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Chemical reaction rates must increasingly be determined in systems that evolve under the control of external stimuli. In these systems, when a reactant population is induced to cross an energy barrier through forcing from a temporally…

Chemical Physics · Physics 2015-05-01 Galen T. Craven , Thomas Bartsch , Rigoberto Hernandez

We consider a lattice model in which a tracer particle moves in the presence of randomly distributed immobile obstacles. The crowding effect due to the obstacles interplays with the quasi-confinement imposed by wrapping the lattice onto a…

Statistical Mechanics · Physics 2026-03-05 A. Squarcini , A. Tinti , P. Illien , O. Bénichou , T. Franosch

We compare the fluctuation relations for work and entropy in underdamped and overdamped systems, when the friction coefficient of the medium is space-dependent. We find that these relations remain unaffected in both cases. However, for the…

Statistical Mechanics · Physics 2015-06-15 Sourabh Lahiri , Shubhashis Rana , A. M. Jayannavar

We theoretically consider specific adhesion of a fluctuating membrane to a hard substrate via the formation of bonds between receptors attached to the substrate and ligands in the membrane. By integrating out the degrees of freedom of the…

Soft Condensed Matter · Physics 2010-10-13 Thomas Speck , Ellen Reister , Udo Seifert

We investigate single-particle diffusion in a two-state Langevin model where the friction coefficient randomly switches between low-friction (liquid-like) and high-friction (glassy-like) states. The dynamics are governed by the ratio…

Chemical Physics · Physics 2025-12-03 Fivos Perakis , Takeshi Kawasaki , Shinji Saito

The authors in a previous paper proved the hydrodynamic incompressible limit in $d\ge 3$ for a thermal lattice gas, namely a law of large numbers for the density, velocity field and energy. In this paper the equilibrium fluctuations for…

Mathematical Physics · Physics 2007-05-23 O. Benois , R. Esposito , R. Marra

We propose that the super-Arrhenius relaxation rates observed in glassy materials are determined by thermally nucleated rearrangements of increasing numbers of molecules at decreasing temperatures. In our model of this mechanism,…

Materials Science · Physics 2016-08-16 J. S. Langer , Anaël Lemaître

We identify a new scenario for dynamical phase transitions associated with time-integrated observables occurring in diffusive systems described by the macroscopic fluctuation theory. It is characterized by the pairwise meeting of first- and…

Statistical Mechanics · Physics 2023-07-19 Tal Agranov , Michael E. Cates , Robert L. Jack

We study the nature of the glass transition by cooling model atomistic glass formers at constant rate from a temperature above the onset of glassy dynamics to $T=0$. Motivated by the East model, a kinetically constrained lattice model with…

Statistical Mechanics · Physics 2018-04-16 Alexander Hudson , Kranthi K. Mandadapu

In mechanical systems it is of interest to know the onset of fracture in dependence of the boundary conditions. Here we study a one-dimensional model which allows for an underlying heterogeneous structure in the discrete setting. Such…

Analysis of PDEs · Mathematics 2021-11-03 Laura Lauerbach , Stefan Neukamm , Mathias Schäffner , Anja Schlömerkemper

Conformational fluctuations are believed to play an important role in the process by which transcription factor proteins locate and bind their target site on the genome of a bacterium. Using a simple model, we show that the binding time can…

Soft Condensed Matter · Physics 2008-07-22 Longhua Hu , Alexander Y. Grosberg , Robijn Bruinsma

This paper is concerned with transition paths within the framework of the overdamped Langevin dynamics model of chemical reactions. We aim to give an efficient description of typical transition paths in the small temperature regime. We…

Probability · Mathematics 2017-06-27 Yulong Lu , Andrew M. Stuart , Hendrik Weber

We study theoretically the dimensional crossover from a three-dimensional elongated condensate to a one-dimensional condensate as the transverse degrees of freedom get frozen by tight confinement, in the limit of small density fluctuations,…

Other Condensed Matter · Physics 2007-05-23 Fabrice Gerbier

A pair of random walkers, the motion of each of which in two dimensions is confined spatially by the action of a quadratic potential centered at different locations for the two walks, are analyzed in the context of reaction-diffusion. The…

Biological Physics · Physics 2016-10-20 S. Sugaya , V. M. Kenkre

Folding kinetics of a lattice model of protein is studied. It uses the Random Energy Model for the intrachain couplings and a temperature dependent free energy of solvation derived from a realistic hydration model of apolar solutes. The…

Statistical Mechanics · Physics 2008-11-06 Olivier Collet

We study diffusion-reaction processes on periodic square planar lattices and simple cubic (sc) lattices. Considered first is a single diffusing reactant undergoing an irreversible reaction upon first encounter with a stationary co-reactant…

Statistical Mechanics · Physics 2018-08-22 E. Abad , T. Abil , A. Santos , J. J. Kozak

In this paper the Turing pattern formation mechanism of a two component reaction-diffusion system modeling the Schnakenberg chemical reaction coupled to linear cross-diffusion terms is studied. The linear cross-diffusion terms favors the…

Pattern Formation and Solitons · Physics 2017-05-08 G. Gambino , S. Lupo , M. Sammartino

A fractional reaction-diffusion equation is derived from a continuous time random walk model when the transport is dispersive. The exit from the encounter distance, which is described by the algebraic waiting time distribution of jump…

Statistical Mechanics · Physics 2009-11-10 Kazuhiko Seki , Mariusz Wojcik , M. Tachiya

We consider a single-species diffusion-limited annihilation reaction with reactants confined to a two-dimensional surface with one arbitrarily large dimension and the other comparable in size to interparticle distances. This situation could…

Biomolecules · Quantitative Biology 2015-03-20 Aleksandr Kivenson , Michael F. Hagan

A study of a reacting boundary layer flow with heat transfer at conditions typical for configurations at elevated pressures has been performed using a set of direct numerical simulations. Effects of wall temperatures are investigated,…

Fluid Dynamics · Physics 2021-02-16 Nikolaos Perakis , Oskar Haidn , Matthias Ihme
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