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We investigate the low-energy properties of the Holstein polaron through calculation of the q-dependent phonon spectral function using an improved exact-diagonalization technique, defined over a variational Hilbert space. We perform a…

Other Condensed Matter · Physics 2010-09-28 Lev Vidmar , Janez Bonca , Stuart A. Trugman

We describe a new approach to compute the electron-phonon self-energy and carrier mobilities in semiconductors. Our implementation does not require a localized basis set to interpolate the electron-phonon matrix elements, with the advantage…

Information over the phonon band structure is crucial to predicting many thermodynamic properties of materials, such as thermal transport coefficients. Highly accurate phonon dispersion curves can be, in principle, calculated in the…

Materials Science · Physics 2020-11-25 Miquel Royo , Konstanze R. Hahn , Massimiliano Stengel

Phonon decoherence determines the characteristic timescales over which coherent lattice vibrations decay, making it a crucial process for understanding the non-equilibrium dynamics of crystal lattices after excitation by a pump pulse. Here,…

Strongly Correlated Electrons · Physics 2025-02-04 Yiming Pan , Christoph Emeis , Stephan Jauernik , Michael Bauer , Fabio Caruso

A first-principles approach called the {\it{self-consistent quasiharmonic approximation}} (SC-QHA) method is formulated to calculate the thermal expansion, thermomechanics, and thermodynamic functions of solids at finite temperatures with…

Materials Science · Physics 2016-04-28 Liang-Feng Huang , Xue-Zeng Lu , Emrys Tennessen , James M. Rondinelli

Accelerating the calculations of finite-temperature thermodynamic properties is a major challenge for rational materials design. Reliable methods can be quite expensive, limiting their effective applicability in autonomous high-throughput…

We present a scheme for the improved description of the long-range interatomic force constants in a more accurate way than the procedure which is commonly used within plane-wave based density-functional perturbation-theory calculations. Our…

Materials Science · Physics 2013-05-29 Katalin Gaal-Nagy , Dieter Strauch

Understanding the vibrational and thermal properties of amorphous solids is one of the most discussed and long-standing issues in condensed matter physics. Recent works have made significant steps towards understanding harmonic vibrational…

Soft Condensed Matter · Physics 2020-02-28 Hideyuki Mizuno , Masanari Shimada , Atsushi Ikeda

The renormalization of the band structure at zero temperature due to electron-phonon coupling is investigated in diamond, BN, LiF and MgO crystals. We implement a dynamical scheme to compute the frequency-dependent self-energy and the…

We develop a computational framework, based on the Boltzmann transport equation, with the ability to compute the thermal transport in nanostructured materials of any geometry using as the only input the bulk thermal conductivity…

Mesoscale and Nanoscale Physics · Physics 2014-10-20 Giuseppe Romano , Jeffrey C. Grossman

We present a perturbative method for calculating phonon properties of an insulator in the presence of a finite electric field. The starting point is a variational total-energy functional with a field-coupling term that represents the effect…

Materials Science · Physics 2009-12-17 Xinjie Wang , David Vanderbilt

Harnessing the power of low-dimensional materials in thermal applications calls for a solid understanding of the anomalous thermal properties of such systems. We analyze thermal conduction in one-dimensional systems by determining the…

Computational Physics · Physics 2015-12-21 K. Sääskilahti , J. Oksanen , S. Volz , J. Tulkki

An increasing number of theoretical calculations on few-layer materials have been reporting a non-zero sound velocity for all three acoustic phonon modes. In contrast with these reports, here we show that the lowest phonon dispersion branch…

Materials Science · Physics 2017-02-06 Jesús Carrete , Wu Li , Lucas Lindsay , David A. Broido , Luis J. Gallego , Natalio Mingo

Lattice vibrations within crystalline solids, or phonons, provide information on a variety of important material characteristics, from thermal qualities to optical properties and phase transition behaviour. When the material contains light…

Computational Physics · Physics 2025-06-27 Taylor Baird , Rodolphe Vuilleumier , Sara Bonella

The variational stochastic self-consistent harmonic approximation is combined with the calculation of third-order anharmonic coefficients within density-functional perturbation theory and the "$2n+1$" theorem to calculate anharmonic…

Materials Science · Physics 2015-06-16 Lorenzo Paulatto , Ion Errea , Matteo Calandra , Francesco Mauri

This paper gives a short overview of the calculation of thermal properties of materials from first principles, using the Quasi-Harmonic Approximation (QHA). We first introduce some of the thermal properties of interest and describe how they…

Materials Science · Physics 2011-12-22 Stefano Baroni , Paolo Giannozzi , Eyvaz Isaev

In quasicrystals, the phason degree of freedom and the inherent anharmonic potentials lead to complex dynamics which cannot be described by the usual phonon modes of motion. We have constructed simple one-dimensional model systems, the…

Materials Science · Physics 2010-10-11 Hansjörg Lipp , Michael Engel , Steffen Sonntag , Hans-Rainer Trebin

A first-principles-based method for computing phonons of magnetic random solid solutions including thermal magnetic fluctuations is developed. The method takes fluctuations of force constants (FCs) due to magnetic excitations as well as due…

Materials Science · Physics 2019-08-07 Yuji Ikeda , Fritz Körmann , Biswanath Dutta , Abel Carreras , Atsuto Seko , Jörg Neugebauer , Isao Tanaka

We report the first successful application of the {\it ab initio} quantum Monte Carlo (QMC) framework to a phonon dispersion calculation. A full phonon dispersion of diamond is successfully calculated at the variational Monte Carlo (VMC)…

Materials Science · Physics 2021-04-14 Kousuke Nakano , Tommaso Morresi , Michele Casula , Ryo Maezono , Sandro Sorella

While the vibrational thermodynamics of materials with small anharmonicity at low temperatures has been understood well based on the harmonic phonons approximation; at high temperatures, this understanding must accommodate how phonons…

Materials Science · Physics 2015-10-20 Tian Lan