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A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal…

Chemical Physics · Physics 2017-05-04 Andrey Yachmenev , Sergei N. Yurchenko

We study the ellipticity of high-order harmonics emitted from CO$_2$ molecule driven by linearly polarized laser fields using numerical simulations within the time-dependent density functional theory. We find that the overall ellipticity of…

Atomic and Molecular Clusters · Physics 2024-09-17 Andres Mora , Lauren Bauerle , Yuqing Xia , Agnieszka Jaron

High-order harmonic generation from atomic systems is considered in the crossed fields of a relativistically strong infrared laser and a weak attosecond-pulse train of soft x-rays. Due to one-photon ionization by the x-ray pulse, the…

Atomic Physics · Physics 2009-11-13 Michael Klaiber , Karen Z. Hatsagortsyan , Carsten Müller , Christoph H. Keitel

We show that a linear molecule subjected to a short specific elliptically polarized laser field yields postpulse revivals exhibiting alignment alternatively located along the orthogonal axis and the major axis of the ellipse. The effect is…

Quantum Physics · Physics 2007-05-23 D. Daems , S. Guérin , E. Hertz , H. R. Jauslin , B. Lavorel , O. Faucher

We propose schemes to produce highly nuclear-spin polarized small molecules in an intense and cold molecular beam via microwave or infrared rotational excitation, followed by hyperfine-induced quantum beats. Repumping schemes can be used to…

Chemical Physics · Physics 2026-03-20 C. S. Kannis , T. P. Rakitzis

At levels of laser intensity below threshold for multiphoton ionization, the parametric generation of optical harmonics in gases and other isotropic media is subject to selection rules with origins in angular momentum conservation. The…

Optics · Physics 2019-06-13 David L. Andrews , Henryk Haniewicz , Enrique J. Galvez

The interaction of intense mid-infrared laser fields with atoms and molecules leads to a range of new opportunities, from the production of bright, coherent radiation in the soft x-ray range to imaging molecular structures and dynamics with…

Isotropic gases irradiated by long pulses of intense IR light can generate very high harmonics of the incident field. It is generally accepted that, due to the symmetry of the generating medium, be it an atomic or an isotropic molecular…

Atomic Physics · Physics 2016-09-28 R. E. F. Silva , P. Rivière , F. Morales , O. Smirnova , M. Ivanov , F. Martín

We report the observation of macroscopic field-free orientation, i.e. more than 73 % of CO molecules pointing in the same direction. This is achieved through an all-optical scheme operating at high particle densities ($>10^{17}$cm$^{-3}$)…

Chemical Physics · Physics 2014-07-09 P. M. Kraus , D. Baykusheva , H. J. Wörner

We investigate high-order harmonic spectra from aligned diatomic molecules in intense driving fields whose components have orthogonal polarizations. We focus on how the driving-field ellipticity influences structural interference patterns…

We present a metamaterial-based random polarization control plate to produce incoherent laser irradiation by exploiting the ability of metamaterial in local polarization manipulation of beam upon transmission via tuning its local geometry.…

Optics · Physics 2013-12-24 Xiaohui Ling , Hailu Luo , Chujun Zhao , Shuangchun Wen , Dianyuan Fan

We consider deflection of polarizable molecules by inhomogeneous optical fields, and analyze the role of molecular orientation and rotation in the scattering process. It is shown that molecular rotation induces spectacular rainbow-like…

Quantum Physics · Physics 2015-05-19 E. Gershnabel , I. Sh. Averbukh

Relativistic spin-polarized electron beams are important for fundamental research and the industry, but their generation currently requires conventional accelerators or ultrastrong laser facilities, limiting their accessibility and broad…

We explore the role of laser induced anti-alignment in enhancing molecular orientation. A field-free enhanced orientation via anti-alignment scheme is presented, which combines a linearly polarized femtosecond laser pulse with a half-cycle…

Optics · Physics 2009-11-11 E. Gershnabel , I. Sh. Averbukh , Robert J. Gordon

The strong ellipticity dependence of high-harmonic generation in gases enables numerous experimental techniques that are nowadays routinely used, for instance, to create isolated attosecond pulses. Extending such techniques to high-harmonic…

The single ionization of noble gas atoms by the combined action of XUV attopulses and an infrared laser field is theoretically investigated by means of a non-perturbative model that under certain approximations gives closed-form expressions…

Atomic Physics · Physics 2015-12-21 D. I. R. Boll , O. A. Fojón

When a laser pulse impinges on a molecule which is invariant under certain symmetry operations selection rules for harmonic generation (HG) arise. In other words: symmetry controls which channels are open for the deposition and emission of…

Atomic Physics · Physics 2009-11-07 D. Bauer , F. Ceccherini

Following excitation by a strong ultra-short laser pulse, molecules develop coordinated rotational motion, exhibiting transient alignment along the direction of the laser electric field, followed by periodic full and fractional revivals…

Quantum Physics · Physics 2007-05-23 Sharly Fleischer , Ilya. Sh. Averbukh , Yehiam Prior

We use extreme-ultraviolet interferometry to measure the phase of high-order harmonic generation from transiently aligned CO2 molecules. We unambiguously observe a reversal in phase of the high order harmonic emission for higher harmonic…

Atomic Physics · Physics 2009-11-13 Xibin Zhou , Robynne Lock , Wen Li , Nick Wagner , Margaret. M. Murnane , Henry C. Kapteyn

We propose and computationally study a method for simultaneously orienting the angular momentum of asymmetric top molecules along: 1) a laboratory-fixed direction; 2) the molecular intermediate moment of inertia axis; 3) the laser field…

Quantum Physics · Physics 2022-11-21 Emil J. Zak