computational Physics Quantum Physics

Abstract

The explicit split-operator algorithm is often used for solving the linear and nonlinear time-dependent Schr\"{o}dinger equations. However, when applied to certain nonlinear time-dependent Schr\"{o}dinger equations, this algorithm loses time reversibility and second-order accuracy, which makes it very inefficient. Here, we propose to overcome the limitations of the explicit split-operator algorithm by abandoning its explicit nature. We describe a family of high-order implicit split-operator algorithms that are norm-conserving, time-reversible, and very efficient. The geometric properties of the integrators are proven analytically and demonstrated numerically on the local control of a two-dimensional model of retinal. Although they are only applicable to separable Hamiltonians, the implicit split-operator algorithms are, in this setting, more efficient than the recently proposed integrators based on the implicit midpoint method.

Keywords

Cite

@article{arxiv.2109.10630,
  title  = {An implicit split-operator algorithm for the nonlinear time-dependent Schr\"{o}dinger equation},
  author = {Julien Roulet and Jiří Vaníček},
  journal= {arXiv preprint arXiv:2109.10630},
  year   = {2024}
}
R2 v1 2026-06-24T06:12:43.052Z