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Noncovalent Functionalization of Black Phosphorus

Chemical Physics 2018-05-24 v1 Materials Science
Authors: Gonzalo Abellán , Vicent Lloret , Udo Mundloch , Mario Marcia , Christian Neiss , Andreas Görling , Maria Varela , Frank Hauke , Andreas Hirsch
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Abstract

The first non-covalent functionalization of black phosphorus (BP) is presented. The treatment of BP with electron- withdrawing 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) leads to electron transfer from BP to the organic dopant. On the other hand, the non-covalent interaction of BP with perylene diimide is mainly due to van-der-Waals interactions but also leads to a considerable stabilization of the BP flakes against oxygen degradation.

Cite

@article{arxiv.1805.09130,
  title  = {Noncovalent Functionalization of Black Phosphorus},
  author = {Gonzalo Abellán and Vicent Lloret and Udo Mundloch and Mario Marcia and Christian Neiss and Andreas Görling and Maria Varela and Frank Hauke and Andreas Hirsch},
  journal= {arXiv preprint arXiv:1805.09130},
  year   = {2018}
}

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