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The analysis of correlation energy of the simplest first approximation of a variational method for the intrashell states of two-electron atoms is the purpose of the present work. This method allows to divide energy of atom on Coulomb and…

Atomic Physics · Physics 2008-10-23 V. V. Kavera

We consider the semi-relativistic Pauli-Fierz Hamiltonian and a no-pair model of a hydrogen-like atom interacting with a quantized photon field at the respective critical values of the Coulomb coupling constant. For arbitrary values of the…

Mathematical Physics · Physics 2013-08-07 Martin Könenberg , Oliver Matte

Taking into account results of WKB-approximation, we derive exact quantum energies and wave functions of even and odd states in the one-dimensional Coulomb potential

Quantum Physics · Physics 2019-02-07 A. M. Ishkhanyan , V. P. Krainov

We derive the ground state energy up to the fourth order in the fine structure constant $\alpha$ for the translation invariant Pauli-Fierz Hamiltonian for a spinless electron coupled to the quantized radiation field. As a consequence, we…

Mathematical Physics · Physics 2015-05-19 Jean-Marie Barbaroux , Semjon Vugalter

A calculation of the QED vacuum polarization potential in the Coulomb field of a pointlike nucleus was presented in an earlier publication by the author and his collaborators. Corrections up to order $\alpha^2 (Z\alpha)^7$ were evaluated,…

Atomic Physics · Physics 2026-04-29 Sergey Volkov

In calculating the energy corrections to the hydrogen levels we can identify two different types of modifications of the Coulomb potential $V_{C}$, with one of them being the standard quantum electrodynamics corrections, $\delta V$,…

Atomic Physics · Physics 2018-10-03 A. D. Bermudez Manjarres , D. Bedoya Fierro , N. G. Kelkar , M. Nowakowski

Based on classical electrodynamics, it is argued that the Coulomb potential (which is strictly valid for two point charges at rest), commonly used in the study of energy levels of hydrogen atom is not the correct one, because the electron…

General Physics · Physics 2012-01-11 Harihar Behera

We consider atoms or molecules coupled to the quantized electromagnetic radiation field in a dipole approximation. We show the existence of ground states and resonance states in situations where the eigenvalues are degenerate and protected…

Mathematical Physics · Physics 2025-07-08 David Hasler , Markus Lange

We calculate pair potential curves for interacting Rydberg atoms in a constant electric field and use them to determine the effective $C_3$ dipole-dipole and $C_6$ van der Waals coefficients. We compare the $C_3$ and $C_6$ with experiments…

We consider the van der Waals energy of an atom near the infinitely thin sphere with finite conductivity which model the fullerene. We put the sphere into spherical cavity inside the infinite dielectric media, then calculate the energy of…

Quantum Physics · Physics 2011-03-30 Nail R. Khusnutdinov

We consider a hydrogen-like atom in a quantized electromagnetic field which is modeled by means of the semi-relativistic Pauli-Fierz operator and prove that the infimum of the spectrum of the latter operator is an eigenvalue. In particular,…

Mathematical Physics · Physics 2011-10-18 Martin Könenberg , Oliver Matte , Edgardo Stockmeyer

The structure and stability of atomic and molecular systems with van der Waals (vdW) bonding are often determined by the interplay between attractive dispersion interactions and repulsive interactions caused by electron confinement. Arising…

Chemical Physics · Physics 2022-02-17 Ornella Vaccarelli , Dmitry V. Fedorov , Martin Stöhr , Alexandre Tkatchenko

We compute the expectations of the squares of the electric and magnetic fields in the vacuum region outside a half-space filled with a uniform non-dispersive dielectric. This gives predictions for the Casimir-Polder force on an atom in the…

High Energy Physics - Theory · Physics 2008-11-26 Adam D. Helfer , Andrew S. I. D. Lang

We study the energy of relativistic electrons and positrons interacting via the second quantized Coulomb potential in the field of a nucleus of charge Z within the Hartree-Fock approximation. We show that the associated functional has a…

Mathematical Physics · Physics 2007-05-23 J. -M. Barbaroux , W. Farkas , B. Helffer , H. Siedentop

A simple and computationally efficient scheme to calculate approximate imaginary-frequency dependent polarizability, hence asymptotic van der Waals coefficient, within density functional theory is proposed. The dynamical dipolar…

Materials Science · Physics 2009-04-20 Huy-Viet Nguyen , Stefano de Gironcoli

We review our recent progress in the determination of the high-density correlation energy $\Ec$ in two-electron systems. Several two-electron systems are considered, such as the well known helium-like ions (helium), and the Hooke's law atom…

Chemical Physics · Physics 2011-01-14 Pierre-François Loos , Peter M. W. Gill

We provide a theoretical description for the coupling between the intersubband excitations of a bi-dimensional electron gas with the electromagnetic field. This description, based on the electrical dipole gauge, applies to an arbitrary…

Quantum Gases · Physics 2012-12-21 Yanko Todorov , Carlo Sirtori

We analyze the supersymmetric features of isolated double-well potentials, both symmetric ones and ones under an asymmetric perturbation. Our studies are in concert with results obtained elsewhere. Further on, a particular interest is paid…

Chemical Physics · Physics 2008-07-25 Mladen Georgiev

In this work we investigate the Wigner localization of two interacting electrons at very low density in two and three dimensions using the exact diagonalization of the many-body Hamiltonian. We use our recently developed method based on…

Strongly Correlated Electrons · Physics 2021-10-13 Miguel Escobar Azor , Estefania Alves , Stefano Evangelisti , J. Arjan Berger

The problem of two electrons in a two-dimensional random potential is addressed numerically. Specifically, the role of the Coulomb interaction between electrons on localization is investigated by writing the Hamiltonian on a localized basis…

Disordered Systems and Neural Networks · Physics 2009-10-31 Jorge Talamantes , Michael Pollak