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We observe anharmonic decay of the photoexcited coherent A1g phonon in bismuth to points in the Brillouin zone where conservation of momentum and energy are satisfied for three-phonon scattering. The decay of a coherent phonon can be…

The thermal properties of silver are calculated within the quasi-harmonic approximation, by using phonon dispersions from density-functional perturbation theory, and the pseudopotential plane-wave method. The resulting free energy provides…

Materials Science · Physics 2009-10-31 Jianjun Xie , Stefano de Gironcoli , Stefano Baroni , Matthias Scheffler

Within unitary transformed Hamiltonian of Fr\"ohlich type, using the Green's functions method, exact renormalized energy spectrum of quasiparticle strongly interacting with two-mode polarization phonons is obtained at $T=0$ K in a model of…

Soft Condensed Matter · Physics 2023-03-09 M. V. Tkach , Ju. O. Seti , O. M. Voitsekhivska , V. V. Hutiv

We present a general harmonic theory for the temperature dependence of phonon-renormalized properties of solids. Firstly, we formulate a perturbation theory in phonon-phonon interactions to calculate the phonon renormalization of physical…

Materials Science · Physics 2015-10-28 Bartomeu Monserrat , G. J. Conduit , R. J. Needs

Photoemission and phonon spectroscopies have yielded widely varying estimates of the electron-phonon coupling constant \lambda\ on the surfaces of topological insulators, even for a particular material and technique. We connect the results…

Mesoscale and Nanoscale Physics · Physics 2014-02-27 Colin Howard , M. El-Batanouny

Taking into account the constraints imposed by the lattice symmetry, the phonon dispersion is calculated for graphene with interactions between the first and second nearest neighbors in the framework of the Born-von Karman model. Analytical…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 L. A. Falkovsky

We study the thermal conductivity of amorphous solids by constructing a continuum model whose degrees of freedom are propagating vibrational modes (phonons) and extended Volterra dislocation line defects with their own vibrational degrees…

Materials Science · Physics 2026-01-21 Fernando Lund , Bruno Scheihing-Hitschfeld

The renormalization of electronic eigenenergies due to electron-phonon coupling is sizable in many materials with light atoms. This effect, often neglected in ab-initio calculations, can be computed using the perturbation-based…

The existing techniques of account for the phonon dispersion are computationally costly, while its impact on a variety of thermodynamic properties appears negligible. We develop a mathematical formalism, which allows for clear understanding…

Statistical Mechanics · Physics 2014-05-01 Roman Belousov , Mauro Prencipe

The dynamics of quasicrystals is characterized by the existence of phason excitations in addition to the usual phonon modes. In order to investigate their interplay on an elementary level we resort to various one-dimensional model systems.…

Other Condensed Matter · Physics 2007-05-23 Michael Engel , Steffen Sonntag , Hansjörg Lipp , Hans-Rainer Trebin

We propose a method to evaluate the Gibbs free energy from constant-volume first-principles phonon calculations. The volume integral of the pressure is performed by determining the volume and the bulk modulus in equilibrium at finite…

Materials Science · Physics 2025-07-02 Kota Hashimoto , Tomonori Tanaka , Yoshihiro Gohda

The electron and phonon temperature distribution function are calculated in semiconductors. We solved the coupled one-dimensional heat-diffussion equations in the linear approximation in which the physical parameters on the sample are…

Condensed Matter · Physics 2009-10-28 G. Gonzalez de la Cruz , Yu. G. Gurevich

We develop a theoretical and computational framework to study polarons in semiconductors and insulators from first principles. Our approach provides the formation energy, excitation energy, and wavefunction of both electron and hole…

Materials Science · Physics 2019-06-21 Weng Hong Sio , Carla Verdi , Samuel Ponce , Feliciano Giustino

In this Tutorial, we describe the use of the quasiharmonic approximation and first-principles density functional theory (DFT) to calculate and analyze the thermal expansion of insulating solids. We discuss the theory underlying the…

Materials Science · Physics 2019-11-15 Ethan T. Ritz , Sabrina J. Li , Nicole A. Benedek

We develop a first-principles scheme to calculate adiabatic and non-adiabatic phonon frequencies in the full Brillouin zone. The method relies on the variational properties of a force-constants functional with respect to the first-order…

Materials Science · Physics 2015-05-19 Matteo Calandra , Gianni Profeta , Francesco Mauri

Relying on the anharmonic special displacement method, we introduce an ab initio quasistatic polymorphous framework to describe local disorder, anharmonicity, and electron-phonon coupling in superionic conductors. Using the example of cubic…

We present a detailed analysis of the non-analytic structure of the free energy for the itinerant ferromagnet near the quantum critical point in two and three dimensions. We analyze a model of electrons with an isotropic dispersion…

Strongly Correlated Electrons · Physics 2013-10-09 C. J. Pedder , F. Krüger , A. G. Green

We study the effect of quantum vibronic coupling on the electronic properties of carbon allotropes, including molecules and solids, by combining path integral first principles molecular dynamics (FPMD) with a colored noise thermostat. In…

Materials Science · Physics 2021-08-04 Arpan Kundu , Marco Govoni , Han Yang , Michele Ceriotti , Francois Gygi , Giulia Galli

The formation of a polaron quasiparticle from a bare electron is studied in the framework of the Holstein model of electron-phonon coupling. Using Schr\"{o}dinger's formalism, we calculate the time evolution of the distribution of the…

Strongly Correlated Electrons · Physics 2007-05-23 Li-Chung Ku , S. A. Trugman

The concept of quasi-particles forms the theoretical basis of our microscopic understanding of emergent phenomena associated with quantum mechanical many-body interactions. However, quasi-particle theory in disordered materials has proven…