Related papers: Differentiability of the van der Waals interaction…
Violation of the action-reaction principle is shown to occur in the van der Waals interaction between two atoms, one of which is excited. It is accompanied by the transfer of linear momentum to the electromagnetic vacuum. The vacuum…
In this Chapter we reexamine the concept of $\textit{covalency}$ and $\textit{ionicity}$ on example of the simplest molecules. First, starting from the exact expression for the two-particle wave function in the case of $H_2$ molecule within…
We consider the van der Waals interaction of an excited atom and a ground state atom across a vacuum-medium interface under the circumstances of the resonant coupling of the excited atom to a surface polariton mode of the system. We…
We analyze van der Waals interactions between two rigid polymers with sequence-specific, anisotropic polarizabilities along the polymer backbones, so that the dipole moments fluctuate parallel to the polymer backbones. Assuming that each…
Interactions are explored through the observation of the dynamics of particles. On the classical level the basic underlying assumption in that scheme is that Newton's second law holds. Relaxing the validity of this axiom by, e.g., allowing…
Using the general expressions for level shifts obtained from the master equation for a small system interacting with a large one considered as a reservoir, we calculate the dispersive potentials between an atom and a wall in the dipole…
In some respects, a cluster consisting of many atoms may be regarded as a single large atom. Knowing the dielectric properties of such a cluster permits one to evaluate the form of the van der Waals (dispersion) interactions between two…
The origin of a chemical reaction between two reactant atoms is associated to the activation energy, with the assumption that, high-energy collisions between these atoms, are the ones that overcome the activation energy. Here, we (i) show…
Van der Waals torque determines the relative rotational motion between anisotropic objects, being of relevance to low-dimensional systems. Here we demonstrate a substantial torque between anisotropic two-dimensional materials that arises…
The unitary transformation that leads from the minimal-coupling description to the electric-dipole one is analysed in detail. The momentum cut-off function f(k), which is understood in the definition of such a transformation, is obtained…
We propose a new approach to calculate van der Waals forces between nanoparticles where the van der Waals energy can be reduced to the energy of elementary surface plasmon oscillations in nanoparticles. The general theory is applied to…
In inhomogeneous dielectric media the divergence of the electromagnetic stress is related to the gradients of \varepsilon and \mu, which is a consequence of Maxwell's equations. Investigating spherically symmetric media we show that this…
Relativistic systems of particles interacting pairwise at a distance (interactions not mediated by fields) in flat spacetime are studied. It is assumed that the interactions propagate at the speed of light in vacuum and that all masses are…
We investigate the influence of the appearance of excitonic states on van der Waals interactions among two Rydberg atoms. The atoms are assumed to be in different Rydberg states, e.g., in the $|ns\rangle$ and $|np\rangle$ states. The…
At long distances interactions between neutral ground state atoms can be described by the Van der Waals potential V(r) =-C6/r^6-C8/r^8 - ... . In the ultra-cold regime atom-atom scattering is dominated by s-waves phase shifts given by an…
We verify that the van der Waals interaction and hence all dispersion interactions for the hydrogen molecule given by: W"= -{A/R^6}-{B/R^8}-{C/R^10}- ..., in which R is the internuclear separation, are exactly soluble. The constants…
Using the multipolar expansion of electrostatic and magnetostatic potential energies, we characterize the long-range interactions between two weakly-bound diatomic molecules, taking as an example the paramagnetic Er$_2$ Feshbach molecules…
We consider the scattering of two color dipoles (e.g., heavy quarkonium states) at low energy - a QCD analog of Van der Waals interaction. Even though the couplings of the dipoles to the gluon field can be described in perturbation theory,…
This article focuses on isomerizations of molecules, i.e. chemical reactions during which a molecule is transformed into another one with the same atoms in a different spatial configuration. We consider the special case in which the system…
The term "long-range interactions" refers to electrostatic and magnetostatic potential energies between atoms and molecules with mutual distances ranging from a few tens to a few hundreds Bohr radii. The involved energies are much smaller…