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Metal oxide thin-film transistors are fast becoming a ubiquitous technology for application in driving backplanes of organic light-emitting diode displays. Currently all commercial products rely on metal oxides processed via physical vapor…

We present a monolayer black phosphorus (BP)-based metamaterial structure for tunable anisotropic absorption in the mid-infrared. Based on the critical coupling mechanism of guided resonance, the structure realizes the high absorption…

Black phosphorous (BP), a two-dimensional (2D) material, has a direct bandgap, which fills up the bandgap lacuna left by graphene topological insulators and transition-metal dichalcogenides because of its dependence on the layers and…

Materials Science · Physics 2015-05-25 Rui Zhang , Yuxia Zhang , Haohai Yu , Huaijin Zhang , Ruinong Yang , Bingchao Yang , Zhongyuan Liu , Jiyang Wang

Phosphorene and its components are highly reactive to oxygen when exposed to ambient conditions due to the presence of lone pairs of electrons on phosphorus atoms. Functionalization serves as a solution to prevent the chemical degradation…

Low-dimensional materials, due to their versatile properties are very interesting for numerous electronics and optoelectronics applications. Recently rediscovered black phosphorus, with a graphite-like structure can be exfoliated up to the…

The first non-covalent functionalization of black phosphorus (BP) is presented. The treatment of BP with electron- withdrawing 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) leads to electron transfer from BP to the organic dopant. On the other…

There have been continuous efforts to seek for novel functional two-dimensional semiconductors with high performance for future applications in nanoelectronics and optoelectronics. In this work, we introduce a successful experimental…

Electric and thermoelectric properties of strictly monolayer MoS$_2$ films, which are grown using a novel micro-cavity based CVD growth technique, have been studied under diverse environmental and annealing conditions. Resistance of a…

Mesoscale and Nanoscale Physics · Physics 2020-09-16 Swarup Deb , Pritam Bhattacharyya , Poulab Chakrabarti , Himadri Chakraborti , Kantimay Das Gupta , Alok Shukla , Subhabrata Dhar

The interest in obtaining high-quality monolayer transition metal dichalcogenides (TMDs) for optoelectronic device applications has been growing dramatically. However, the prevalence of defects and unwanted doping in these materials remains…

Chemical Physics · Physics 2023-01-18 Zhaojun Li , Hope Bretscher , Akshay Rao

Atomic structure of single-crystalline black phosphorus was studied by high resolution synchrotron-based photoelectron diffraction (XPD). The results show that the topmost phosphorene layer in the black phosphorus is slightly displaced…

Materials Science · Physics 2016-02-03 Luis Henrique de Lima , Lucas Barreto , Richard Landers , Abner de Siervo

Wave polarization contains valuable information for electromagnetic signal processing and the ability to manipulate it can be extremely useful in photonic devices. In this work, we propose designs comprised of one of the emerging and…

The electronic structure of few-layer(FL) black phosphorus(BP) sensitively depends on the sample thickness, strain and doping. In this paper, we show that it is also vulnerable to air-exposure. The oxidation of BP caused by air-exposure…

Mesoscale and Nanoscale Physics · Physics 2019-03-27 Fanjie Wang , Guowei Zhang , Shenyang Huang , Chaoyu Song , Chong Wang , Qiaoxia Xing , Yuchen Lei , Hugen Yan

Black phosphorus is a monoatomic semiconducting layered material that degrades exothermically in the presence of light and ambient contaminants. Its degradation dynamics remain largely unknown. Even before degradation, local-probe studies…

We study the response of GaAs photonic crystal membrane resonators to thin film deposition. Slow spectral shifts of the cavity mode of several nanometers are observed at low temperatures, caused by cryo-gettering of background molecules.…

Black phosphorus thin films might offer attractive alternatives to narrow gap compound semiconductors for optoelectronics across mid- to near-infrared frequencies. In this work, we calculate the optical conductivity tensor of multilayer…

Materials Science · Physics 2014-09-18 Tony Low , A. S. Rodin , A. Carvalho , Yongjin Jiang , Han Wang , Fengnian Xia , A. H. Castro Neto

Black phosphorus (BP) is an emerging two-dimensional semiconducting material with great potential for nanoelectronic and nanophotonic applications, especially owing to its unique anisotropic electrical and optical properties. Many…

Controlling the bandgap through local-strain engineering is an exciting avenue for tailoring optoelectronic materials. Two-dimensional crystals are particularly suited for this purpose because they can withstand unprecedented…

We calculate an electron-phonon scattering and intrinsic transport properties of black phosphorus monolayer using tight-binding and Boltzmann treatments as a function of temperature, carrier density, and electric field. The low-field…

Mesoscale and Nanoscale Physics · Physics 2017-04-12 Yuri Trushkov , Vasili Perebeinos

Energy bandgap largely determines the optical and electronic properties of a semiconductor. Variable bandgap therefore makes versatile functionality possible in a single material. In layered material black phosphorus, the bandgap can be…

In this work we report results of step-by-step modeling of the oxidation of free-standing boron monolayers of different types. Results of the calculations demonstrate that the process of the oxidation is always exothermic and lead toward…

Materials Science · Physics 2020-04-22 Xue Lei , Anatoly F. Zatsepin , Danil W. Boukhvalov
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